Elements Of Physical Chemistry
7th Edition
ISBN: 9780198727873
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 8, Problem 8.2P
Interpretation Introduction
Interpretation:
The ionization energy of lithium ion has to be calculated.
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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that
both of them
have a molecular ion peak at m/2 =128. However ketone
(A) has a fragment peak at m/2 = 99 and 72
while ketone (B) snowed a
fragment peak at m/2 = 113 and 58.
9) Propose the most plausible structures for both ketones
b) Explain how you arrived at your conclusion by drawing the
Structures of the distinguishing fragments for each ketone,
including their fragmentation mechanisms.
Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from
the compound in KBr pellet) and the mass spectrum as shown below.
The mass spectrum of compound Tesla showed strong mt peak at 71.
TRANSMITTANCE
LOD
Relative Intensity
100
MS-NW-1539
40
20
80
T
44
55
10
15
20
25
30
35
40
45
50
55
60
65
70
75
m/z
D
4000
3000
2000
1500
1000
500
HAVENUMBERI-11
Chapter 8 Solutions
Elements Of Physical Chemistry
Ch. 8 - Prob. 8A.1STCh. 8 - Prob. 8A.2STCh. 8 - Prob. 8A.3STCh. 8 - Prob. 8A.4STCh. 8 - Prob. 8A.5STCh. 8 - Prob. 8B.2STCh. 8 - Prob. 8B.3STCh. 8 - Prob. 8B.4STCh. 8 - Prob. 8C.1STCh. 8 - Prob. 8C.2ST
Ch. 8 - Prob. 8D.1STCh. 8 - Prob. 8D.2STCh. 8 - Prob. 8D.3STCh. 8 - Prob. 8D.4STCh. 8 - Prob. 8D.5STCh. 8 - Prob. 8D.6STCh. 8 - Prob. 8D.7STCh. 8 - Prob. 8A.1ECh. 8 - Prob. 8A.2ECh. 8 - Prob. 8A.3ECh. 8 - Prob. 8A.6ECh. 8 - Prob. 8A.7ECh. 8 - Prob. 8A.8ECh. 8 - Prob. 8A.9ECh. 8 - Prob. 8A.10ECh. 8 - Prob. 8A.12ECh. 8 - Prob. 8B.1ECh. 8 - Prob. 8B.2ECh. 8 - Prob. 8B.3ECh. 8 - Prob. 8C.1ECh. 8 - Prob. 8C.2ECh. 8 - Prob. 8D.1ECh. 8 - Prob. 8D.2ECh. 8 - Prob. 8D.3ECh. 8 - Prob. 8D.4ECh. 8 - Prob. 8D.5ECh. 8 - Prob. 8D.6ECh. 8 - Prob. 8D.7ECh. 8 - Prob. 8D.8ECh. 8 - Prob. 8D.9ECh. 8 - Prob. 8D.11ECh. 8 - Prob. 8D.12ECh. 8 - Prob. 8.1DQCh. 8 - Prob. 8.2DQCh. 8 - Prob. 8.3DQCh. 8 - Prob. 8.4DQCh. 8 - Prob. 8.5DQCh. 8 - Prob. 8.6DQCh. 8 - Prob. 8.7DQCh. 8 - Prob. 8.8DQCh. 8 - Prob. 8.2PCh. 8 - Prob. 8.4PCh. 8 - Prob. 8.7PCh. 8 - Prob. 8.8PCh. 8 - Prob. 8.9PCh. 8 - Prob. 8.11PCh. 8 - Prob. 8.12P
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- Technetium is the first element in the periodic chart that does not have any stable isotopes. Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half life ideally suited for medical tests. It would seem that the decay of technetium should fit the treatment above with the result In(c/c) = -kt. The table below includes data from the two sites: http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130 http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab). a. b. C. Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also graph In(c/c.) on the vertical axis versus time on the horizontal axis. When half of the original amount of starting material has hours fraction remaining disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the material to decay away). Determine the slope of your In(c/c.) vs t graph and…arrow_forwardPlease correct answer and don't use hand ratingarrow_forward1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)arrow_forward
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