Owlv2 With Labskills, 4 Terms (24 Months) Printed Access Card For Williamson/masters' Macroscale And Microscale Organic Experiments, 7th
7th Edition
ISBN: 9781305884168
Author: Williamson, Kenneth L.; Masters, Katherine M.
Publisher: Cengage Learning
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Textbook Question
Chapter 8, Problem 10Q
A TLC plate showed two spots with
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Complete boxes in the flow chart. Draw the structure of the organic compound foundin each layer after adding 3M NaOH and extraction. Make sure to include any charges. Provide explanation on answers.
==
Vid4Q2
Unanswered
☑
Provide IUPAC name of product in the reaction
below
A 3,4-dimethylcyclohexene
B 1,2-dimethylcyclohexane
C 1,2-dimethylcyclohexene
D 3,4-dimethylcyclohexane
H₂
Pd
5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
Chapter 8 Solutions
Owlv2 With Labskills, 4 Terms (24 Months) Printed Access Card For Williamson/masters' Macroscale And Microscale Organic Experiments, 7th
Ch. 8 - Prob. 1QCh. 8 - Prob. 2QCh. 8 - What problem will ensue if the level of the...Ch. 8 - Prob. 4QCh. 8 - Prob. 5QCh. 8 - Arrange the following in order of increasing Rf...Ch. 8 - What will be the result of applying too much...Ch. 8 - Prob. 8QCh. 8 - Prob. 9QCh. 8 - A TLC plate showed two spots with Rf values of...
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- Nonearrow_forwardStereochemistry: Three possible answers- diastereomers, enantiomers OH CH₂OH I -c=0 21108 1101 41745 HOR CH₂OH IL Но CH₂OH TIL a. Compounds I and III have this relationship with each other: enantiomers b. Compounds II and IV have this relationship with each other: c. Compounds I and II have this relationship with each other: d. *Draw one structure that is a stereoisomer of II, but neither a diastereomer nor an enantiomer. (more than one correct answer)arrow_forwardNonearrow_forward
- Don't used Ai solutionarrow_forwardIn mass spectrometry, alpha cleavages are common in molecules with heteroatoms. Draw the two daughter ions that would be observed in the mass spectrum resulting from an alpha cleavage of this molecule. + NH2 Q Draw Fragment with m/z of 72arrow_forwardDon't used Ai solution and don't used hand raitingarrow_forward
- If 3.8 moles of Ca2 are consumed in this reaction, how many grams of H2O are needed?If 3.8 moles of Ca2 are consumed in this reaction, how many grams of H2O are needed?arrow_forwardDon't used Ai solutionarrow_forwardWrite the systematic (IUPAC) name for each of the following organic molecules: F structure Br LL Br Br الحمد name ☐ ☐arrow_forward
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