Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
11th Edition
ISBN: 9781305705159
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 7, Problem 7.65P
Interpretation Introduction
Interpretation:
Whether it would make any difference if we measure the rate of disappearance of reactants instead of the rate of appearance of the products in a
Concept introduction:
In a chemical reaction,
Rate of reaction = Rate of disappearance of the reactant (A) = Rate of appearance of the product (B).
Rate of reaction =
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 7 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 7.1 - Problem 7-1 In the reaction we measure the...Ch. 7.4 - Problem 7-2 Calculate the rate for the reaction in...Ch. 7.6 - Prob. 7.3PCh. 7.6 - Prob. 7.4PCh. 7.6 - Prob. 7.5PCh. 7.7 - Prob. 7.6PCh. 7.7 - Problem 7-7 Consider the following equilibrium...Ch. 7.7 - Prob. 7.8PCh. 7.7 - Prob. 7.9PCh. 7 - 7-10 The rate of disappearance of HCI was measured...
Ch. 7 - 7-11 Consider the following reaction: Suppose we...Ch. 7 - 7-12 Two kinds of gas molecules are reacted at a...Ch. 7 - 7-13 Why are reactions between ions in aqueous...Ch. 7 - Prob. 7.14PCh. 7 - 7-15 A certain reaction is exothermic by 9...Ch. 7 - 7-16 A quart of milk quickly spoils if left at...Ch. 7 - 7-17 If a certain reaction takes 16 h to go to...Ch. 7 - Prob. 7.18PCh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20PCh. 7 - Prob. 7.21PCh. 7 - 7-22 If you add a piece of marble, CaCO3 to a 6 M...Ch. 7 - Prob. 7.23PCh. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - 7-26 Write the chemical equations corresponding to...Ch. 7 - Prob. 7.27PCh. 7 - 7-28 When the following reaction reached...Ch. 7 - 7-29 The following reaction was allowed to reach...Ch. 7 - Prob. 7.30PCh. 7 - 7-31 Here are equilibrium constants for several...Ch. 7 - 7-32 A particular reaction has an equilibrium...Ch. 7 - Prob. 7.33PCh. 7 - Prob. 7.34PCh. 7 - 7-35 A reaction has a high rate constant but a...Ch. 7 - 7-36 Complete the following table showing the...Ch. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - Prob. 7.39PCh. 7 - 7-40 Is there any change in conditions that change...Ch. 7 - 7-41 The equilibrium constant at 1127°C for the...Ch. 7 - Prob. 7.42PCh. 7 - 7-43 (Chemical Connections 7A and 7B) Why is a...Ch. 7 - Prob. 7.44PCh. 7 - 7-45 (Chemical Connections 7C) A painkiller—for...Ch. 7 - 7-46 (Chemical Connections 7D) What reaction takes...Ch. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - Prob. 7.49PCh. 7 - 7-50 Draw an energy diagram for an exothermic...Ch. 7 - Prob. 7.51PCh. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - 7-57 Write the reaction to which the following...Ch. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.61PCh. 7 - Prob. 7.62PCh. 7 - Prob. 7.63PCh. 7 - 7-64 As we shall see in Chapter 20, there are two...Ch. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Prob. 7.67PCh. 7 - Prob. 7.68PCh. 7 - 7-69 Pure carbon exists is several forms, two of...Ch. 7 - Prob. 7.70PCh. 7 - 7-71 You have a beaker that contains solid silver...Ch. 7 - Prob. 7.72PCh. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Prob. 7.75PCh. 7 - Prob. 7.76PCh. 7 - Prob. 7.77PCh. 7 - Prob. 7.78PCh. 7 - Prob. 7.79PCh. 7 - Prob. 7.80PCh. 7 - Prob. 7.81PCh. 7 - 7-82 An equilibrium mixture of O2, SO2, and SO3...Ch. 7 - Prob. 7.83PCh. 7 - Prob. 7.84P
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- Hi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forward
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