Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Question
Chapter 7.3, Problem 7E
Interpretation Introduction
Interpretation:
Whether the given isomers are diastereoisomers or enantiomers needs to be determined.
Concept Introduction :
The stereoisomers having different configurations at all stereocenters are known as enantiomers of each other and if there is a different configuration at only one stereocenter but same at other and both isomers are a non-mirror image of each other, and they will be diastereomers.
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1. In the structure provided choose the option YES or NO to indicate if the carbon atoms are chiral.
H
2. Assign the absolute configuration of the asymmetric/chiral centers in the provided structures a, b
and c.
a.
a.
C-H
HO-CH3
H
b.
NH₂
3. For the following two structures compared in parts A and B, determine whether they
are enantiomers OR diastereomers OR the same structure drawn differently (non-bonding
electrons not included for clarity).
d.
Br
Br
OH
door
OH
Br
b.
CH3
HC OH
H-C
O
Br
$R=
C.
OH
Br Br
OH
Br
1
Consider the following molecules. Which of the following statements is correct?
OH
II
OH
но..
Question 6 options:
。 I and II are enantiomers
。
о
I and III are enantiomers
II and IV are diastereomers
o III and IV are enantiomers
...
III
IV
3B. and 3G
Chapter 7 Solutions
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Ch. 7.2 - Prob. 1ECh. 7.2 - Prob. 2ECh. 7.2 - Prob. 3ECh. 7.2 - Prob. 4ECh. 7.2 - Prob. 5ECh. 7.2 - Prob. 6ECh. 7.2 - Prob. 7ECh. 7.2 - Prob. 8ECh. 7.2 - Prob. 9ECh. 7.2 - Prob. 10E
Ch. 7.3 - Prob. 1ECh. 7.3 - Prob. 2ECh. 7.3 - Prob. 3ECh. 7.3 - Prob. 4ECh. 7.3 - Prob. 5ECh. 7.3 - Prob. 6ECh. 7.3 - Prob. 7ECh. 7.3 - Prob. 8ECh. 7.4 - Prob. 1ECh. 7.4 - Prob. 2ECh. 7.4 - Prob. 3ECh. 7.4 - Prob. 4ECh. 7.4 - Prob. 5ECh. 7.4 - Prob. 6ECh. 7.4 - Prob. 7ECh. 7.4 - Prob. 8ECh. 7.4 - Prob. 9ECh. 7.4 - Prob. 10ECh. 7.4 - Prob. 11ECh. 7.4 - Prob. 12ECh. 7.4 - Prob. 13ECh. 7.6 - Prob. 1ECh. 7.6 - Prob. 2ECh. 7.6 - Prob. 3ECh. 7.6 - Prob. 4ECh. 7.6 - Prob. 5ECh. 7.6 - Prob. 6ECh. 7.6 - Prob. 7ECh. 7.6 - Prob. 8ECh. 7.6 - Prob. 9ECh. 7.6 - Prob. 10E
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