Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 7.3, Problem 30PP
Calculate the mass, in grams, of N in each of the following:
a. 0.82 g of
b. 40.0 g of
c. 0.464 g of
d. 1.46 g of
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 7 Solutions
Basic Chemistry
Ch. 7.1 - What is a mole?Ch. 7.1 - What is Avogadro’s number?Ch. 7.1 - Calculate each of the following: a. number of C...Ch. 7.1 - Calculate each of the following: a. number of Li...Ch. 7.1 - Calculate each of the following quantities in 2.00...Ch. 7.1 - Calculate each of the following quantities in...Ch. 7.1 - Quinine, C20H24N2O2 , is a component of tonic...Ch. 7.1 - Aluminum sulfate, Al2(SO4)3 , is used in some...Ch. 7.1 - Naproxen is used to treat pain and inflammation...Ch. 7.1 - Benadryl is an over-the-counter drug used to treat...
Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, in 0.150 mol of each...Ch. 7.3 - Calculate the mass, in grams, in 2.28 mol of each...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in 25.0 g of each of...Ch. 7.3 - Calculate the number of moles in 4.00 g of each of...Ch. 7.3 - Calculate the mass, in grams, of C in each of the...Ch. 7.3 - Calculate the mass, in grams, of N in each of the...Ch. 7.3 - Propane gas, C3H8 , is used as a fuel for many...Ch. 7.3 - Allyl sulfide, (C3H5)2S , gives garlic, onions,...Ch. 7.3 - a. The compound MgSO4 , Epsom salts, is used to...Ch. 7.3 - Prob. 34PPCh. 7.3 - Prob. 35PPCh. 7.3 - Prob. 36PPCh. 7.4 - Calculate the mass percent composition of each of...Ch. 7.4 - Calculate the mass percent composition of each of...Ch. 7.4 - Prob. 39PPCh. 7.4 - Prob. 40PPCh. 7.4 - Prob. 41PPCh. 7.4 - Calculate the mass percent of S in each of the...Ch. 7.5 - Calculate the empirical formula for each of the...Ch. 7.5 - Calculate the empirical formula for each of the...Ch. 7.5 - Calculate the empirical formula for each of the...Ch. 7.5 - Calculate the empirical formula for each of the...Ch. 7.6 - Write the empirical formula for each of the...Ch. 7.6 - Prob. 48PPCh. 7.6 - The carbohydrate fructose found in honey and...Ch. 7.6 - Caffeine has an empirical formula of C4H5N2O . If...Ch. 7.6 - Prob. 51PPCh. 7.6 - Glyoxal, used in textiles; maleic acid, used to...Ch. 7.6 - Prob. 53PPCh. 7.6 - Prob. 54PPCh. 7.6 - Vanillic acid contains 57.14% C, 4.80% H, and...Ch. 7.6 - Lactic acid, the substance that builds up in...Ch. 7.6 - A sample of nicotine, a poisonous compound found...Ch. 7.6 - Adenine, a nitrogen-containing compound found in...Ch. 7.6 - Clavulanic acid has a molecular formula of C8H9NO5...Ch. 7.6 - Phenylpropanolamine (PPA) is used to treat urinary...Ch. 7 - The chapter sections to review are shown in...Ch. 7 - The chapter sections to review are shown in...Ch. 7 - The chapter sections to review are shown in...Ch. 7 - Prob. 64UTCCh. 7 - Prob. 65APPCh. 7 - Calculate the mass, in grams, of Cu in each of the...Ch. 7 - Prob. 67APPCh. 7 - Calculate the mass percent composition for each of...Ch. 7 - Prob. 69APPCh. 7 - Prob. 70APPCh. 7 - A mixture contains 0.250 mol of Mn2O3 and 20.0 g...Ch. 7 - A mixture contains 4.001023 molecules of PCl3 and...Ch. 7 - Prob. 73APPCh. 7 - Prob. 74APPCh. 7 - Prob. 75APPCh. 7 - Prob. 76APPCh. 7 - Prob. 77APPCh. 7 - Prob. 78APPCh. 7 - Calculate the molar mass for each of the...Ch. 7 - Calculate the molar mass for each of the...Ch. 7 - Aspirin, C9H8O4 , is used to reduce inflammation...Ch. 7 - Ammonium sulfate, (NH4)2SO4 , is used in...Ch. 7 - Prob. 83APPCh. 7 - Prob. 84APPCh. 7 - Oleic acid, a component of olive oil, is 76.54% C,...Ch. 7 - Prob. 86APPCh. 7 - Prob. 87CPCh. 7 - Prob. 88CPCh. 7 - Prob. 89CPCh. 7 - The following problems are related to the topics...Ch. 7 - For parts a to f, consider the loss of electrons...Ch. 7 - A sterling silver bracelet, which is 92.5% silver...Ch. 7 - Prob. 9CICh. 7 - The active ingredient in an antacid tablet is...Ch. 7 - Oseltamivir, C16H28N2O4 , is a drug that is used...Ch. 7 - Prob. 12CI
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
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- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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