ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
6th Edition
ISBN: 9781260325294
Author: SMITH
Publisher: RENT MCG
Question
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Chapter 7.15, Problem 31P
Interpretation Introduction

(a)

Interpretation: The compound from the given pair that reacts faster in nucleophilic substitution is to be identified.

Concept introduction: Nucleophilic substitution reaction takes place by two mechanisms, SN1 and SN2. In SN1 mechanism, formation of carbocation takes place by removal of halide and then nucleophile attack on that carbocation. However in SN2 mechanism, removal of halide and attack of nucleophile takes place simultaneously. The presence of good leaving group increases the rate of both SN1 and SN2 reactions.

Interpretation Introduction

(b)

Interpretation: The compound form the given pair that reacts faster in nucleophilic substitution is to be identified.

Concept introduction: Nucleophilic substitution reaction takes place by two mechanisms, SN1 and SN2. In SN1 mechanism, formation of carbocation takes place by removal of halide and then nucleophile attack on that carbocation. However in SN2 mechanism, removal of halide and attack of nucleophile takes place simultaneously. The presence of good leaving group increases the rate of both SN1 and SN2 reactions.

Interpretation Introduction

(c)

Interpretation: The compound from the given pair that reacts faster in nucleophilic substitution is to be identified.

Concept introduction: Nucleophilic substitution reaction takes place by two mechanisms, SN1 and SN2. In SN1 mechanism, formation of carbocation takes place by removal of halide and then nucleophile attack on that carbocation. However in SN2 mechanism, removal of halide and attack of nucleophile takes place simultaneously. The presence of good leaving group increases the rate of both SN1 and SN2 reactions.

Interpretation Introduction

(d)

Interpretation: The compound from the given pair that reacts faster in nucleophilic substitution is to be identified.

Concept introduction: Nucleophilic substitution reaction takes place by two mechanisms, SN1 and SN2. In SN1 mechanism, formation of carbocation takes place by removal of halide and then nucleophile attack on that carbocation. However in SN2 mechanism, removal of halide and attack of nucleophile takes place simultaneously. The presence of good leaving group increases the rate of both SN1 and SN2 reactions.

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