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Chapter 7 Solutions
EBK INTRODUCTORY CHEMISTRY
- Lead(II) nitrate is added to four separate beakers that contain the following: aker 1 (sodium chloride) eaker 2 (sodium hydroxide) eaker 3 (sodium phosphate) eaker 4 (sodium sulfate) ter the addition of the lead(II) nitrate solution to each beaker, in which beaker(s) will a precipitate form? Use the general solubility rules given in Table 7.1 to guide you.arrow_forwardThe procedures and principles of qualitative analysis are coy cred in many introductory chemistry laboratory courses. In qualitative analysis, students learn to analyze mixtures of the common positive and negative ions, separating and confirming the presence of the particular ions in the mixture. One of the first steps in such an analysis is to treat the mixture with hydrochloric acid, which precipitates and removes silver ion, lead(II) ion, and mercury(I) ion from the aqueous mixture as the insoluble chloride salts. Write balanced net ionic equations for the precipitation reactions of these three cations with chloride ion.arrow_forwardSeparate samples of a solution of an unknown soluble ionic compound are treated with KCl, Na2SO4, and NaOH. A precipitate forms only when Na2SO4 is added. Which cations could be present in the unknown soluble ionic compound?arrow_forward
- ssume a highly magnified view of a solution of HCI that allows you to “see” the HCl. Draw this magnified view. If you dropped in a piece of magnesium, the magnesium would disappear, and hydrogen gas would he released. Represent this change using symbols for the elements, and write the balanced equation.arrow_forwardName the reagent, if any, that you would add to a solution of iron(lll) chloride to precipitate (a) iron(lll) hydroxide. (b) iron(lll) carbonate. (c) iron(lll) phosphate.arrow_forwardWhich compound or compounds in each of the following groups is (are) soluble in water? (a) BaSO4, Ba(NO3)2, BaCO3 (b) Na2SO4, NaClO4, NaCH3CO2 (c) AgBr, KBr, Al2Br6arrow_forward
- Polychlorinated biphenyls (PCBs) have been used extensively as dielectric materials in electrical transformers. Because PCBs have been shown to be potentially harmful, analysis for their presence in the environment has become very important. PCBs are manufactured according to the following generic reaction: C12H10+nCl2C12H10nCln.+nHCl This reaction results in a mixture of PCB products. The mixture is analyzed by decomposing the PCBs and then precipitating the resulting Cl asAgCl. a. Develop a general equation that relates the average value of n to the mass of a given mixture of PCBs and the mass of AgCl produced. b. A 0.1947-g sample of a commercial PCB yielded 0.4791 g of AgCl. What is the average value of n for this sample?arrow_forwardConsider the following generic equation OH(aq)+HB(aq) B(aq)+H2OFor which of the following pairs would this be the correct prototype equation for the acid-base reaction in solution? If it is not correct, write the proper equation for the acid-base reaction between the pair. (a) hydrochloric acid and pyridine, C5H5N (b) sulfuric acid and rubidium hydroxide (c) potassium hydroxide and hydrofluoric acid (d) ammonia and hydriodic acid (e) strontium hydroxide and hydrocyanic acidarrow_forwardAn aqueous sample is known to contain either Mg2+ or Ba2+ ions. Treatment of the sample with Na2CO3 produces a precipitate, but treatment with ammonium sulfate does not. Use the solubility rules (see Table 4.1) to determine which cation is present.arrow_forward
- 42. a. Fill in the following table as if it is a well plate and you are mixing two aqueous compounds at a time to see if a precipitate forms. If a precipitate is expected to form, indicate that by writing the correct formula for the precipitate in the corresponding box in the table. If no precipitate is expected to form, write “NO” in the box. CaCI2 Pb(NO3)2 (NH4)3PO4 Na2CO3 AgNO3 K2SO4 b. How do you prepare 300.0 mL of a 0.250 M CaCl2 solution using an available 2(X) M solution? Support your answer with calculations, but also make sure you describe how to prepare the solution.arrow_forwardThe reagent shelf in a general chemistry lab contains aqueous solutions of the following substances: silver nitrate, sodium chloride, acetic acid, nitric acid, sulfuric acid, potassium chromate, barium nitrate, phosphoric acid, hydrochloric acid, lead nitrate, sodium hydroxide, and sodium carbonate. Suggest how you might prepare the following pure substances using these reagents and any normal laboratory equipment. If it is not possible to prepare a substance using these reagents. indicate why. :math>BaCrO4(s) d. PbSO4(s) :math>NaC2H3O2(s)e. Na2SO4(s) msp;AgCl(s) f. i> BaCO3(s)arrow_forwardAn aqueous sample is known to contain either Ag+ or Mg2+ ions. Treatment of the sample with NaOH produces a precipitate, but treatment with KBr does not. Use the solubility rules (see Table 4.1) to determine which cation is present. TABLE 4.1 Solubility Rules for Ionic Compounds in Waterarrow_forward
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