(a) Interpretation: Using the average atomic masses, the number of atoms of the sample should be determined. 160, 000 amu of oxygen Concept Introduction: Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12 t h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Question

Q2: Ranking Acidity a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly explain the ranking. Use Table 2.2 as reference. Ha Нь HC H-N Ha OHe b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is more acidic? Explain. (Hint: use resonance structures to help) Name the functional groups on atenolol. H H-N atenolol Ν H-N OH Н

Answer 1

Question

Chapter 8, Problem 105AP

Interpretation Introduction

(a)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

160, 000 amu of oxygen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(b)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

8139.81 amu of nitrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(c)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

13, 490 amu of aluminium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(d)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

5040 amu of hydrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(e)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

367, 495.15 amu of sodium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

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Q2: Ranking Acidity a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly explain the ranking. Use Table 2.2 as reference. Ha Нь HC H-N Ha OHe b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is more acidic? Explain. (Hint: use resonance structures to help) Name the functional groups on atenolol. H H-N atenolol Ν H-N OH Н

Answer d, e, and f

If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1

Answer 2

Question

Chapter 8, Problem 105AP

Interpretation Introduction

(a)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

160, 000 amu of oxygen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(b)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

8139.81 amu of nitrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(c)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

13, 490 amu of aluminium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(d)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

5040 amu of hydrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(e)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

367, 495.15 amu of sodium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

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Answer 3

Question

Chapter 8, Problem 105AP

Interpretation Introduction

(a)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

160, 000 amu of oxygen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(b)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

8139.81 amu of nitrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(c)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

13, 490 amu of aluminium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(d)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

5040 amu of hydrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(e)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

367, 495.15 amu of sodium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

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Answer 4

Question

Chapter 8, Problem 105AP

Interpretation Introduction

(a)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

160, 000 amu of oxygen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(b)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

8139.81 amu of nitrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(c)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

13, 490 amu of aluminium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(d)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

5040 amu of hydrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(e)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

367, 495.15 amu of sodium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

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Answer 5

Chapter 8, Problem 105AP

Interpretation Introduction

(a)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

160, 000 amu of oxygen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(b)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

8139.81 amu of nitrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(c)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

13, 490 amu of aluminium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(d)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

5040 amu of hydrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Interpretation Introduction

(e)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

367, 495.15 amu of sodium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 6

Chapter 8, Problem 105AP

Interpretation Introduction

(a)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

160, 000 amu of oxygen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 7

Chapter 8, Problem 105AP

Interpretation Introduction

(a)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

160, 000 amu of oxygen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

8139.81 amu of nitrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

8139.81 amu of nitrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

13, 490 amu of aluminium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

13, 490 amu of aluminium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

5040 amu of hydrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

5040 amu of hydrogen

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 14

Interpretation Introduction

(e)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

367, 495.15 amu of sodium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 15

Interpretation Introduction

(e)

Interpretation:

Using the average atomic masses, the number of atoms of the sample should be determined.

367, 495.15 amu of sodium

Concept Introduction:

Atomic mass unit measures mass in an atomic scale, it is a standard unit for mass. Here, 1 amu is equal to the mass of either one proton or neutron and equals to 1 g/mol. Atomic mass unit is equal to 1/12^t^h of the mass of C-12 atom. For example, if average atomic mass of carbon is 12.01 thus, it is the mass of 1 carbon atom.

Answer 16

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Answer 17

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Answer 27

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Solution Summary: The author explains how the average atomic masses determine the number of atoms of the sample.

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