(a) Interpretation: The change that occurs to the rate of an S N 2 reaction when [ RX ] is tripled and [ Nu − ] stays the same is to be predicted. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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Answer 1

Question

Chapter 7.11, Problem 18P

Interpretation Introduction

(a)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is tripled and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The change that occurs to the rate of an SN2 reaction when both [RX] and [Nu−] are tripled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] is doubled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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The rate equation for the reaction of CH3CH2Br with −OH is: rate = k[CH3CH2Br][−OH]. What effect does the indicated concentration change have on the overall rate of the reaction? a. tripling the concentration of CH3CH2Br only b. tripling the concentration of −OH only c. tripling the concentration of both CH3CH2Br and −OH

1. The reaction shown below has a rate law equation of rate = k[PtL3X+]. What would happen to the rate if the concentration of both [PtL3X]+ and Y- are doubled? A.There will be no change in the rate. B.The rate will be halved. C.The rate will be doubled. D.The rate will be quadrupled.

Draw an energy diagram for each reaction. Label the axes, the starting material, product, transition state, ΔHo, and Ea. a. a concerted reaction with ΔHo = −80 kJ/mol and Ea = 16 kJ/mol a two-step reaction, A → B → C, in which the relative energy of the compounds is A < C < B, and the step A → B is rate-determining

Answer 2

Question

Chapter 7.11, Problem 18P

Interpretation Introduction

(a)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is tripled and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The change that occurs to the rate of an SN2 reaction when both [RX] and [Nu−] are tripled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] is doubled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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Answer 3

Question

Chapter 7.11, Problem 18P

Interpretation Introduction

(a)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is tripled and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The change that occurs to the rate of an SN2 reaction when both [RX] and [Nu−] are tripled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] is doubled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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Answer 4

Question

Chapter 7.11, Problem 18P

Interpretation Introduction

(a)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is tripled and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The change that occurs to the rate of an SN2 reaction when both [RX] and [Nu−] are tripled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] is doubled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

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Answer 5

Chapter 7.11, Problem 18P

Interpretation Introduction

(a)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is tripled and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation: The change that occurs to the rate of an SN2 reaction when both [RX] and [Nu−] are tripled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] is doubled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 6

Chapter 7.11, Problem 18P

Interpretation Introduction

(a)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is tripled and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 7

Chapter 7.11, Problem 18P

Interpretation Introduction

(a)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is tripled and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation: The change that occurs to the rate of an SN2 reaction when both [RX] and [Nu−] are tripled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 9

Interpretation Introduction

(b)

Interpretation: The change that occurs to the rate of an SN2 reaction when both [RX] and [Nu−] are tripled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 10

Interpretation Introduction

(c)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 11

Interpretation Introduction

(c)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] stays the same is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 12

Interpretation Introduction

(d)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] is doubled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 13

Interpretation Introduction

(d)

Interpretation: The change that occurs to the rate of an SN2 reaction when [RX] is halved and [Nu−] is doubled is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as a nucleophile. In a nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking the electron deficient carbon atom.

Answer 14

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Answer 16

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Answer 17

Ch. 7.1 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7.2 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7.2 - Prob. 3P Ch. 7.3 - An sp3 hybridized CCl bond is more polar than an...Ch. 7.4 - Prob. 5P Ch. 7.6 - Prob. 6P Ch. 7.7 - Prob. 10P Ch. 7.8 - Prob. 15P Ch. 7.8 - Prob. 16P Ch. 7.8 - Prob. 17P

Solution Summary: The author explains the rate of a nucleophilic substitution reaction when the concentration of left[RXright] is tripled.

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