(a) Interpretation: The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified. Concept introduction: Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

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Answer 1

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Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

Answer 2

Question

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

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Answer 3

Question

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

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Answer 4

Question

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

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Answer 5

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

Answer 6

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Answer 7

Chapter 7, Problem 7.69AP

Interpretation Introduction

(a)

Interpretation:

The predominant diastereomer generated from addition of HBr to 1- methylcyclohexene is to be identified.

Concept introduction:

Diasteromers are the type of molecules in which more than one stereo centre is present. When the stereochemistry of at least one carbon is changed but the stereochemistry of all the other carbon remains same, then the structures obtained are known as diastereomers.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason as to why the reaction occurs with an anti-stereochemistry is to be stated.

Concept introduction:

In a reaction, stereochemistry of the product depends upon the stability of the structure of the product. Free radical mechanism is the pathway in which odd electron species is generated as the reaction intermediate.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

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