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Concept explainers
(a)
To determine: The number of hydrogen atoms in the hydrocarbon that has nine carbon atoms, three double bonds and one ring.
Interpretation: The number of hydrogen atoms in the hydrocarbon that has nine carbon atoms, three double bonds and one ring is to be calculated.
Concept introduction: The compounds that have double bonds or triple bonds are called unsaturated compounds.
(b)
To determine: The number of elements of unsaturation implied by the molecular formula
Interpretation: The number of elements of unsaturation implied by the molecular formula
Concept introduction: The compounds that have double bond or triple bond are called unsaturated compounds. Alkenes are the unsaturated compounds that have double number of hydrogen atoms than the number of carbon atoms.
(c)
To determine: The five structures of the compound that have the molecular formula
Interpretation: The five structures of the compound that have the molecular formula
Concept introduction: The structure of the compound is the graphic representation of the molecular formula that shows that the arrangement of the atoms in the compound.
The compounds having same molecular formula and different structural arrangement of the atoms are called isomers of that compound. Isomers are of two types; structural isomers and stereoisomer. The Structural isomers can be chain isomer, position isomer and
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Chapter 7 Solutions
Organic Chemistry, Books a la Carte Edition (9th Edition)
- An unknown salt, AB, has the following precipitation reaction:A+(aq) + B-(aq) ⇌ AB(s) the K value for this reaction is 4.50 x10-6. Draw a model that represents what will happen when 1.00 L each of 1.00 M solution of A+(aq) and 1.00M solution of B-(aq) are combined.arrow_forward5. a) Use the rules in Example 4.4 (p. 99) and calculate sizes of octahedral and tetrahedral cavities in titanium and in zirconium. Use values for atomic radii given in Fig. 9.1 (p.291). (3 points) b) Consider the formation of carbides (MC) of these metals. Which metal is able to accommodate carbon atoms better, and which cavities (octahedral or tetrahedral) would be better suited to accommodate C atoms into metal's lattice? (4 points)arrow_forward2. Read paragraph 3.4 in your textbook ("Chiral Molecules"), and explain if Cobalt(ethylenediamine) 33+ shown in previous problem is a chiral species. If yes, draw projections of both enantiomers as mirror images, analogous to mirror projections of hands (below). Mirror (4 points)arrow_forward
- 3. Borane (BH3) belongs to D3h point group. Consider the vibrational (stretching) modes possible for B-H bonds under D3h symmetry. Using the methods we used in class, construct the reducible representation I, and break it down into irreducible representations using the character table provided. Sketch those modes, indicate whether they are IR-active. (6 points) D3h E 2C3 3C2 σh 283 30% A₁' 1 1 1 1 1 1 x² + y², z² 1 -1 1 1 -1 R₂ E' 2 0 2 0 (x, y) (x² - y², xy) " A₁" 1 1 -1 A2" 1 -1 -1 1 Z E" 2 -1 0 -2 1 0 (Ry, Ry) (xz, yz)arrow_forward1. List all the symmetry elements, and assign the compounds to proper point groups: a) HCIBrC-BrCIH Cl Br H (2 points) H Br b) Pentacarbonylmanganese(I)bromide Br OEC-Mn-CEO 00- c) Phenazine (aromatic molecule, with delocalized bonding) 1 d) Cobalt(ethylenediamine)33+ (just the cation) 3+ H₂N H₂ .NH2 (CI)3 NH2 H2 H₂N. (2 points) (2 points) (2 points)arrow_forwardHello, I desperately need help figuring out 8-14; I also wanted to see if you would mind letting me know if I picked the right degree as my melting points on the two graphs. Please and thank you in advance! All the information is provided.arrow_forward
- The reaction: A + B ⇌ 2 C, can be represented by the equilibrium expression, KC =[C]2[A][B]=258 at 520K.When 1.00 M of C was allowed to reach equilibrium and 0.055 M of A was formed. If this reaction wasperformed at the same temperature using 0.500 M C, what would the equilibrium concentration of Abe?arrow_forward1. What is the functional group of an alcohol and a phenol? 2. Why are some alcohols soluble in water? 3. Classify each of the following alcohols as primary, secondary or tertiary. a. 3-pentanol b. 2-methyl-2-butanol c. 1-propanolarrow_forwardI need help with B2 using the information in B1. This is for my lab notebook, and I got confused on number 2. Please help.arrow_forward
- 4. Aluminum has a face-centered cubic structure. The unit cell length is 4.05Å. Calculate the radius of Al atom in the metal. (5 points).arrow_forwardHF and HNO2 are both considered weak acids. Given the following K values for their dissociationequations, which is the weaker of these two weak acids?HF (aq) ⇌ H+(aq) + F –(aq) K=6.6 x10-4 HNO2 (aq) ⇌ H+(aq) + NO2–(aq) K=7.2 X 10-4arrow_forwardThe equilibrium constant for this reaction is 5.88 x 104. If concentration of the lead ion is 5.24 M, whatis the concentration of the chloride ion?Pb2+(aq) + 2 Cl- (aq) ⇌ PbCl2(s)arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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