ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
6th Edition
ISBN: 9781266633973
Author: SMITH
Publisher: MCG
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Chapter 7.12, Problem 23P

What happens to the rate of an S N 1 reaction under each of the following conditions?

a. [ RX ] is tripled, and [ Nu ] stays the same.

b. Both [ RX ] and [ Nu ] are tripled.

c. [ RX ] is halved, and [ Nu ] stays the same.

d. [ RX ] is halved, and [ Nu ] is doubled.

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1. The reaction shown below has a rate law equation of rate = k[PtL3X+]. What would happen to the rate if the concentration of both [PtL3X]+ and Y- are doubled?  A.There will be no change in the rate.  B.The rate will be halved. C.The rate will be doubled. D.The rate will be quadrupled.
The rate equation for the reaction of CH3CH2Br with −OH is: rate = k[CH3CH2Br][−OH]. What effect does the indicated concentration change have on the overall rate of the reaction? a. tripling the concentration of CH3CH2Br only b. tripling the concentration of −OH only c. tripling the concentration of both CH3CH2Br and −OH
Draw an energy diagram for each reaction. Label the axes, the starting material, product, transition state, ΔHo, and Ea. a. a concerted reaction with ΔHo = −80 kJ/mol and Ea = 16 kJ/mol a two-step reaction, A → B → C, in which the relative energy of the compounds is A < C < B, and the step A → B is rate-determining

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