A chair conformation for ( S ) -3-methylpiperidine showing the s p 3 orbital that contains the nitrogen unshared electron pair is to be drawn. The number of chair conformations of ( S ) -3-methylpiperidine that are in rapid equilibrium are to be predicted. Concept introduction: In a cyclohexane ring, the steric interactions that takes place between an axial substituent located on the carbon atom 1 and the hydrogen atoms located on carbon 3 and 5 is known as 1, 3 diaxial interaction. In the cyclohexane derivatives, each 1, 3-diaxial interaction between the methyl and hydrogen increases the enthalpy of the ring by 3.7 kJ mol − 1 .

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Answer 1

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Chapter 7, Problem 7.50AP

Interpretation Introduction

Interpretation:

A chair conformation for (S)-3-methylpiperidine showing the sp3 orbital that contains the nitrogen unshared electron pair is to be drawn. The number of chair conformations of (S)-3-methylpiperidine that are in rapid equilibrium are to be predicted.

Concept introduction:

In a cyclohexane ring, the steric interactions that takes place between an axial substituent located on the carbon atom 1 and the hydrogen atoms located on carbon 3 and 5 is known as 1, 3 diaxial interaction. In the cyclohexane derivatives, each 1, 3-diaxial interaction between the methyl and hydrogen increases the enthalpy of the ring by 3.7 kJ mol−1.

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Answer 2

Question

Chapter 7, Problem 7.50AP

Interpretation Introduction

Interpretation:

A chair conformation for (S)-3-methylpiperidine showing the sp3 orbital that contains the nitrogen unshared electron pair is to be drawn. The number of chair conformations of (S)-3-methylpiperidine that are in rapid equilibrium are to be predicted.

Concept introduction:

In a cyclohexane ring, the steric interactions that takes place between an axial substituent located on the carbon atom 1 and the hydrogen atoms located on carbon 3 and 5 is known as 1, 3 diaxial interaction. In the cyclohexane derivatives, each 1, 3-diaxial interaction between the methyl and hydrogen increases the enthalpy of the ring by 3.7 kJ mol−1.

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Answer 3

Question

Chapter 7, Problem 7.50AP

Interpretation Introduction

Interpretation:

A chair conformation for (S)-3-methylpiperidine showing the sp3 orbital that contains the nitrogen unshared electron pair is to be drawn. The number of chair conformations of (S)-3-methylpiperidine that are in rapid equilibrium are to be predicted.

Concept introduction:

In a cyclohexane ring, the steric interactions that takes place between an axial substituent located on the carbon atom 1 and the hydrogen atoms located on carbon 3 and 5 is known as 1, 3 diaxial interaction. In the cyclohexane derivatives, each 1, 3-diaxial interaction between the methyl and hydrogen increases the enthalpy of the ring by 3.7 kJ mol−1.

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Answer 4

Question

Chapter 7, Problem 7.50AP

Interpretation Introduction

Interpretation:

A chair conformation for (S)-3-methylpiperidine showing the sp3 orbital that contains the nitrogen unshared electron pair is to be drawn. The number of chair conformations of (S)-3-methylpiperidine that are in rapid equilibrium are to be predicted.

Concept introduction:

In a cyclohexane ring, the steric interactions that takes place between an axial substituent located on the carbon atom 1 and the hydrogen atoms located on carbon 3 and 5 is known as 1, 3 diaxial interaction. In the cyclohexane derivatives, each 1, 3-diaxial interaction between the methyl and hydrogen increases the enthalpy of the ring by 3.7 kJ mol−1.

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Answer 5

Chapter 7, Problem 7.50AP

Interpretation Introduction

Interpretation:

A chair conformation for (S)-3-methylpiperidine showing the sp3 orbital that contains the nitrogen unshared electron pair is to be drawn. The number of chair conformations of (S)-3-methylpiperidine that are in rapid equilibrium are to be predicted.

Concept introduction:

In a cyclohexane ring, the steric interactions that takes place between an axial substituent located on the carbon atom 1 and the hydrogen atoms located on carbon 3 and 5 is known as 1, 3 diaxial interaction. In the cyclohexane derivatives, each 1, 3-diaxial interaction between the methyl and hydrogen increases the enthalpy of the ring by 3.7 kJ mol−1.

Answer 6

Chapter 7, Problem 7.50AP

Interpretation Introduction

Interpretation:

A chair conformation for (S)-3-methylpiperidine showing the sp3 orbital that contains the nitrogen unshared electron pair is to be drawn. The number of chair conformations of (S)-3-methylpiperidine that are in rapid equilibrium are to be predicted.

Concept introduction:

In a cyclohexane ring, the steric interactions that takes place between an axial substituent located on the carbon atom 1 and the hydrogen atoms located on carbon 3 and 5 is known as 1, 3 diaxial interaction. In the cyclohexane derivatives, each 1, 3-diaxial interaction between the methyl and hydrogen increases the enthalpy of the ring by 3.7 kJ mol−1.

Answer 7

Chapter 7, Problem 7.50AP

Interpretation Introduction

Interpretation:

A chair conformation for (S)-3-methylpiperidine showing the sp3 orbital that contains the nitrogen unshared electron pair is to be drawn. The number of chair conformations of (S)-3-methylpiperidine that are in rapid equilibrium are to be predicted.

Concept introduction:

In a cyclohexane ring, the steric interactions that takes place between an axial substituent located on the carbon atom 1 and the hydrogen atoms located on carbon 3 and 5 is known as 1, 3 diaxial interaction. In the cyclohexane derivatives, each 1, 3-diaxial interaction between the methyl and hydrogen increases the enthalpy of the ring by 3.7 kJ mol−1.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

Solution Summary: The author explains the structure of (S)-3-methylpiperidine and the number of chair conformations that are in rapid equilibrium.

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