Macroscale and Microscale Organic Experiments
Macroscale and Microscale Organic Experiments
7th Edition
ISBN: 9781305577190
Author: Kenneth L. Williamson, Katherine M. Masters
Publisher: Brooks Cole
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Chapter 7, Problem 9Q
Interpretation Introduction

Interpretation:

Equations that describe the extraction and isolation procedure of caffeine should be written.

Concept introduction:

Caffeine is a natural product found in tea leaves and coffee beans. It is a beneficial central nervous system stimulant.

Extraction of natural products like caffeine can be done using the appropriate choice of solvents. There are several techniques for extraction of caffeine. The commonly used method is liquid-liquid extraction that is carried out in the presence of water and dichloromethane as the solvents. The difference in densities of water and dichloromethane allow them to form separate layers in a separatory funnel and thus allows the effective separation and isolation of caffeine.

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A buffered solution containing dissolved aniline, CH,NH2, and aniline hydrochloride, CH, NH, Cl, has a pH of 5.41. Determine the concentration of CH, NH in the solution if the concentration of CH, NH, is 0.305 M. The pK of aniline is 9.13. [CHẠNH] = Calculate the change in pH of the solution, ApH, if 0.375 g NaOH is added to the buffer for a final volume of 1.40 L. Assume that any contribution of NaOH to the volume is negligible. ApH = M
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