
Concept explainers
Interpretation: The Lewis structure, electron pair and molecular geometry for the given set of molecules should be determined also that their similarities and differences should be compared.
Concept Introduction:
- Lewis structures are diagrams that represent the
chemical bonding of covalently bonded molecules and coordination compounds. - It is also known as Lewis dot structures which represent the bonding between atoms of a molecule and the lone pairs of electrons that may exist in the molecule.
- The Lewis structure is based on the concept of the octet rule so that the electrons shared in each atom should have 8 electrons in its outer shell.
Lewis structure for any molecule is drawn by using the following steps,
First the skeletal structure for the given molecule is drawn then the total number of valence electrons for all atoms present in the molecule is determined
The next step is to subtract the electrons present in the total number of bonds present in the skeletal structure of the molecule with the total valence electrons such that considering each bond contains two electrons with it.
Finally, the electrons which got after subtractions have to be equally distributed such that each atom contains eight electrons in its valence shell.
VSEPR Theory:
As the name itself indicates that the basis for this theory is the electron pair that is bonded electron present in either single or double bonds or lone pair electrons, present in the valence shell tends to repel each other which then tend to be in position in order to minimize the repulsions. The steps involved in the theory in describing the geometry is as follows,
- The first step is to draw the correct Lewis structure for the molecule.
- Then, the electron domain around the central atom should be counted and the geometry that matches with that type of domain in VSEPR should be determined.
- Finally, the geometry is predicted by using the orientation of atoms.
The molecules with considering the domains of type
Electron Domain: In VSEPR theory, both the lone pair and the bonded pair are together considered as electron domain regardless of the type of bond in which the bonded pair presents.
Electron-Pair geometry: It is the geometry obtained by considering all valence electrons and bond pairs around central atom.
Molecular geometry: It is the geometry obtained by considering only the directly bonded atoms with the central atom.

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Chapter 8 Solutions
OWLv2 6-Months Printed Access Card for Kotz/Treichel/Townsend's Chemistry & Chemical Reactivity, 9th, 9th Edition
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