The compound that has zero dipole moment and higher boiling point. Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified. Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule. Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

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Answer 1

Question

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

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Answer 2

Question

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

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Answer 3

Question

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

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Answer 4

Question

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

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Answer 5

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

Answer 6

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

Answer 7

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

Answer 8

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

Answer 9

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

Answer 10

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

Answer 11

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7.3A - Prob. 7.1P Ch. 7.3A - Prob. 7.2P Ch. 7.3B - Draw five more compounds of formula C4H6NOC1.Ch. 7.3B - For each of the following molecular formulas,...Ch. 7.4 - Give the systematic (IUPAC) names of the following...Ch. 7.5B - The following names are all incorrect. Draw the...Ch. 7.5B - Prob. 7.8P Ch. 7.5B - a. How many stereogcmc double bonds are in...Ch. 7.6 - Teflon-coated frying pans routinely endure...Ch. 7.7B - Prob. 7.11P

Solution Summary: The author analyzes the structure of the compounds with dipole notations.

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