Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180 0 . Concept Introduction : If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

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Answer 1

Question

Chapter 7.6, Problem 3E

Interpretation Introduction

Interpretation:

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180⁰.

Concept Introduction :

If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you manipulated and exploited the acid-base chemistry of one or more of the compounds in your mixture to facilitate their separation into different phases. The key to understanding how liquid- liquid extractions work is by knowing which layer a compound is in, and in what protonation state. The following liquid-liquid extraction is different from the one you performed in Experiment 4, but it uses the same type of logic. Your task is to show how to separate apart Compound A and Compound B. . Complete the following flowchart of a liquid-liquid extraction. Handwritten work is encouraged. • Draw by hand (neatly) only the appropriate organic compound(s) in the boxes. . Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4 and 5. • Box 7a requires the solvent (name is fine). • Box 7b requires one inorganic compound. • You can neatly complete this assignment by hand and…

b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;' The compound has the ff electronic transitions: 0%o* and no a* 1H NMR Spectrum (CDCl3, 400 MHz) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm 13C{H} NMR Spectrum (CDCl3, 100 MHz) Solvent 80 70 60 50 40 30 20 10 0 ppm ppm ¹H-13C me-HSQC Spectrum ppm (CDCl3, 400 MHz) 5 ¹H-¹H COSY Spectrum (CDCl3, 400 MHz) 0.5 10 3.5 3.0 2.5 2.0 1.5 1.0 10 15 20 20 25 30 30 -35 -1.0 1.5 -2.0 -2.5 3.0 -3.5 0.5 ppm 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm

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Answer 2

Question

Chapter 7.6, Problem 3E

Interpretation Introduction

Interpretation:

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180⁰.

Concept Introduction :

If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

Expert Solution & Answer

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Answer 3

Question

Chapter 7.6, Problem 3E

Interpretation Introduction

Interpretation:

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180⁰.

Concept Introduction :

If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Chapter 7.6, Problem 3E

Interpretation Introduction

Interpretation:

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180⁰.

Concept Introduction :

If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 5

Chapter 7.6, Problem 3E

Interpretation Introduction

Interpretation:

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180⁰.

Concept Introduction :

If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

Answer 6

Chapter 7.6, Problem 3E

Interpretation Introduction

Interpretation:

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180⁰.

Concept Introduction :

If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

Answer 7

Chapter 7.6, Problem 3E

Interpretation Introduction

Interpretation:

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180⁰.

Concept Introduction :

If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 7.2 - Prob. 1E Ch. 7.2 - Prob. 2E Ch. 7.2 - Prob. 3E Ch. 7.2 - Prob. 4E Ch. 7.2 - Prob. 5E Ch. 7.2 - Prob. 6E Ch. 7.2 - Prob. 7E Ch. 7.2 - Prob. 8E Ch. 7.2 - Prob. 9E Ch. 7.2 - Prob. 10E

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180 0 . Concept Introduction : If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

Solution Summary: The author explains that if a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution.

Interpretation:

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180⁰.

Concept Introduction :

If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

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Chapter 7 Solutions

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180 0 . Concept Introduction : If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

Solution Summary: The author explains that if a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution.

Interpretation: Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 1800. Concept Introduction : If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.

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Chapter 7 Solutions

Interpretation:

Whether the rotation is (+) or (-) needs to be determined if the observed rotation is 180⁰.

Concept Introduction :

If a solution is capable of rotating the plane of polarized light, it is said to be an optical active solution and this capability is known as an optical activity.