(a) Interpretation: The chair conformation of the compound after 180 ° rotation about the given axis is to be drawn. Concept introduction: The conformation of cyclohexane is a type of 3 − D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis- configuration the two groups remains at the same side to each other.

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Answer 1

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Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis- configuration the two groups remains at the same side to each other.

Interpretation Introduction

(b)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis configuration the two groups remains at the same side to each other.

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A J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3

1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ

Answer 2

Question

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis- configuration the two groups remains at the same side to each other.

Interpretation Introduction

(b)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis configuration the two groups remains at the same side to each other.

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Answer 3

Question

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis- configuration the two groups remains at the same side to each other.

Interpretation Introduction

(b)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis configuration the two groups remains at the same side to each other.

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Answer 4

Question

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis- configuration the two groups remains at the same side to each other.

Interpretation Introduction

(b)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis configuration the two groups remains at the same side to each other.

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Answer 5

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis- configuration the two groups remains at the same side to each other.

Interpretation Introduction

(b)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis configuration the two groups remains at the same side to each other.

Answer 6

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis- configuration the two groups remains at the same side to each other.

Answer 7

Chapter 7, Problem 7.10P

Interpretation Introduction

(a)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis- configuration the two groups remains at the same side to each other.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis configuration the two groups remains at the same side to each other.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The chair conformation of the compound after 180° rotation about the given axis is to be drawn.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation. In cis configuration the two groups remains at the same side to each other.

Answer 10

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Answer 12

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Answer 13

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that the chair conformation of the compound after 180° rotation about the given axis is to be drawn.

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