Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
11th Edition
ISBN: 9781305705159
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 8, Problem 8.105P
Interpretation Introduction
Interpretation:
A student pulls a bottle of TRIS off a shelf and notes that the bottle says, “TRIS (basic form), pKa = 8.3”. The student tells we that if we add 0.1 mol of this compound to 100 mL of water, the pH will be 8.3. Explanation required that student is correct or not.
Concept Introduction:
There are associated scales within the chemistry utilized to find out how basic and acidic a solution is, as well as the strength of bases and acids. Though most familiar is pH scale, Ka, pKa, Kb and pKb are the common calculation which offer understanding into acid-base reactions.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
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f. Moles of CO2 evolved.
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Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
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Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
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• CH3
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c.…
Chapter 8 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 8.3 - Problem 8-1 Draw the acid and base reactions for...Ch. 8.4 - Prob. 8.2PCh. 8.5 - Prob. 8.3PCh. 8.5 - Problem 8-4 Which is the stronger acid? (a)...Ch. 8.6 - Problem 8-5 Write the balanced net ionic equation...Ch. 8.7 - Problem 8-6 The [OH-] of an aqueous solution is M....Ch. 8.8 - Problem 8-7 (a) The [H3O+] of an acidic solution...Ch. 8.8 - Problem 8-8 The [OH-] of a solution is M. What are...Ch. 8.9 - Problem 8-9 Calculate the concentration of an...Ch. 8.10 - Problem 8-10 What is the pH of a buffer solution...
Ch. 8.11 - Problem 8-11 What is the pH of a boric acid buffer...Ch. 8.12 - Prob. 8.12PCh. 8 - 8-13 Define (a) an Arrhenius acid and (b) an...Ch. 8 - 8-14 Write an equation for the reaction that takes...Ch. 8 - 8-15 Write an equation for the reaction that takes...Ch. 8 - 8-16 For each of the following, tell whether the...Ch. 8 - 8-17 For each of the following, tell whether the...Ch. 8 - 8-18 Which of these acids are monoprotic, which...Ch. 8 - 8-19 Define (a) a Brønsted—Lowry acid and (b) a...Ch. 8 - 8-20 Write the formula for the conjugate base of...Ch. 8 - 8-21 Write the formula for the conjugate base of...Ch. 8 - Prob. 8.22PCh. 8 - Prob. 8.23PCh. 8 - Prob. 8.24PCh. 8 - 8-25 Draw the acid and base reactions for the...Ch. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - 8-28 Will carbon dioxide be evolved as a gas when...Ch. 8 - Prob. 8.29PCh. 8 - Prob. 8.30PCh. 8 - Prob. 8.31PCh. 8 - Prob. 8.32PCh. 8 - 8-33 Write an equation for the reaction of HCI...Ch. 8 - 8-34 When a solution of sodium hydroxide is added...Ch. 8 - 8-35 Given the following values of [H3O+),...Ch. 8 - 8-36 Given the following values of [OH-],...Ch. 8 - 8-37 What is the pH of each solution given the...Ch. 8 - 8-38 What is the pH and pOH of each solution given...Ch. 8 - 8-39 What is the pH of each solution given the...Ch. 8 - Prob. 8.40PCh. 8 - 8-41 What is the [OH-] and pOH of each solution?...Ch. 8 - Prob. 8.42PCh. 8 - 8-43 What is the molarity of a solution made by...Ch. 8 - 8-44 What is the molarity of a solution made by...Ch. 8 - 8-45 Describe how you would prepare each of the...Ch. 8 - 8-46 If 25.0 mL of an aqueous solution of H2SO4...Ch. 8 - 8-47 A sample of 27.0 mL of 0.310 M NaOH is...Ch. 8 - 8-48 A 0.300 M solution of H2SO4 was used to...Ch. 8 - 8-49 A solution of NaOH base was titrated with...Ch. 8 - 8-50 The usual concentration of HCO3- ions in...Ch. 8 - 8-51 What is the end point of a titration?Ch. 8 - Prob. 8.52PCh. 8 - 8-53 Write equations to show what happens when, to...Ch. 8 - 8-54 Write equations to show what happens when, to...Ch. 8 - 8-55 We commonly refer to a buffer as consisting...Ch. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - 8-58 What is the connection between buffer action...Ch. 8 - Prob. 8.59PCh. 8 - 8-60 How is the buffer capacity affected by the...Ch. 8 - 8-61 Can 100 of 0.1 M phosphate buffer at pH 7.2...Ch. 8 - 8-62 What is the pH of a buffer solution made by...Ch. 8 - 8-63 The pH of a solution made by dissolving 1.0...Ch. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - 8-66 Calculate the pH of an aqueous solution...Ch. 8 - Prob. 8.67PCh. 8 - 8-68 If you have 100 mL of a 0.1 M buffer made of...Ch. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - 8-71 Explain why you do not need to know the...Ch. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - Prob. 8.75PCh. 8 - 8-76 (Chemical Connections 8B) Name the most...Ch. 8 - Prob. 8.77PCh. 8 - Prob. 8.78PCh. 8 - 8-79 (Chemical Connections 8D) Another form of the...Ch. 8 - Prob. 8.80PCh. 8 - Prob. 8.81PCh. 8 - 8-82 Assume that you have a dilute solution of HCI...Ch. 8 - Prob. 8.83PCh. 8 - Prob. 8.84PCh. 8 - Prob. 8.85PCh. 8 - 8-86 Following are three organic acids and the...Ch. 8 - 8-87 The pKavalue of barbituric acid is 5.0. If...Ch. 8 - Prob. 8.88PCh. 8 - Prob. 8.89PCh. 8 - Prob. 8.90PCh. 8 - Prob. 8.91PCh. 8 - Prob. 8.92PCh. 8 - 8-93 Do a 1.0 M CH3COOH solution and a 1.0 M HCI...Ch. 8 - 8-94 Suppose you wish to make a buffer whose pH is...Ch. 8 - Prob. 8.95PCh. 8 - 8-96 Suppose you want to make a CH3COOH/CH3COO-...Ch. 8 - Prob. 8.97PCh. 8 - 8-98 When a solution prepared by dissolving 4.00 g...Ch. 8 - Prob. 8.99PCh. 8 - Prob. 8.100PCh. 8 - 8-101 Suppose you have an aqueous solution...Ch. 8 - Prob. 8.102PCh. 8 - 8-103 Suppose you have a phosphate buffer...Ch. 8 - Prob. 8.104PCh. 8 - Prob. 8.105PCh. 8 - Prob. 8.106PCh. 8 - 8-107 Following are pH ranges for several human...Ch. 8 - 8-108 What is the ratio of HPO42-/H2PO4- in a...Ch. 8 - Prob. 8.109PCh. 8 - 8-110 A concentrated hydrochloric acid solution...Ch. 8 - 8-111 The volume of an adult's stomach ranges from...Ch. 8 - 8-112 Consider an initial 0.040 M hypobromous acid...Ch. 8 - Prob. 8.113PCh. 8 - Prob. 8.114PCh. 8 - 8-115 When a solution prepared by dissolving 0.125...Ch. 8 - 8-116 A railroad tank car derails and spills 26...Ch. 8 - Prob. 8.117P
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