Laboratory Manual Chemistry in Context
8th Edition
ISBN: 9780073518121
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 8, Problem 26Q
Consider these three sources of light: a candle, a battery-powered flashlight, and an electric light bulb. For each source, provide
- a. the origin of the light.
- b. the immediate source of the energy that appears as light.
- c. the original source of the energy that appears as light.
Hint: Trace this back stepwise as far as possible.
- d. the end-products and by-products produced from using each.
- e. the environmental costs associated with each.
- f. the advantages and disadvantages of each light source.
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Please predict the products for each of the
following reactions.
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(syn- vs anti- or both).
If a mixture of enantiomers is formed, please
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Hint: In this case you must choose the best
answer to demonstrate the stereochemistry of
H2 addition.
1.03
2. (CH3)2S
BIZ
CH₂OH
2. DMS
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ΖΗ
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HBr
20 1
HBr
ROOR (peroxide)
HO
H-SO
HC
12 11 10
BH, THE
2. H2O2, NaOH
Brz
cold
HI
19
18
17
16
MCPBA
15
14
13
A
Br
H₂O
BH3⚫THF
Brz
EtOH
Pd or Ni (catalyst)
D₂ (deuterium)
1. Os04
2. H2O2
CH3CO3H
(peroxyacid)
1. MCPBA
2. H₂O*
H
B
+
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H
H
"H
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H
H
D
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Chapter 8 Solutions
Laboratory Manual Chemistry in Context
Ch. 8.1 - Prob. 8.3YTCh. 8.1 - Prob. 8.4YTCh. 8.3 - Prob. 8.9CTCh. 8.4 - Prob. 8.10CTCh. 8.4 - Prob. 8.11SCCh. 8.5 - Prob. 8.13SCCh. 8.5 - Prob. 8.14CTCh. 8.6 - Prob. 8.16CTCh. 8.7 - Prob. 8.17CTCh. 8.7 - Prob. 8.18YT
Ch. 8.7 - Prob. 8.21CTCh. 8.8 - Prob. 8.23CTCh. 8 - Prob. 1QCh. 8 - Prob. 2QCh. 8 - Which chemical species gets oxidized and which...Ch. 8 - What is the difference between a galvanic cell and...Ch. 8 - Two common units associated with electricity are...Ch. 8 - Consider the galvanic cell pictured. A coating of...Ch. 8 - Prob. 7QCh. 8 - a. How does the voltage from a tiny AAA alkaline...Ch. 8 - Prob. 9QCh. 8 - The mercury battery has been used extensively in...Ch. 8 - Prob. 12QCh. 8 - During the conversion of O2(g) to H2O(l) in a fuel...Ch. 8 - How does the reaction between hydrogen and oxygen...Ch. 8 - This diagram represents the hydrogen fuel cell...Ch. 8 - What is a PEM fuel cell? How does it differ from...Ch. 8 - In addition to hydrogen, methane also has been...Ch. 8 - Prob. 18QCh. 8 - Potassium and lithium both are reactive Group 1...Ch. 8 - What challenges keep hydrogen fuel cells from...Ch. 8 - Every year, 5.6 1021 kJ of energy comes to Earth...Ch. 8 - Prob. 22QCh. 8 - Prob. 23QCh. 8 - Prob. 24QCh. 8 - Prob. 25QCh. 8 - Consider these three sources of light: a candle, a...Ch. 8 - Prob. 27QCh. 8 - What is the difference between an electrolytic...Ch. 8 - Provide some differences between a leadacid...Ch. 8 - Prob. 30QCh. 8 - The company ZPower is promoting its silverzinc...Ch. 8 - Prob. 32QCh. 8 - Prob. 33QCh. 8 - You never need to plug in Toyotas gasolinebattery...Ch. 8 - Prob. 35QCh. 8 - What is the tragedy of the commons? How does this...Ch. 8 - Hydrogen is considered an environmentally friendly...Ch. 8 - Fuel cells were invented in 1839 but never...Ch. 8 - Hydrogen and methane both can react with oxygen in...Ch. 8 - Engineers have developed a prototype fuel cell...Ch. 8 - How can the principles of green chemistry be...Ch. 8 - Prob. 42QCh. 8 - Prob. 43QCh. 8 - Small quantities of hydrogen gas can be prepared...Ch. 8 - Prob. 45QCh. 8 - Prob. 46QCh. 8 - Prob. 47QCh. 8 - Prob. 48QCh. 8 - Although Alessandro Volta is credited with the...Ch. 8 - Prob. 50QCh. 8 - If all of todays technology presently based on...Ch. 8 - Prob. 52QCh. 8 - Prob. 53QCh. 8 - Prob. 54QCh. 8 - Prob. 55Q
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- Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. cold KMnO4, NaOH 2. DMS 1. 03 CH3OH Br2 1. 03 2. (CH3)2S H₂ Pd or Pt (catalyst) HBr 18 19 20 1 HBr ROOR (peroxide) H₂O H₂SO4 HCI HI 17 16 6 15 MCPBA 1. BH3 THF 2. H₂O2, NaOH 1. OsO4 2. H₂O₂ 110 CH3CO₂H (peroxyacid) 1. MCPBA 2. H₂O* Br2 H₂O BH3 THF B12 EtOH Pd or Ni (catalyst) D₂ (deuterium) Bra A B C D H OH H OH OH H OH α α α OH H OH OH фон d H "Harrow_forwardBriefly indicate the models that describe the structure of the interface: Helmholtz-Perrin, Gouy-Chapman, Stern and Grahame models.arrow_forwardElectrochemistry. Briefly describe the Gibbs model and the Gibbs absorption equation.arrow_forward
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