Bundle: Chemistry: An Atoms First Approach, 2nd, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
2nd Edition
ISBN: 9781305717633
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 8, Problem 21Q
Interpretation Introduction
Interpretation:
The level of column of barometer if the barometer is filled with water instead of mercury should be determined and explained.
Concept Introduction:
- The manometer is a devise used measure the pressure of a gas. The pressure of gas is determined by the value of ‘h’ shown by the manometer. This ‘h’-value is added or subtracted with atmospheric pressure to determine the pressure of gas.
- The fluid used in a manometer can be varied.
- The pressure is directly proportional to the mass of fluid, because pressure is the force acting per area.
- Equation for density is,
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 8 Solutions
Bundle: Chemistry: An Atoms First Approach, 2nd, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 8 - Prob. 1RQCh. 8 - Prob. 2RQCh. 8 - Prob. 3RQCh. 8 - Prob. 4RQCh. 8 - Prob. 5RQCh. 8 - Prob. 6RQCh. 8 - Prob. 7RQCh. 8 - Prob. 8RQCh. 8 - Prob. 9RQCh. 8 - Why do real gases not always behave ideally? Under...
Ch. 8 - Prob. 3ALQCh. 8 - Prob. 4ALQCh. 8 - Prob. 6ALQCh. 8 - Prob. 8ALQCh. 8 - Prob. 11ALQCh. 8 - Prob. 12ALQCh. 8 - Prob. 15ALQCh. 8 - Prob. 16ALQCh. 8 - Draw molecular-level views that show the...Ch. 8 - Prob. 20QCh. 8 - Prob. 21QCh. 8 - Prob. 22QCh. 8 - Prob. 23QCh. 8 - Prob. 24QCh. 8 - Prob. 25QCh. 8 - Consider two different containers, each filled...Ch. 8 - Prob. 27QCh. 8 - Prob. 28QCh. 8 - Prob. 29QCh. 8 - Prob. 30QCh. 8 - Prob. 31QCh. 8 - Prob. 32QCh. 8 - Prob. 33QCh. 8 - Prob. 34QCh. 8 - Prob. 35QCh. 8 - Prob. 36QCh. 8 - Prob. 37ECh. 8 - Prob. 38ECh. 8 - A sealed-tube manometer (as shown below) can be...Ch. 8 - Prob. 40ECh. 8 - A diagram for an open-tube manometer is shown...Ch. 8 - Prob. 42ECh. 8 - Prob. 43ECh. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - Prob. 47ECh. 8 - Prob. 48ECh. 8 - Prob. 49ECh. 8 - Prob. 50ECh. 8 - The Steel reaction vessel of a bomb calorimeter,...Ch. 8 - A 5.0-L flask contains 0.60 g O2 at a temperature...Ch. 8 - Prob. 53ECh. 8 - A person accidentally swallows a drop of liquid...Ch. 8 - A gas sample containing 1.50 moles at 25C exerts a...Ch. 8 - Prob. 56ECh. 8 - Prob. 57ECh. 8 - What will be the effect on the volume of an ideal...Ch. 8 - Prob. 59ECh. 8 - Prob. 60ECh. 8 - An ideal gas is contained in a cylinder with a...Ch. 8 - Prob. 62ECh. 8 - A sealed balloon is filled with 1.00 L helium at...Ch. 8 - Prob. 64ECh. 8 - Consider the following reaction:...Ch. 8 - A student adds 4.00 g of dry ice (solid CO2) to an...Ch. 8 - Air bags are activated when a severe impact causes...Ch. 8 - Concentrated hydrogen peroxide solutions are...Ch. 8 - In 1897 the Swedish explorer Andre tried to reach...Ch. 8 - Sulfur trioxide, SO3, is produced in enormous...Ch. 8 - A 15.0-L rigid container was charged with 0.500...Ch. 8 - An important process for the production of...Ch. 8 - Consider the reaction between 50.0 mL liquid...Ch. 8 - Urea (H2NCONH2) is used extensively as a nitrogen...Ch. 8 - Prob. 75ECh. 8 - Prob. 76ECh. 8 - Prob. 77ECh. 8 - A compound has the empirical formula CHCl. A...Ch. 8 - Prob. 79ECh. 8 - Given that a sample of air is made up of nitrogen,...Ch. 8 - Prob. 81ECh. 8 - Prob. 82ECh. 8 - Prob. 83ECh. 8 - Prob. 84ECh. 8 - Consider the flasks in the following diagram. What...Ch. 8 - Consider the flask apparatus in Exercise 85, which...Ch. 8 - Prob. 87ECh. 8 - At 0C a 1.0-L flask contains 5.0 102 mole of N2,...Ch. 8 - Prob. 89ECh. 8 - A tank contains a mixture of 52.5 g oxygen gas and...Ch. 8 - Prob. 91ECh. 8 - Helium is collected over water at 25C and 1.00 atm...Ch. 8 - At elevated temperatures, sodium chlorate...Ch. 8 - Xenon and fluorine will react to form binary...Ch. 8 - Methanol (CH3OH) can be produced by the following...Ch. 8 - In the Mthode Champenoise, grape juice is...Ch. 8 - Hydrogen azide, HN3, decomposes on heating by the...Ch. 8 - Prob. 98ECh. 8 - Some very effective rocket fuels are composed of...Ch. 8 - The oxides of Group 2A metals (symbolized by M...Ch. 8 - Prob. 101ECh. 8 - Prob. 102ECh. 8 - Prob. 103ECh. 8 - Prob. 104ECh. 8 - Prob. 105ECh. 8 - Prob. 106ECh. 8 - Prob. 107ECh. 8 - Prob. 108ECh. 8 - Prob. 109ECh. 8 - Prob. 110ECh. 8 - Prob. 111ECh. 8 - Prob. 112ECh. 8 - Prob. 113ECh. 8 - Prob. 114ECh. 8 - Prob. 115ECh. 8 - Prob. 116ECh. 8 - Prob. 117ECh. 8 - Prob. 118ECh. 8 - Prob. 119ECh. 8 - Prob. 120ECh. 8 - Prob. 121ECh. 8 - Prob. 122ECh. 8 - Prob. 123AECh. 8 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2,...Ch. 8 - Prob. 125AECh. 8 - A 2.747g sample of manganese metal is reacted with...Ch. 8 - Prob. 127AECh. 8 - Cyclopropane, a gas that when mixed with oxygen is...Ch. 8 - The nitrogen content of organic compounds can be...Ch. 8 - Prob. 130AECh. 8 - A 15.0L tank is filled with H2 to a pressure of...Ch. 8 - A spherical glass container of unknown volume...Ch. 8 - Prob. 133AECh. 8 - A 20.0L stainless steel container at 25C was...Ch. 8 - Metallic molybdenum can be produced from the...Ch. 8 - Prob. 136AECh. 8 - Prob. 137AECh. 8 - One of the chemical controversies of the...Ch. 8 - An organic compound contains C, H, N, and O....Ch. 8 - Prob. 140AECh. 8 - The total volume of hydrogen gas needed to fill...Ch. 8 - Prob. 142AECh. 8 - Prob. 143CWPCh. 8 - Prob. 144CWPCh. 8 - A certain flexible weather balloon contains helium...Ch. 8 - Prob. 146CWPCh. 8 - A 20.0L nickel container was charged with 0.859...Ch. 8 - Consider the unbalanced chemical equation below:...Ch. 8 - Prob. 149CWPCh. 8 - Which of the following statements is(are) true? a....Ch. 8 - A chemist weighed out 5.14 g of a mixture...Ch. 8 - A mixture of chromium and zinc weighing 0.362 g...Ch. 8 - Prob. 153CPCh. 8 - You have an equimolar mixture of the gases SO2 and...Ch. 8 - Methane (CH4) gas flows into a combustion chamber...Ch. 8 - Prob. 156CPCh. 8 - Prob. 157CPCh. 8 - Prob. 158CPCh. 8 - You have a helium balloon at 1.00 atm and 25C. You...Ch. 8 - Prob. 160CPCh. 8 - You are given an unknown gaseous binary compound...Ch. 8 - Prob. 162CPCh. 8 - Calculate w and E when 1 mole of a liquid is...Ch. 8 - The preparation of NO2(g) from N2(g) and O2(g) is...Ch. 8 - In the presence of nitric acid, UO2+ undergoes a...Ch. 8 - Silane, SiH4, is the silicon analogue of methane,...Ch. 8 - Prob. 167IPCh. 8 - Prob. 168IPCh. 8 - Prob. 169MP
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