(a) Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated. Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes . The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 1

Question

Chapter 8, Problem 8.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 2

Question

Chapter 8, Problem 8.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 3

Question

Chapter 8, Problem 8.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 4

Question

Chapter 8, Problem 8.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 5

Chapter 8, Problem 8.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 6

Chapter 8, Problem 8.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 7

Chapter 8, Problem 8.28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 8

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 9

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 10

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 11

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 12

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 13

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 8 - Problem 8.1 Label the and carbons in each alkyl...Ch. 8 - Problem 8.2 Classify each alkene in the following...Ch. 8 - Prob. 8.3P Ch. 8 - Prob. 8.4P Ch. 8 - Problem 8.5 Label each pair of alkenes as...Ch. 8 - Problem 8.6 Which alkene in each pair is more...Ch. 8 - Problem 8.7 Several factors can affect alkene...Ch. 8 - Prob. 8.8P Ch. 8 - Prob. 8.9P Ch. 8 - Prob. 8.10P

Solution Summary: The author explains that the structure of the alkene indicates that it is formed from a primary halide. Strong bases are usually employed for elimination reactions.

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Chapter 8 Solutions