
Laboratory Manual Chemistry in Context
8th Edition
ISBN: 9780073518121
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 8, Problem 34Q
You never need to plug in Toyota’s gasoline–battery hybrid car to recharge the batteries. Explain.
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
acids:
0.2 mol of KOH is added to
1.0 L of a 0.5 M HF
solution.
bases:
Х
other: ☐
acids:
0.10 mol of HI is added to
1.0 L of a solution that is
1.4M in both HF and NaF.
bases:
other: ☐
0,0,...
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18
Ar
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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Chapter 8 Solutions
Laboratory Manual Chemistry in Context
Ch. 8.1 - Prob. 8.3YTCh. 8.1 - Prob. 8.4YTCh. 8.3 - Prob. 8.9CTCh. 8.4 - Prob. 8.10CTCh. 8.4 - Prob. 8.11SCCh. 8.5 - Prob. 8.13SCCh. 8.5 - Prob. 8.14CTCh. 8.6 - Prob. 8.16CTCh. 8.7 - Prob. 8.17CTCh. 8.7 - Prob. 8.18YT
Ch. 8.7 - Prob. 8.21CTCh. 8.8 - Prob. 8.23CTCh. 8 - Prob. 1QCh. 8 - Prob. 2QCh. 8 - Which chemical species gets oxidized and which...Ch. 8 - What is the difference between a galvanic cell and...Ch. 8 - Two common units associated with electricity are...Ch. 8 - Consider the galvanic cell pictured. A coating of...Ch. 8 - Prob. 7QCh. 8 - a. How does the voltage from a tiny AAA alkaline...Ch. 8 - Prob. 9QCh. 8 - The mercury battery has been used extensively in...Ch. 8 - Prob. 12QCh. 8 - During the conversion of O2(g) to H2O(l) in a fuel...Ch. 8 - How does the reaction between hydrogen and oxygen...Ch. 8 - This diagram represents the hydrogen fuel cell...Ch. 8 - What is a PEM fuel cell? How does it differ from...Ch. 8 - In addition to hydrogen, methane also has been...Ch. 8 - Prob. 18QCh. 8 - Potassium and lithium both are reactive Group 1...Ch. 8 - What challenges keep hydrogen fuel cells from...Ch. 8 - Every year, 5.6 1021 kJ of energy comes to Earth...Ch. 8 - Prob. 22QCh. 8 - Prob. 23QCh. 8 - Prob. 24QCh. 8 - Prob. 25QCh. 8 - Consider these three sources of light: a candle, a...Ch. 8 - Prob. 27QCh. 8 - What is the difference between an electrolytic...Ch. 8 - Provide some differences between a leadacid...Ch. 8 - Prob. 30QCh. 8 - The company ZPower is promoting its silverzinc...Ch. 8 - Prob. 32QCh. 8 - Prob. 33QCh. 8 - You never need to plug in Toyotas gasolinebattery...Ch. 8 - Prob. 35QCh. 8 - What is the tragedy of the commons? How does this...Ch. 8 - Hydrogen is considered an environmentally friendly...Ch. 8 - Fuel cells were invented in 1839 but never...Ch. 8 - Hydrogen and methane both can react with oxygen in...Ch. 8 - Engineers have developed a prototype fuel cell...Ch. 8 - How can the principles of green chemistry be...Ch. 8 - Prob. 42QCh. 8 - Prob. 43QCh. 8 - Small quantities of hydrogen gas can be prepared...Ch. 8 - Prob. 45QCh. 8 - Prob. 46QCh. 8 - Prob. 47QCh. 8 - Prob. 48QCh. 8 - Although Alessandro Volta is credited with the...Ch. 8 - Prob. 50QCh. 8 - If all of todays technology presently based on...Ch. 8 - Prob. 52QCh. 8 - Prob. 53QCh. 8 - Prob. 54QCh. 8 - Prob. 55Q
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