Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134564586
Author: Timberlake
Publisher: PEARSON
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Don't used hand raiting and don't used Ai solution
13.84. Chlorine atoms react with methane, forming HCI
and CH3. The rate constant for the reaction is
6.0 × 107 M¹ s¹ at 298 K. When the experiment
was run at three other temperatures, the following data
were collected:
T (K)
k (M-1 s-1)
303
6.5 × 107
308
7.0 × 107
313
7.5 x 107
a. Calculate the values of the activation energy and the
frequency factor for the reaction.
b. What is the value of the rate constant in the lower
stratosphere, where T = 218 K?
Chapter 7 Solutions
Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
Ch. 7.1 - What is a mole?Ch. 7.1 - What is Avogadro’s number?Ch. 7.1 - Calculate each of the following: a. number of C...Ch. 7.1 - Calculate each of the following: a. number of Li...Ch. 7.1 - Calculate each of the following quantities in 200...Ch. 7.1 - Calculate each of the following quantities in...Ch. 7.1 - Quinine, C20H24N2O2 , is a component of tonic...Ch. 7.1 - Aluminum sulphate, Al2SO43 , is used in some...Ch. 7.1 - Naproxen, found in Aleve, is used to treat the...Ch. 7.1 - Benadryl is an over-the-counter drug used to treat...
Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, in 0.150 mole of...Ch. 7.3 - Calculate the mass, in grams, in 2.28 moles of...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in 25.0 g of each of...Ch. 7.3 - Calculate the number of moles in 4.00 g of each of...Ch. 7.3 - Chloroethane, C2H5Cl , is used to diagnose dead...Ch. 7.3 - Allyl sulfide, C3H52S , gives garlic, onions, and...Ch. 7.3 - a. The compound MgSO4 , Epsom salts, is used to...Ch. 7.3 - a. Cyclopropane, C3H6 , is an anesthetic given by...Ch. 7.3 - Dinitrogen oxide (or nitrous oxide), N2O , also...Ch. 7.3 - Chloroform, CHCl3 , was formerly used as an...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.5 - Prob. 7.41PPCh. 7.5 - Prob. 7.42PPCh. 7.5 - Prob. 7.43PPCh. 7.5 - Prob. 7.44PPCh. 7.6 - Prob. 7.45PPCh. 7.6 - Prob. 7.46PPCh. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - Prob. 7.49PPCh. 7.6 - Prob. 7.50PPCh. 7.6 - Prob. 7.51PPCh. 7.6 - Prob. 7.52PPCh. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - The chemical reaction of hydrogen with oxygen...Ch. 7.7 - Ammonia is produced by the chemical reaction of...Ch. 7.7 - Carbon disulfide and carbon monoxide are produced...Ch. 7.7 - In the acetylene torch, acetylene gas C2H2 burns...Ch. 7.8 - Sodium reacts with oxygen to produce sodium oxide....Ch. 7.8 - Nitrogen gas reacts with hydrogen gas to produce...Ch. 7.8 - Ammonia and oxygen react to form nitrogen and...Ch. 7.8 - Iron(III) oxide reacts with carbon to give iron...Ch. 7.8 - Nitrogen dioxide and water react to produce nitric...Ch. 7.8 - Calcium cyanamide, CaCN2 , reads with water to...Ch. 7.8 - When solid lead(II) sulfide reacts with oxygen...Ch. 7.8 - When the gases dihydrogen sulfide and oxygen...Ch. 7.9 - Prob. 7.67PPCh. 7.9 - a. What is measured by the heat of reaction? b. In...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - a. What is meant by the rate of a reaction? b. Why...Ch. 7.9 - a. How does a catalyst affect the activation...Ch. 7.9 - Prob. 7.75PPCh. 7.9 - How would each of the following change the rate of...Ch. 7.9 - a. During cellular respiration, aqueous C6H12O6...Ch. 7.9 - Fatty acids undergo reaction with oxygen gas and...Ch. 7 - Prob. 7.79UTCCh. 7 - Using the models of the molecules (black = C,...Ch. 7 - A dandruff shampoo contains dipyrithione,...Ch. 7 - Ibuprofen, an anti-inflammatory drug in Advil, has...Ch. 7 - Prob. 7.83UTCCh. 7 - Balance each of the following by adding...Ch. 7 - Prob. 7.85UTCCh. 7 - Prob. 7.86UTCCh. 7 - If blue spheres represent nitrogen atoms, purple...Ch. 7 - Prob. 7.88UTCCh. 7 - Prob. 7.89UTCCh. 7 - Prob. 7.90UTCCh. 7 - Calculate the molar mass for each of the...Ch. 7 - Calculate the molar mass for each of the...Ch. 7 - How many grams are in 0.150 mole of each of the...Ch. 7 - How many grams are in 2.25 moles of each of the...Ch. 7 - How many moles are in 25.0 g of each of the...Ch. 7 - How many moles are in 4.00 g of each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Prob. 7.99APPCh. 7 - Prob. 7.100APPCh. 7 - Identify each of the following as an oxidation or...Ch. 7 - Identify each of the following as an oxidation or...Ch. 7 - When ammonia NH3 gas reacts with fluorine gas, the...Ch. 7 - When nitrogen dioxide NO2 gas from car exhaust...Ch. 7 - Pentane gas, C5H12 undergoes combustion with...Ch. 7 - Prob. 7.106APPCh. 7 - Prob. 7.107APPCh. 7 - The equation for the formation of nitrogen oxide...Ch. 7 - Prob. 7.109CPCh. 7 - Prob. 7.110CPCh. 7 - Prob. 7.111CPCh. 7 - A toothpaste contains 0.240% by mass sodium...Ch. 7 - Prob. 7.113CPCh. 7 - Prob. 7.114CPCh. 7 - Prob. 7.115CPCh. 7 - Prob. 7.116CP
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- My Organic Chemistry textbook says about the formation of cyclic hemiacetals, "Such intramolecular reactions to form five- and six-membered rings are faster than the corresponding intermolecular reactions. The two reacting functional groups, in this case OH and C=O, are held in close proximity, increasing the probability of reaction."According to the book, the formation of cyclic hemiacetals occurs in acidic conditions. So my question is whether the carbonyl group in this reaction reacts first with the end alcohol on the same molecule or with the ethylene glycol. And, given the explanation in the book, if it reacts first with ethylene glycol before its own end alcohol, why would it? I don't need to know the final answer. I need to know WHY it would not undergo an intermolecular reaction prior to reacting with the ethylene glycol if that is the case. Please do not use an AI answer.arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardHighlight in red each acidic location on the organic molecule at left. Highlight in blue each basic location on the organic molecule at right. Note for advanced students: we mean acidic or basic in the Brønsted-Lowry sense only. Cl N شیخ x Garrow_forward
- Q4: Draw the mirror image of the following molecules. Are the molecules chiral? C/ F LL CI CH3 CI CH3 0 CI CH3 CI CH3 CH3arrow_forwardComplete combustion of a 0.6250 g sample of the unknown crystal with excess O2 produced 1.8546 g of CO2 and 0.5243 g of H2O. A separate analysis of a 0.8500 g sample of the blue crystal was found to produce 0.0465 g NH3. The molar mass of the substance was found to be about 310 g/mol. What is the molecular formula of the unknown crystal?arrow_forward4. C6H100 5 I peak 3 2 PPM Integration values: 1.79ppm (2), 4.43ppm (1.33) Ipeakarrow_forward
- Nonearrow_forward3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…arrow_forwardA chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.arrow_forward
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