Number of stereo centers in (+)-tartaric acid should be identified. Concept Introduction : Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

Question

As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G m

Answer 1

Question

Chapter 7.6, Problem 1E

(a)

Interpretation Introduction

Interpretation:

Number of stereo centers in (+)-tartaric acid should be identified.

Concept Introduction :

Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

(b)

Interpretation Introduction

Interpretation:

All possible stereo isomers of (+)-tartaric acid should be drawn by indicating the optical activity of the each structure while indicating pairs of them as enantiomers, diastereomers or meso compounds.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

Other stereoisomers of (+)-tartaric acid that can be used to resolve racemic 1-phenylethylamine should be identified.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

A possible advantage of using a different stereoisomer of (+)-tartaric acid to resolve racemic 1-phenylethylamine should be identified and the reason should be explained.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(e)

Interpretation Introduction

Interpretation:

Importance of the optical purity of the resolving compound should be identified and explained.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

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As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G m

Including activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.

give example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)

Answer 2

Question

Chapter 7.6, Problem 1E

(a)

Interpretation Introduction

Interpretation:

Number of stereo centers in (+)-tartaric acid should be identified.

Concept Introduction :

Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

(b)

Interpretation Introduction

Interpretation:

All possible stereo isomers of (+)-tartaric acid should be drawn by indicating the optical activity of the each structure while indicating pairs of them as enantiomers, diastereomers or meso compounds.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

Other stereoisomers of (+)-tartaric acid that can be used to resolve racemic 1-phenylethylamine should be identified.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

A possible advantage of using a different stereoisomer of (+)-tartaric acid to resolve racemic 1-phenylethylamine should be identified and the reason should be explained.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(e)

Interpretation Introduction

Interpretation:

Importance of the optical purity of the resolving compound should be identified and explained.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

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Answer 3

Question

Chapter 7.6, Problem 1E

(a)

Interpretation Introduction

Interpretation:

Number of stereo centers in (+)-tartaric acid should be identified.

Concept Introduction :

Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

(b)

Interpretation Introduction

Interpretation:

All possible stereo isomers of (+)-tartaric acid should be drawn by indicating the optical activity of the each structure while indicating pairs of them as enantiomers, diastereomers or meso compounds.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

Other stereoisomers of (+)-tartaric acid that can be used to resolve racemic 1-phenylethylamine should be identified.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

A possible advantage of using a different stereoisomer of (+)-tartaric acid to resolve racemic 1-phenylethylamine should be identified and the reason should be explained.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(e)

Interpretation Introduction

Interpretation:

Importance of the optical purity of the resolving compound should be identified and explained.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

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Answer 4

Question

Chapter 7.6, Problem 1E

(a)

Interpretation Introduction

Interpretation:

Number of stereo centers in (+)-tartaric acid should be identified.

Concept Introduction :

Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

(b)

Interpretation Introduction

Interpretation:

All possible stereo isomers of (+)-tartaric acid should be drawn by indicating the optical activity of the each structure while indicating pairs of them as enantiomers, diastereomers or meso compounds.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

Other stereoisomers of (+)-tartaric acid that can be used to resolve racemic 1-phenylethylamine should be identified.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

A possible advantage of using a different stereoisomer of (+)-tartaric acid to resolve racemic 1-phenylethylamine should be identified and the reason should be explained.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(e)

Interpretation Introduction

Interpretation:

Importance of the optical purity of the resolving compound should be identified and explained.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

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Answer 5

Chapter 7.6, Problem 1E

(a)

Interpretation Introduction

Interpretation:

Number of stereo centers in (+)-tartaric acid should be identified.

Concept Introduction :

Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

(b)

Interpretation Introduction

Interpretation:

All possible stereo isomers of (+)-tartaric acid should be drawn by indicating the optical activity of the each structure while indicating pairs of them as enantiomers, diastereomers or meso compounds.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(c)

Interpretation Introduction

Interpretation:

Other stereoisomers of (+)-tartaric acid that can be used to resolve racemic 1-phenylethylamine should be identified.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(d)

Interpretation Introduction

Interpretation:

A possible advantage of using a different stereoisomer of (+)-tartaric acid to resolve racemic 1-phenylethylamine should be identified and the reason should be explained.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

(e)

Interpretation Introduction

Interpretation:

Importance of the optical purity of the resolving compound should be identified and explained.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Answer 6

Chapter 7.6, Problem 1E

(a)

Interpretation Introduction

Interpretation:

Number of stereo centers in (+)-tartaric acid should be identified.

Concept Introduction :

Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

Answer 7

Chapter 7.6, Problem 1E

(a)

Interpretation Introduction

Interpretation:

Number of stereo centers in (+)-tartaric acid should be identified.

Concept Introduction :

Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

Answer 8

(b)

Interpretation Introduction

Interpretation:

All possible stereo isomers of (+)-tartaric acid should be drawn by indicating the optical activity of the each structure while indicating pairs of them as enantiomers, diastereomers or meso compounds.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation:

All possible stereo isomers of (+)-tartaric acid should be drawn by indicating the optical activity of the each structure while indicating pairs of them as enantiomers, diastereomers or meso compounds.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Other stereoisomers of (+)-tartaric acid that can be used to resolve racemic 1-phenylethylamine should be identified.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Other stereoisomers of (+)-tartaric acid that can be used to resolve racemic 1-phenylethylamine should be identified.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Answer 12

(d)

Interpretation Introduction

Interpretation:

A possible advantage of using a different stereoisomer of (+)-tartaric acid to resolve racemic 1-phenylethylamine should be identified and the reason should be explained.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Answer 13

(d)

Interpretation Introduction

Interpretation:

A possible advantage of using a different stereoisomer of (+)-tartaric acid to resolve racemic 1-phenylethylamine should be identified and the reason should be explained.

Concept Introduction :

Stereoisomers are the compounds that have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Importance of the optical purity of the resolving compound should be identified and explained.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Importance of the optical purity of the resolving compound should be identified and explained.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Answer 16

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Ch. 7.2 - Prob. 1E Ch. 7.2 - Prob. 2E Ch. 7.2 - Prob. 3E Ch. 7.2 - Prob. 4E Ch. 7.2 - Prob. 5E Ch. 7.2 - Prob. 6E Ch. 7.2 - Prob. 7E Ch. 7.2 - Prob. 8E Ch. 7.2 - Prob. 9E Ch. 7.2 - Prob. 10E

Number of stereo centers in (+)-tartaric acid should be identified. Concept Introduction : Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

Interpretation: Number of stereo centers in (+)-tartaric acid should be identified. Concept Introduction : Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

Interpretation: Importance of the optical purity of the resolving compound should be identified and explained. Concept Introduction : Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.

Chapter 7 Solutions

Interpretation:

Number of stereo centers in (+)-tartaric acid should be identified.

Concept Introduction :

Stereo centers are those carbon atoms which are attached to 4 different groups. They are also known as chiral centers.

Interpretation:

Importance of the optical purity of the resolving compound should be identified and explained.

Concept Introduction :

Stereoisomers are the compounds which have the same molecular formula but differ only with the partial arrangement of the atoms in the molecule.