Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 7.3, Problem 7.1CYU
(a) What element has the configuration 1s22s22p63s2ps?
(b) Using spdf notation and an orbital box diagram, show the electron configuration of phosphorus.
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22.7 Predict the monoalkylated products of the following reactions with benzene.
(a)
AlCl3
Ya
(b)
AlCl3
(c)
H3PO4
(d)
22.8 Think-Pair-Share
AICI3
The reaction below is a common electrophilic aromatic substitution.
SO3
H₂SO4
SO₂H
(a) Draw the reaction mechanism for this reaction using HSO,+ as the electrophile.
(b) Sketch the reaction coordinate diagram, where the product is lower in energy
than the starting reactant.
(c) Which step in the reaction mechanism is highest in energy? Explain.
(d) Which of the following reaction conditions could be used in an electrophilic aro-
matic substitution with benzene to provide substituted phenyl derivatives?
(i)
AICI3
HNO3
H₂SO4
K2Cr2O7
(iii)
H₂SO4
(iv) H₂PO₁
Is an acid-base reaction the only type of reaction that would cause leavening products to rise?
Chapter 7 Solutions
Chemistry & Chemical Reactivity
Ch. 7.3 - (a) What element has the configuration...Ch. 7.3 - Write one possible set of quantum numbers for the...Ch. 7.3 - Using the periodic table and without looking at...Ch. 7.4 - Prob. 7.4CYUCh. 7.5 - Without looking at the figures for the periodic...Ch. 7.6 - The most common oxidation state of a rare earth...Ch. 7.6 - Prob. 1.2ACPCh. 7.6 - Prob. 1.3ACPCh. 7.6 - Use the atomic radii of scandium, yttrium,...Ch. 7.6 - Prob. 1.5ACP
Ch. 7.6 - Prob. 1.6ACPCh. 7.6 - Give the electron configurations for iron and the...Ch. 7.6 - Prob. 2.2ACPCh. 7.6 - Prob. 2.3ACPCh. 7.6 - Prob. 2.4ACPCh. 7 - Write the electron configurations for P and CI...Ch. 7 - Write the electron configurations for Mg and Ar...Ch. 7 - Using spdf notation, write the electron...Ch. 7 - Using spdf notation, give the electron...Ch. 7 - Prob. 5PSCh. 7 - Prob. 6PSCh. 7 - Use noble gas and spdf notations to depict...Ch. 7 - The lanthanides, once called the rare earth...Ch. 7 - Prob. 9PSCh. 7 - Prob. 10PSCh. 7 - What is the maximum number of electrons that can...Ch. 7 - What is the maximum number of electrons that can...Ch. 7 - Depict the electron configuration for magnesium...Ch. 7 - Depict the electron configuration for phosphorus...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Prob. 17PSCh. 7 - Which of the following statements correctly...Ch. 7 - Prob. 19PSCh. 7 - Prob. 20PSCh. 7 - Using orbital box diagrams, depict an electron...Ch. 7 - Prob. 22PSCh. 7 - Prob. 23PSCh. 7 - Using orbital box diagrams and noble gas notation,...Ch. 7 - Manganese is found as MnO2 in deep ocean deposits....Ch. 7 - One compound found in alkaline batteries is NiOOH,...Ch. 7 - Prob. 27PSCh. 7 - Arrange the following elements in order of...Ch. 7 - Prob. 29PSCh. 7 - Prob. 30PSCh. 7 - Which of the following groups of elements is...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Compare the elements Na, Mg, O, and P. (a) Which...Ch. 7 - Compare the elements B. Al, C, and Si. (a) Which...Ch. 7 - Explain each answer briefly. (a) Place the...Ch. 7 - Explain each answer briefly. (a) Rank the...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Explain why the photoelectron spectra of hydrogen...Ch. 7 - Sketch the major features (number of peaks and...Ch. 7 - These questions are not designated as to type or...Ch. 7 - The deep blue color of sapphires comes from the...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Prob. 44GQCh. 7 - Prob. 45GQCh. 7 - Prob. 46GQCh. 7 - Which of the following is not an allowable set of...Ch. 7 - A possible excited state for the H atom has an...Ch. 7 - The magnet in the following photo is made from...Ch. 7 - Name the element corresponding to each...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Prob. 52GQCh. 7 - Answer the questions below about the elements A...Ch. 7 - Answer (he following questions about the elements...Ch. 7 - Which of the following ions are unlikely to be...Ch. 7 - Prob. 56GQCh. 7 - Answer each of the following questions: (a) Of the...Ch. 7 - Prob. 58GQCh. 7 - Prob. 59GQCh. 7 - Two elements in the second transition series (Y...Ch. 7 - Prob. 61GQCh. 7 - The configuration of an element is given here. (a)...Ch. 7 - Answer the questions below about the elements A...Ch. 7 - Answer the questions below concerning ground state...Ch. 7 - Nickel(II) formate [Ni(HCO2)2] is widely used as a...Ch. 7 - Spinets are solids with the general formula M2+...Ch. 7 - The following questions use concepts from this and...Ch. 7 - Which ions in the following list are not likely to...Ch. 7 - Answer the following questions about first...Ch. 7 - The ionization of the hydrogen atom can be...Ch. 7 - Compare the configurations below with two...Ch. 7 - Prob. 72SCQCh. 7 - Write electron configurations to show the first...Ch. 7 - Prob. 74SCQCh. 7 - (a) Explain why the sizes of atoms change when...Ch. 7 - Which of the following elements has the greatest...Ch. 7 - Prob. 77SCQCh. 7 - Prob. 78SCQCh. 7 - The energies of the orbitals in many elements have...Ch. 7 - The ionization energies for the removal of the...Ch. 7 - Using your knowledge of the trends in element...Ch. 7 - Prob. 82SCQCh. 7 - Prob. 83SCQCh. 7 - Prob. 84SCQCh. 7 - Thionyl chloride. SOCl2, is an important...Ch. 7 - Prob. 86SCQCh. 7 - Slaters rules are a way to estimate the effective...
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