
Concept explainers
Interpretation:
The de Broglie wavelength of an electron with kinetic energy
Concept introduction:
According to de-Broglie, just like light, matter also has a dual character as a wave and as a particle. The term wavicle was proposed for such a particle. However, matter waves are different from
The de Broglie equation to relate the wavelength of a moving particle with its mass and velocity is as follows:
Here,

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Chapter 7 Solutions
Chemistry: The Molecular Nature of Matter and Change
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- О The following figures represent distributions of gas molecules between two containers connected by an open tube. In which figure is the entropy of the system maximized? O O Oarrow_forwardGiven the following data, determine the rate constant, k, of the reaction H2(g) + 21C1(g) → 12(g) + 2HCl(g) = Experiment 1 2 3 1.65 × 10 5 torr ¹s -1 6.06 104 torr -1s-1 8.17 105 torr -1s-1 1.34 torr -1s-1 3.48103 torr -¹s−1 [H2] (torr) [ICI] (torr) Rate (torr/s) 250 325 1.34 250 81 0.331 50 325 0.266arrow_forwardPredict the temperature change produced by burning 3.55 g benzoic acid in a bomb calorimeter that has a heat capacity of 20.12 kJ/°C. The enthalpy of combustion of benzoic acid is −26.43 kJ/g.arrow_forward
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- In an experiment, 74.3 g of metallic copper was heated to 100.0°C and then quickly dropped into 200.0 mL of water in a calorimeter. The heat capacity of the calorimeter with the water was 875 J/°C. The initial temperature of the calorimeter was 27.5°C, and the final temperature after addition of the metal was 29.8°C. What is the value of the molar heat capacity of copper?arrow_forwardThe Haber-Bosch process permits the direct conversion of molecular nitrogen to ammonia, which can be used in large-scale fertilizer production. Given the balanced Haber-Bosch reaction and using the bond energies in the table below, estimate the enthalpy change associated with the reaction. N2(g) + 3H2(g) → 2NH3(g) Bond N=N N = N Energy (kJ/mol) 941 418 N-N H-H N-H 163 435 388arrow_forwardBenzoic acid is used to determine the heat capacity of bomb calorimeters because it can be obtained in pure form and its energy of combustion is known very accurately (−26.43 kJ/g). Determine the heat capacity of a calorimeter that had a temperature increase of 9.199°C when 3.500 g of benzoic acid was used.arrow_forward
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