Organic Chemistry As a Second Language: Second Semester Topics
4th Edition
ISBN: 9781119110651
Author: David R. Klein
Publisher: WILEY
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Chapter 7.7, Problem 7.60P
Interpretation Introduction
Interpretation:
Efficient synthesis has to be proposed for the given transformation.
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1. Starting with the molecules shown below, perform three different sequential synthetic steps, showing
the reagent (above the arrow) and the product (after the arrow) for each step. You may use any other
molecules or reagents that you desire. Note that each reaction must be performed on the product of the
prior step, and each product must be a stable, neutral, organic molecule. Work-up / protonation of
anions / addition of water does NOT count as a reaction step (but you are welcome to show it). You are
allowed to use more than one reagent in step, but if you do, the sequence of use must be numbered. If
Example:
1) CH3MgBr
OH
РСС
1) LDA
H.
2) H20
CH2CI2
2) EtCI
Complete:
HO
Perform the following syntheses. Use the retrosynthetic analysis shown in the example. Be
certain to show all of your reasoning which leads to your final answer. Both can be accomplished
in 2-3 steps. Show all reagents and intermediate products. All reactions necessary to complete
these syntheses can be found in Chapters 6, 7, and 9. Also, look at the reactions in Part I.
Remember, start from the target product and go one-step back to get started.
CI
HC=C
Design a synthesis for the following compound.
Chapter 7 Solutions
Organic Chemistry As a Second Language: Second Semester Topics
Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Propose a plausible mechanism for each of the...Ch. 7.3 - Predict the major product in each of the following...Ch. 7.3 - Predict the major product in each of the following...Ch. 7.3 - Predict the major product in each of the following...Ch. 7.3 - Predict the major product in each of the following...Ch. 7.3 - Predict the major product in each of the following...
Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.3 - Identify the reagents you would use to achieve...Ch. 7.4 - Predict the major products for each of the...Ch. 7.4 - Predict the major products for each of the...Ch. 7.4 - Predict the major products for each of the...Ch. 7.5 - Prob. 7.23PCh. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - Identify the reagents you would use to make each...Ch. 7.5 - In the space provided, draw a mechanism for each...Ch. 7.5 - In the space provided, draw a mechanism for each...Ch. 7.5 - Prob. 7.33PCh. 7.5 - Prob. 7.34PCh. 7.5 - Prob. 7.35PCh. 7.5 - Prob. 7.36PCh. 7.6 - Based on everything we have just seen, propose a...Ch. 7.6 - Prob. 7.39PCh. 7.6 - Prob. 7.40PCh. 7.6 - Prob. 7.41PCh. 7.6 - Propose a mechanism for the following reaction:Ch. 7.6 - Prob. 7.44PCh. 7.6 - Prob. 7.45PCh. 7.6 - Prob. 7.46PCh. 7.7 - Prob. 7.48PCh. 7.7 - Prob. 7.49PCh. 7.7 - Prob. 7.50PCh. 7.7 - Prob. 7.51PCh. 7.7 - Prob. 7.52PCh. 7.7 - Prob. 7.53PCh. 7.7 - Prob. 7.55PCh. 7.7 - Prob. 7.56PCh. 7.7 - Prob. 7.57PCh. 7.7 - Prob. 7.58PCh. 7.7 - Prob. 7.59PCh. 7.7 - Prob. 7.60PCh. 7.7 - Prob. 7.61PCh. 7.7 - Prob. 7.62PCh. 7.7 - Prob. 7.63PCh. 7.7 - Prob. 7.64PCh. 7.7 - Prob. 7.65P
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