Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry
2nd Edition
ISBN: 9780077633707
Author: Janice Smith
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 7, Problem 7.82AP
Interpretation Introduction
Interpretation:
The most concentrated and the least concentrated solutions have to be given.
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The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 7 Solutions
Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry
Ch. 7.1 - Classify each substance as a heterogeneous...Ch. 7.1 - Classify each product as a solution, colloid, or...Ch. 7.2 - Consider the following diagrams for an aqueous...Ch. 7.2 - Prob. 7.4PCh. 7.2 - Prob. 7.5PCh. 7.2 - Prob. 7.6PCh. 7.2 - Prob. 7.7PCh. 7.2 - If a solution contains 125 mEq of Na+ per liter,...Ch. 7.3 - Prob. 7.9PCh. 7.3 - Prob. 7.10P
Ch. 7.4 - Why does a soft drink become flat faster when it...Ch. 7.4 - Predict the effect each change has on the...Ch. 7.5 - Prob. 7.13PCh. 7.5 - Prob. 7.14PCh. 7.5 - Prob. 7.15PCh. 7.5 - A drink sold in a health food store contains 0.50%...Ch. 7.5 - Prob. 7.17PCh. 7.5 - Prob. 7.18PCh. 7.5 - Prob. 7.19PCh. 7.6 - Prob. 7.20PCh. 7.6 - Prob. 7.21PCh. 7.6 - Prob. 7.22PCh. 7.6 - Prob. 7.23PCh. 7.6 - Prob. 7.24PCh. 7.7 - Prob. 7.25PCh. 7.7 - Prob. 7.26PCh. 7.7 - Prob. 7.27PCh. 7.8 - Which solution in each pair exerts the greater...Ch. 7.8 - Describe the process that occurs when a 1.0 M NaCl...Ch. 7.8 - Prob. 7.30PCh. 7 - Prob. 7.31UKCCh. 7 - Prob. 7.32UKCCh. 7 - Prob. 7.33UKCCh. 7 - Prob. 7.34UKCCh. 7 - Prob. 7.35UKCCh. 7 - Prob. 7.36UKCCh. 7 - Prob. 7.37UKCCh. 7 - Prob. 7.38UKCCh. 7 - Prob. 7.41UKCCh. 7 - Prob. 7.42UKCCh. 7 - Prob. 7.43APCh. 7 - Prob. 7.44APCh. 7 - Prob. 7.45APCh. 7 - Prob. 7.46APCh. 7 - Prob. 7.47APCh. 7 - Prob. 7.48APCh. 7 - Prob. 7.49APCh. 7 - Prob. 7.50APCh. 7 - Prob. 7.51APCh. 7 - Prob. 7.52APCh. 7 - Prob. 7.53APCh. 7 - Prob. 7.54APCh. 7 - Prob. 7.55APCh. 7 - Prob. 7.56APCh. 7 - Prob. 7.57APCh. 7 - Prob. 7.58APCh. 7 - Prob. 7.59APCh. 7 - Prob. 7.60APCh. 7 - Prob. 7.61APCh. 7 - Prob. 7.62APCh. 7 - Prob. 7.63APCh. 7 - Prob. 7.64APCh. 7 - Prob. 7.65APCh. 7 - Prob. 7.66APCh. 7 - Prob. 7.67APCh. 7 - Prob. 7.68APCh. 7 - Prob. 7.69APCh. 7 - Prob. 7.70APCh. 7 - Prob. 7.71APCh. 7 - Prob. 7.72APCh. 7 - Prob. 7.73APCh. 7 - Prob. 7.74APCh. 7 - Prob. 7.75APCh. 7 - Prob. 7.76APCh. 7 - Prob. 7.77APCh. 7 - Prob. 7.78APCh. 7 - Prob. 7.79APCh. 7 - Prob. 7.80APCh. 7 - Prob. 7.81APCh. 7 - Prob. 7.82APCh. 7 - Prob. 7.83APCh. 7 - Prob. 7.84APCh. 7 - Prob. 7.85APCh. 7 - Prob. 7.86APCh. 7 - Prob. 7.87APCh. 7 - Prob. 7.88APCh. 7 - Prob. 7.89APCh. 7 - Prob. 7.90APCh. 7 - If the concentration of glucose in the blood is 90...Ch. 7 - Prob. 7.92APCh. 7 - Prob. 7.93APCh. 7 - Prob. 7.94APCh. 7 - Prob. 7.95APCh. 7 - Prob. 7.96APCh. 7 - Prob. 7.97APCh. 7 - Prob. 7.98APCh. 7 - Prob. 7.99APCh. 7 - Prob. 7.100APCh. 7 - Prob. 7.101APCh. 7 - Prob. 7.102APCh. 7 - Prob. 7.103CPCh. 7 - Prob. 7.104CP
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Similar questions
- a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here? b. What is the purpose of the Na2SO4? c. What equipment would you use to “concentrate [a solution] under reduced pressure”?arrow_forwardWhen N,N-dimethylaniline is treated with bromine both the ortho and para products are observed. However when treated with a mixture of nitric acid and sulfuric acid only the meta product is observed. Explain these results and support your answer with the appropriate drawings *Hint amines are bases* N HNO3 H2SO4 N NO2 N Br2 N Br + N 8-8-8 FeBr3 Brarrow_forwardDraw a mechanism that explains the formation of compound OMe SO3H 1. Fuming H2SO4arrow_forward
- Consider the following two acid-base reactions: OH OHI Based on what you know about the compounds and their acidity, which direction would you expect both of these reactions to proceed? Show your reasoning. A pKa table has been provided in case you need it. Functional group Example pka CHA -50 Alkane -35 Amine : NH3 Alkyne RH 25 Water HO-H 169 16 10 Protonated amines NH 10 5 Carboxylic acids OH Hydrochloric acid HCI A chemist intends to run the following reaction on the three substrates shown below: H₂O R-CI product room temp. Cl Cl (1) (2) (3) They find one will react quickly, one slowly, and one will not react at all. Which is which, and why? HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?arrow_forwardNH3 decomposes through an equilibrium reaction between NH3, H2, and N2. Only one of the options is correct:(A). The mechanism of the NH3 decomposition reaction must necessarily involve the collision of two NH3 molecules to induce a rearrangement of the atoms in this molecule.(B). The molecular weight of the NH3 decomposition reaction is 2 since two NH3 molecules must collide.(C). The rate of the NH3 decomposition reaction must be greater than that of NH3 synthesis, since the former requires two molecules to collide and the latter, four.(D). The NH3 decomposition reaction cannot occur in a single step.arrow_forwardGiven the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 lowarrow_forward
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- Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
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