General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Question
Chapter 7.7, Problem 7.11P
Interpretation Introduction
(a)
Interpretation:
The compound having higher melting point from the given option should be predicted.
Concept Introduction:
The melting point is defined as a temperature required to convert a solid
Interpretation Introduction
(b)
Interpretation:
The compound having higher melting point from the given option should be predicted.
Concept Introduction:
The temperature at which a substance present in solid state starts converting into liquid form (i.e. starts melting) is termed as melting point.
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Students have asked these similar questions
5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 7 Solutions
General, Organic, and Biological Chemistry - 4th edition
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Ch. 7.4 - Prob. 7.7PPCh. 7.4 - Prob. 7.5PCh. 7.5 - Prob. 7.8PPCh. 7.5 - Prob. 7.6PCh. 7.6 - CO2 was added to a cylinder containing 2.5 atm of...Ch. 7.6 - Prob. 7.10PPCh. 7.6 - Prob. 7.7PCh. 7.7 - Prob. 7.8PCh. 7.7 - Prob. 7.9PCh. 7.7 - Prob. 7.11PPCh. 7.7 - Which species in each pair has stronger...Ch. 7.7 - Prob. 7.12PPCh. 7.7 - Prob. 7.11PCh. 7.8 - Prob. 7.13PPCh. 7.8 - Would you predict the surface tension of gasoline,...Ch. 7.9 - Prob. 7.13PCh. 7.10 - Prob. 7.14PPCh. 7.10 - The human body is composed of about 70% water. How...Ch. 7.10 - How much energy is required to heat 28.0 g of iron...Ch. 7.10 - Prob. 7.15PCh. 7.10 - Prob. 7.16PPCh. 7.10 - If the initial temperature of 120. g of ethanol is...Ch. 7.11 - Use the heat of fusion of water from Sample...Ch. 7.11 - Answer the following questions about water, which...Ch. 7.11 - Prob. 7.19PPCh. 7.12 - Answer the following questions about the graph...Ch. 7.12 - How much energy (in calories) is released when...Ch. 7.12 - How much energy (in calories) is required to melt...Ch. 7 - Prob. 19PCh. 7 - Prob. 20PCh. 7 - Prob. 21PCh. 7 - The compressed air tank of a scuba diver reads...Ch. 7 - Assume that each of the following samples is at...Ch. 7 - Use the diagrams in problem 7.23 to answer the...Ch. 7 - Prob. 25PCh. 7 - Prob. 26PCh. 7 - Prob. 27PCh. 7 - Prob. 28PCh. 7 - Prob. 29PCh. 7 - Prob. 30PCh. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - If you pack a bag of potato chips for a snack on a...Ch. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - Prob. 39PCh. 7 - Prob. 40PCh. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Prob. 46PCh. 7 - Prob. 47PCh. 7 - Consider balloons A and B, which contain CH4 and...Ch. 7 - Prob. 49PCh. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Prob. 59PCh. 7 - Prob. 60PCh. 7 - Prob. 61PCh. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Prob. 64PCh. 7 - Which molecules are capable of intermolecular...Ch. 7 - Prob. 66PCh. 7 - Prob. 67PCh. 7 - Explain why the boiling point of A is higher than...Ch. 7 - Prob. 69PCh. 7 - Prob. 70PCh. 7 - Prob. 71PCh. 7 - Prob. 72PCh. 7 - Prob. 73PCh. 7 - Prob. 74PCh. 7 - Prob. 75PCh. 7 - Prob. 76PCh. 7 - Prob. 77PCh. 7 - Prob. 78PCh. 7 - Prob. 79PCh. 7 - Prob. 80PCh. 7 - Prob. 81PCh. 7 - How many calories of heat are needed to increase...Ch. 7 - Prob. 83PCh. 7 - If it takes 37.0 cal of heat to raise the...Ch. 7 - Prob. 85PCh. 7 - What phase change is shown in the accompanying...Ch. 7 - Prob. 87PCh. 7 - Which process requires more energy, melting 250 g...Ch. 7 - Consider the cooling curve drawn below a. Which...Ch. 7 - Prob. 90PCh. 7 - Draw the heating curve that is observed when...Ch. 7 - Prob. 92PCh. 7 - Use the following values to answer each part. The...Ch. 7 - Prob. 94PCh. 7 - Prob. 95PCh. 7 - Prob. 96PCh. 7 - Prob. 97PCh. 7 - Explain why you feel cool when you get out of a...Ch. 7 - Prob. 99CPCh. 7 - As we learned in Chapter 5, an automobile airbag...
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