Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Draw the complete mechanism for the reaction below. Please include appropriate arrows, intermediates, and formal charges.
(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
Chapter 8 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 8 - What are the correct coefficients (reading from...Ch. 8 - Prob. 2SAQCh. 8 - Prob. 3SAQCh. 8 - For the reaction shown here, 3.5 mol A is mixed...Ch. 8 - Manganese(IV) oxide reacts with aluminum to form...Ch. 8 - Sodium and chlorine react to form sodium chloride....Ch. 8 - Sulfur and fluorine react to form sulfur...Ch. 8 - A reaction has a theoretical yield of 45.8 g. When...Ch. 8 - Prob. 9SAQCh. 8 - Solid potassium chlorate (KCIO3) decomposes into...
Ch. 8 - Prob. 1ECh. 8 - Prob. 2ECh. 8 - What is the difference between a physical change...Ch. 8 - What is the difference between a physical property...Ch. 8 - What is a balanced chemical equation?Ch. 8 - Why must chemical equations be balanced?Ch. 8 - What is reaction stoichiometry? What is the...Ch. 8 - In a chemical reaction, what is the limiting...Ch. 8 - In a chemical reaction, what is the theoretical...Ch. 8 - We typically calculate the percent yield using the...Ch. 8 - Prob. 11ECh. 8 - Prob. 12ECh. 8 - Write a general equation for the reaction of an...Ch. 8 - Prob. 14ECh. 8 - Classify each change as physical or chemical....Ch. 8 - Prob. 16ECh. 8 - Prob. 17ECh. 8 - Prob. 18ECh. 8 - Classify each of the listed properties of...Ch. 8 - Prob. 20ECh. 8 - Classify each property as physical or chemical the...Ch. 8 - Prob. 22ECh. 8 - Sulfuric acid (H2SO4) is a component of acid rain...Ch. 8 - Nitric acid (HNO3) is a component of acid rain...Ch. 8 - Prob. 25ECh. 8 - Prob. 26ECh. 8 - Write a balanced chemical equation for the...Ch. 8 - Write a balanced equation for the photosynthesis...Ch. 8 - Write a balanced chemical equation for each...Ch. 8 - Write a balanced chemical equation for each...Ch. 8 - Write a balanced chemical equation for the...Ch. 8 - Write a balanced chemical equation for the...Ch. 8 - Balance each chemical equation. CO2(g) + CaSiO3(s)...Ch. 8 - Balance each chemical equation. Na2S(aq) +...Ch. 8 - Prob. 35ECh. 8 - Consider the unbalanced equation for the...Ch. 8 - Calculate how many moles of NO2 form when each...Ch. 8 - Calculate how many moles of NH3 form when each...Ch. 8 - Consider the balanced equation: SiO2(s) + 3 C(s)...Ch. 8 - Consider the balanced equation: 2 N2H4(s) +...Ch. 8 - Hydrobromic acid (HBr) dissolves solid iron...Ch. 8 - Sulfuric acid (H2SO4) dissolves aluminum metal...Ch. 8 - For each of the reactions, calculate the mass (in...Ch. 8 - For each of the reactions, calculate the mass (in...Ch. 8 - For the following reaction, determine the limiting...Ch. 8 - Find the limiting reactant for each initial amount...Ch. 8 - Consider the reaction: HCl(g) + O2(g) 2 H2O(g) +...Ch. 8 - Consider the reaction: 2 CH 3 OH(g)+3 O 2 (g)2 CO...Ch. 8 - Calculate the theoretical yield of the product (in...Ch. 8 - Calculate the theoretical yield of product (in...Ch. 8 - Zinc sulfide reacts with oxygen according to the...Ch. 8 - Iron(ll) sulfide reacts with hydrochloric acid...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - Iron(lll) oxide reacts with carbon monoxide...Ch. 8 - Elemental phosphorus reacts with chlorine gas...Ch. 8 - Lead(ll) ions can be removed from solution with...Ch. 8 - Prob. 58ECh. 8 - Urea (CH4N2O) is a common fertilizer that is...Ch. 8 - Prob. 60ECh. 8 - Prob. 61ECh. 8 - Complete and balance each combustion reaction...Ch. 8 - Prob. 63ECh. 8 - Prob. 64ECh. 8 - Prob. 65ECh. 8 - Prob. 66ECh. 8 - Prob. 67ECh. 8 - Prob. 68ECh. 8 - Prob. 69ECh. 8 - Prob. 70ECh. 8 - Aspirin can be made in the laboratory by reacting...Ch. 8 - The combustion of liquid ethanol (C2H5OH) produces...Ch. 8 - Prob. 73ECh. 8 - Prob. 74ECh. 8 - Prob. 75ECh. 8 - An important reaction that takes place in a blast...Ch. 8 - A liquid fuel mixture contains 30.35% hexane...Ch. 8 - Titanium occurs in the magnetic mineral ilmenite...Ch. 8 - A mixture of C3H8 and C2H2 has a mass of 2.0 g. It...Ch. 8 - Prob. 80ECh. 8 - Lead poisoning is a serious condition resulting...Ch. 8 - Prob. 82ECh. 8 - Metallic aluminum reacts with MnO2 at elevated...Ch. 8 - Prob. 84ECh. 8 - Consider the reaction: 4K(s)+O2(g)2K2O(s) The...Ch. 8 - Prob. 86ECh. 8 - Consider the reaction:...
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- 2. Propose an efficient synthesis for each of the following transformations. Pay careful attention to both the regio and stereochemical outcomes. ¡ H H racemicarrow_forwardZeroth Order Reaction In a certain experiment the decomposition of hydrogen iodide on finely divided gold is zeroth order with respect to HI. 2HI(g) Au H2(g) + 12(9) Rate = -d[HI]/dt k = 2.00x104 mol L-1 s-1 If the experiment has an initial HI concentration of 0.460 mol/L, what is the concentration of HI after 28.0 minutes? 1 pts Submit Answer Tries 0/5 How long will it take for all of the HI to decompose? 1 pts Submit Answer Tries 0/5 What is the rate of formation of H2 16.0 minutes after the reaction is initiated? 1 pts Submit Answer Tries 0/5arrow_forwardangelarodriguezmunoz149@gmail.com Hi i need help with this question i am not sure what the right answers are.arrow_forward
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