Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
12th Edition
ISBN: 9780321908445
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 7.1, Problem 7.2QAP
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Consider the reaction of 2-methylpropane with a halogen. With which halogen will the product be almost exclusively 2-halo-2-methylpropane? 1. F2 2. Cl2 3. Br2 4. I2
None
Chapter 7 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
Ch. 7.1 - What is a mole?Ch. 7.1 - What is Avogadro’s number?Ch. 7.1 - Calculate each of the following: a. number of C...Ch. 7.1 - Calculate each of the following: a. number of Li...Ch. 7.1 - Calculate each of the following quantities in 200...Ch. 7.1 - Calculate each of the following quantities in...Ch. 7.1 - Prob. 7.7QAPCh. 7.1 - Aluminum sulphate, Al2SO43 , is used in some...Ch. 7.2 - Prob. 7.9QAPCh. 7.2 - Prob. 7.10QAP
Ch. 7.2 - Prob. 7.11QAPCh. 7.2 - Prob. 7.12QAPCh. 7.2 - Prob. 7.13QAPCh. 7.2 - Prob. 7.14QAPCh. 7.2 - Prob. 7.15QAPCh. 7.2 - Prob. 7.16QAPCh. 7.2 - Prob. 7.17QAPCh. 7.2 - Prob. 7.18QAPCh. 7.2 - Prob. 7.19QAPCh. 7.2 - Prob. 7.20QAPCh. 7.2 - Prob. 7.21QAPCh. 7.2 - Prob. 7.22QAPCh. 7.2 - Prob. 7.23QAPCh. 7.2 - Prob. 7.24QAPCh. 7.2 - Prob. 7.25QAPCh. 7.2 - Prob. 7.26QAPCh. 7.3 - Determine whether each of the following chemical...Ch. 7.3 - Determine whether each of the following chemical...Ch. 7.3 - Balance each of the following chemical equations:...Ch. 7.3 - Balance each of the following chemical equations:...Ch. 7.3 - Balance each of the following chemical equations:...Ch. 7.3 - Balance each of the following chemical equations:...Ch. 7.4 - Prob. 7.33QAPCh. 7.4 - Prob. 7.34QAPCh. 7.4 - Prob. 7.35QAPCh. 7.4 - Prob. 7.36QAPCh. 7.4 - Prob. 7.37QAPCh. 7.4 - Prob. 7.38QAPCh. 7.5 - Prob. 7.39QAPCh. 7.5 - Prob. 7.40QAPCh. 7.5 - In each of the following, identify the reactant...Ch. 7.5 - In each of the following, identify the reactant...Ch. 7.5 - Prob. 7.43QAPCh. 7.5 - Prob. 7.44QAPCh. 7.5 - Prob. 7.45QAPCh. 7.5 - Prob. 7.46QAPCh. 7.6 - Write all of the mole—mole factors for each of the...Ch. 7.6 - Write all of the mole—mole factors for each of the...Ch. 7.6 - The chemical reaction of hydrogen with oxygen...Ch. 7.6 - Prob. 7.50QAPCh. 7.6 - Carbon disulfide and carbon monoxide are produced...Ch. 7.6 - Prob. 7.52QAPCh. 7.7 - Sodium reacts with oxygen to produce sodium oxide....Ch. 7.7 - Nitrogen gas reacts with hydrogen gas to produce...Ch. 7.7 - Ammonia and oxygen react to form nitrogen and...Ch. 7.7 - Iron(III) oxide reacts with carbon to give iron...Ch. 7.7 - Nitrogen dioxide and water react to produce nitric...Ch. 7.7 - Calcium cyanamide, CaCN2 , reads with water to...Ch. 7.7 - Prob. 7.59QAPCh. 7.7 - When the gases dihydrogen sulfide and oxygen...Ch. 7.8 - Prob. 7.61QAPCh. 7.8 - Prob. 7.62QAPCh. 7.8 - Classify each of the following as exothermic or...Ch. 7.8 - Classify each of the following as exothermic or...Ch. 7.8 - Classify each of the following as exothermic or...Ch. 7.8 - Classify each of the following as exothermic or...Ch. 7.8 - a. What is meant by the rate of a reaction? b. Why...Ch. 7.8 - a. How does a catalyst affect the activation...Ch. 7.8 - Prob. 7.69QAPCh. 7.8 - How would each of the following change the rate of...Ch. 7 - Prob. 7.71UTCCh. 7 - Using the models of the molecules (black = C,...Ch. 7 - A dandruff shampoo contains dipyrithione,...Ch. 7 - Ibuprofen, an anti-inflammatory drug in Advil, has...Ch. 7 - Prob. 7.75UTCCh. 7 - Balance each of the following by adding...Ch. 7 - Prob. 7.77UTCCh. 7 - Prob. 7.78UTCCh. 7 - If blue spheres represent nitrogen atoms, purple...Ch. 7 - Prob. 7.80UTCCh. 7 - Prob. 7.81UTCCh. 7 - Prob. 7.82UTCCh. 7 - Calculate the molar mass for each of the...Ch. 7 - Calculate the molar mass for each of the...Ch. 7 - How many grams are in 0.150 mole of each of the...Ch. 7 - How many grams are in 2.25 moles of each of the...Ch. 7 - How many moles are in 25.0 g of each of the...Ch. 7 - How many moles are in 4.00 g of each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Prob. 7.91AQAPCh. 7 - Prob. 7.92AQAPCh. 7 - Prob. 7.93AQAPCh. 7 - Prob. 7.94AQAPCh. 7 - Identify each of the following as an oxidation or...Ch. 7 - Prob. 7.96AQAPCh. 7 - When ammonia NH3 gas reacts with fluorine gas, the...Ch. 7 - When nitrogen dioxide NO2 gas from car exhaust...Ch. 7 - Pentane gas, C5H12 undergoes combustion with...Ch. 7 - Prob. 7.100AQAPCh. 7 - Prob. 7.101AQAPCh. 7 - The equation for the formation of nitrogen oxide...Ch. 7 - Prob. 7.103CQCh. 7 - Prob. 7.104CQCh. 7 - Prob. 7.105CQCh. 7 - A toothpaste contains 0.240% by mass sodium...Ch. 7 - Prob. 7.107CQCh. 7 - Prob. 7.108CQCh. 7 - Prob. 7.109CQCh. 7 - Prob. 7.110CQ
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- Nonearrow_forwardn Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward
- 2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forwardPart VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forward
- Part IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forward
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