Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134564586
Author: Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 7.2, Problem 7.14PP
Calculate the molar mass for each of the following:
a.
b.
c.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
17
171.0
21.6
172.0
17
181.0
1.3
183.0
197.0
100.0
198.0
200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 7 Solutions
Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
Ch. 7.1 - What is a mole?Ch. 7.1 - What is Avogadro’s number?Ch. 7.1 - Calculate each of the following: a. number of C...Ch. 7.1 - Calculate each of the following: a. number of Li...Ch. 7.1 - Calculate each of the following quantities in 200...Ch. 7.1 - Calculate each of the following quantities in...Ch. 7.1 - Quinine, C20H24N2O2 , is a component of tonic...Ch. 7.1 - Aluminum sulphate, Al2SO43 , is used in some...Ch. 7.1 - Naproxen, found in Aleve, is used to treat the...Ch. 7.1 - Benadryl is an over-the-counter drug used to treat...
Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, in 0.150 mole of...Ch. 7.3 - Calculate the mass, in grams, in 2.28 moles of...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in 25.0 g of each of...Ch. 7.3 - Calculate the number of moles in 4.00 g of each of...Ch. 7.3 - Chloroethane, C2H5Cl , is used to diagnose dead...Ch. 7.3 - Allyl sulfide, C3H52S , gives garlic, onions, and...Ch. 7.3 - a. The compound MgSO4 , Epsom salts, is used to...Ch. 7.3 - a. Cyclopropane, C3H6 , is an anesthetic given by...Ch. 7.3 - Dinitrogen oxide (or nitrous oxide), N2O , also...Ch. 7.3 - Chloroform, CHCl3 , was formerly used as an...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.5 - Prob. 7.41PPCh. 7.5 - Prob. 7.42PPCh. 7.5 - Prob. 7.43PPCh. 7.5 - Prob. 7.44PPCh. 7.6 - Prob. 7.45PPCh. 7.6 - Prob. 7.46PPCh. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - Prob. 7.49PPCh. 7.6 - Prob. 7.50PPCh. 7.6 - Prob. 7.51PPCh. 7.6 - Prob. 7.52PPCh. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - The chemical reaction of hydrogen with oxygen...Ch. 7.7 - Ammonia is produced by the chemical reaction of...Ch. 7.7 - Carbon disulfide and carbon monoxide are produced...Ch. 7.7 - In the acetylene torch, acetylene gas C2H2 burns...Ch. 7.8 - Sodium reacts with oxygen to produce sodium oxide....Ch. 7.8 - Nitrogen gas reacts with hydrogen gas to produce...Ch. 7.8 - Ammonia and oxygen react to form nitrogen and...Ch. 7.8 - Iron(III) oxide reacts with carbon to give iron...Ch. 7.8 - Nitrogen dioxide and water react to produce nitric...Ch. 7.8 - Calcium cyanamide, CaCN2 , reads with water to...Ch. 7.8 - When solid lead(II) sulfide reacts with oxygen...Ch. 7.8 - When the gases dihydrogen sulfide and oxygen...Ch. 7.9 - Prob. 7.67PPCh. 7.9 - a. What is measured by the heat of reaction? b. In...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - a. What is meant by the rate of a reaction? b. Why...Ch. 7.9 - a. How does a catalyst affect the activation...Ch. 7.9 - Prob. 7.75PPCh. 7.9 - How would each of the following change the rate of...Ch. 7.9 - a. During cellular respiration, aqueous C6H12O6...Ch. 7.9 - Fatty acids undergo reaction with oxygen gas and...Ch. 7 - Prob. 7.79UTCCh. 7 - Using the models of the molecules (black = C,...Ch. 7 - A dandruff shampoo contains dipyrithione,...Ch. 7 - Ibuprofen, an anti-inflammatory drug in Advil, has...Ch. 7 - Prob. 7.83UTCCh. 7 - Balance each of the following by adding...Ch. 7 - Prob. 7.85UTCCh. 7 - Prob. 7.86UTCCh. 7 - If blue spheres represent nitrogen atoms, purple...Ch. 7 - Prob. 7.88UTCCh. 7 - Prob. 7.89UTCCh. 7 - Prob. 7.90UTCCh. 7 - Calculate the molar mass for each of the...Ch. 7 - Calculate the molar mass for each of the...Ch. 7 - How many grams are in 0.150 mole of each of the...Ch. 7 - How many grams are in 2.25 moles of each of the...Ch. 7 - How many moles are in 25.0 g of each of the...Ch. 7 - How many moles are in 4.00 g of each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Prob. 7.99APPCh. 7 - Prob. 7.100APPCh. 7 - Identify each of the following as an oxidation or...Ch. 7 - Identify each of the following as an oxidation or...Ch. 7 - When ammonia NH3 gas reacts with fluorine gas, the...Ch. 7 - When nitrogen dioxide NO2 gas from car exhaust...Ch. 7 - Pentane gas, C5H12 undergoes combustion with...Ch. 7 - Prob. 7.106APPCh. 7 - Prob. 7.107APPCh. 7 - The equation for the formation of nitrogen oxide...Ch. 7 - Prob. 7.109CPCh. 7 - Prob. 7.110CPCh. 7 - Prob. 7.111CPCh. 7 - A toothpaste contains 0.240% by mass sodium...Ch. 7 - Prob. 7.113CPCh. 7 - Prob. 7.114CPCh. 7 - Prob. 7.115CPCh. 7 - Prob. 7.116CP
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- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
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