The product for the given reaction has to be shown and the major product has to be indicated. Concept introduction: Autoxidation involves reaction of a C − H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide. Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain. Major product is more substituted double bond.

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Answer 1

Question

Chapter 8, Problem 8.31P

(a)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

(b)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

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Answer 2

Question

Chapter 8, Problem 8.31P

(a)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

(b)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

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Answer 3

Question

Chapter 8, Problem 8.31P

(a)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

(b)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

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Answer 4

Question

Chapter 8, Problem 8.31P

(a)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

(b)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

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Answer 5

Chapter 8, Problem 8.31P

(a)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

(b)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

Answer 6

Chapter 8, Problem 8.31P

(a)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

Answer 7

Chapter 8, Problem 8.31P

(a)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product for the given reaction has to be shown and the major product has to be indicated.

Concept introduction:

Autoxidation involves reaction of a C−H bond, (usually allylic one) with oxygen under radical initiation condition. The product is a hydroperoxide.

Mechanism involves a radical chain process in which resonance-delocalized allylic radical intermediates reacts with molecular oxygen to give peroxy radical that continues the radical chain.

Major product is more substituted double bond.

Answer 10

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Answer 21

Ch. 8.2 - Prob. 8.1P Ch. 8.4 - Name and draw structural formulas for all...Ch. 8.4 - Using the table of bond dissociation enthalpies in...Ch. 8.5 - Prob. 8.4P Ch. 8.6 - Given the solution to Example 8.5, predict the...Ch. 8.7 - Prob. 8.6P Ch. 8.7 - Linoleic acid is shown below. What makes this...Ch. 8.7 - Prob. BQ Ch. 8.7 - Prob. CQ Ch. 8.7 - The strength of the HO bond in vitamin E is weaker...

Solution Summary: The author explains that autoxidation involves reaction of a C-H bond with oxygen under radical initiation condition.

Chapter 8 Solutions