General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Question
Chapter 7, Problem 67P
Interpretation Introduction
Interpretation:
Whether 2 formaldehyde molecules can have intermolecular hydrogen bonding or not needs to be explained.
Concept introduction:
The intermolecular force is defined as the force which occurs between the one molecule to another as attraction. Hydrogen bond - this type of intermolecular force exists in that molecule in which the hydrogen atom is covalently bonded with the atom with high electro negativity and it has strong intermolecular attraction.
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
O
HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 7 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 7.1 - Prob. 7.1PCh. 7.2 - Convert each pressure unit to the indicated unit....Ch. 7.3 - Prob. 7.2PPCh. 7.3 - Prob. 7.2PCh. 7.3 - Prob. 7.3PPCh. 7.3 - Prob. 7.3PCh. 7.3 - Prob. 7.4PPCh. 7.3 - Prob. 7.4PCh. 7.3 - The pressure inside a 1.0-L balloon at 25C was 750...Ch. 7.4 - A sample of nitrogen gas contains 5.0 mol in a...
Ch. 7.4 - Prob. 7.7PPCh. 7.4 - Prob. 7.5PCh. 7.5 - Prob. 7.8PPCh. 7.5 - Prob. 7.6PCh. 7.6 - CO2 was added to a cylinder containing 2.5 atm of...Ch. 7.6 - Prob. 7.10PPCh. 7.6 - Prob. 7.7PCh. 7.7 - Prob. 7.8PCh. 7.7 - Prob. 7.9PCh. 7.7 - Prob. 7.11PPCh. 7.7 - Which species in each pair has stronger...Ch. 7.7 - Prob. 7.12PPCh. 7.7 - Prob. 7.11PCh. 7.8 - Prob. 7.13PPCh. 7.8 - Would you predict the surface tension of gasoline,...Ch. 7.9 - Prob. 7.13PCh. 7.10 - Prob. 7.14PPCh. 7.10 - The human body is composed of about 70% water. How...Ch. 7.10 - How much energy is required to heat 28.0 g of iron...Ch. 7.10 - Prob. 7.15PCh. 7.10 - Prob. 7.16PPCh. 7.10 - If the initial temperature of 120. g of ethanol is...Ch. 7.11 - Use the heat of fusion of water from Sample...Ch. 7.11 - Answer the following questions about water, which...Ch. 7.11 - Prob. 7.19PPCh. 7.12 - Answer the following questions about the graph...Ch. 7.12 - How much energy (in calories) is released when...Ch. 7.12 - How much energy (in calories) is required to melt...Ch. 7 - Prob. 19PCh. 7 - Prob. 20PCh. 7 - Prob. 21PCh. 7 - The compressed air tank of a scuba diver reads...Ch. 7 - Assume that each of the following samples is at...Ch. 7 - Use the diagrams in problem 7.23 to answer the...Ch. 7 - Prob. 25PCh. 7 - Prob. 26PCh. 7 - Prob. 27PCh. 7 - Prob. 28PCh. 7 - Prob. 29PCh. 7 - Prob. 30PCh. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - If you pack a bag of potato chips for a snack on a...Ch. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - Prob. 39PCh. 7 - Prob. 40PCh. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Prob. 46PCh. 7 - Prob. 47PCh. 7 - Consider balloons A and B, which contain CH4 and...Ch. 7 - Prob. 49PCh. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Prob. 59PCh. 7 - Prob. 60PCh. 7 - Prob. 61PCh. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Prob. 64PCh. 7 - Which molecules are capable of intermolecular...Ch. 7 - Prob. 66PCh. 7 - Prob. 67PCh. 7 - Explain why the boiling point of A is higher than...Ch. 7 - Prob. 69PCh. 7 - Prob. 70PCh. 7 - Prob. 71PCh. 7 - Prob. 72PCh. 7 - Prob. 73PCh. 7 - Prob. 74PCh. 7 - Prob. 75PCh. 7 - Prob. 76PCh. 7 - Prob. 77PCh. 7 - Prob. 78PCh. 7 - Prob. 79PCh. 7 - Prob. 80PCh. 7 - Prob. 81PCh. 7 - How many calories of heat are needed to increase...Ch. 7 - Prob. 83PCh. 7 - If it takes 37.0 cal of heat to raise the...Ch. 7 - Prob. 85PCh. 7 - What phase change is shown in the accompanying...Ch. 7 - Prob. 87PCh. 7 - Which process requires more energy, melting 250 g...Ch. 7 - Consider the cooling curve drawn below a. Which...Ch. 7 - Prob. 90PCh. 7 - Draw the heating curve that is observed when...Ch. 7 - Prob. 92PCh. 7 - Use the following values to answer each part. The...Ch. 7 - Prob. 94PCh. 7 - Prob. 95PCh. 7 - Prob. 96PCh. 7 - Prob. 97PCh. 7 - Explain why you feel cool when you get out of a...Ch. 7 - Prob. 99CPCh. 7 - As we learned in Chapter 5, an automobile airbag...
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