Student Solutions Manual for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th
11th Edition
ISBN: 9781305081055
Author: Bettelheim, Frederick A.
Publisher: Cengage Learning
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Chapter 7, Problem 7.42P
Interpretation Introduction
Interpretation:
Whether increase in body temperature kills bacteria directly or by other mechanism should be determined.
Concept Introduction:
Enzymes work in a particular temperature. If it is changed then
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 7 Solutions
Student Solutions Manual for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th
Ch. 7.1 - Problem 7-1 In the reaction we measure the...Ch. 7.4 - Problem 7-2 Calculate the rate for the reaction in...Ch. 7.6 - Prob. 7.3PCh. 7.6 - Prob. 7.4PCh. 7.6 - Prob. 7.5PCh. 7.7 - Prob. 7.6PCh. 7.7 - Problem 7-7 Consider the following equilibrium...Ch. 7.7 - Prob. 7.8PCh. 7.7 - Prob. 7.9PCh. 7 - 7-10 The rate of disappearance of HCI was measured...
Ch. 7 - 7-11 Consider the following reaction: Suppose we...Ch. 7 - 7-12 Two kinds of gas molecules are reacted at a...Ch. 7 - 7-13 Why are reactions between ions in aqueous...Ch. 7 - Prob. 7.14PCh. 7 - 7-15 A certain reaction is exothermic by 9...Ch. 7 - 7-16 A quart of milk quickly spoils if left at...Ch. 7 - 7-17 If a certain reaction takes 16 h to go to...Ch. 7 - Prob. 7.18PCh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20PCh. 7 - Prob. 7.21PCh. 7 - 7-22 If you add a piece of marble, CaCO3 to a 6 M...Ch. 7 - Prob. 7.23PCh. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - 7-26 Write the chemical equations corresponding to...Ch. 7 - Prob. 7.27PCh. 7 - 7-28 When the following reaction reached...Ch. 7 - 7-29 The following reaction was allowed to reach...Ch. 7 - Prob. 7.30PCh. 7 - 7-31 Here are equilibrium constants for several...Ch. 7 - 7-32 A particular reaction has an equilibrium...Ch. 7 - Prob. 7.33PCh. 7 - Prob. 7.34PCh. 7 - 7-35 A reaction has a high rate constant but a...Ch. 7 - 7-36 Complete the following table showing the...Ch. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - Prob. 7.39PCh. 7 - 7-40 Is there any change in conditions that change...Ch. 7 - 7-41 The equilibrium constant at 1127°C for the...Ch. 7 - Prob. 7.42PCh. 7 - 7-43 (Chemical Connections 7A and 7B) Why is a...Ch. 7 - Prob. 7.44PCh. 7 - 7-45 (Chemical Connections 7C) A painkiller—for...Ch. 7 - 7-46 (Chemical Connections 7D) What reaction takes...Ch. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - Prob. 7.49PCh. 7 - 7-50 Draw an energy diagram for an exothermic...Ch. 7 - Prob. 7.51PCh. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - 7-57 Write the reaction to which the following...Ch. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.61PCh. 7 - Prob. 7.62PCh. 7 - Prob. 7.63PCh. 7 - 7-64 As we shall see in Chapter 20, there are two...Ch. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Prob. 7.67PCh. 7 - Prob. 7.68PCh. 7 - 7-69 Pure carbon exists is several forms, two of...Ch. 7 - Prob. 7.70PCh. 7 - 7-71 You have a beaker that contains solid silver...Ch. 7 - Prob. 7.72PCh. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Prob. 7.75PCh. 7 - Prob. 7.76PCh. 7 - Prob. 7.77PCh. 7 - Prob. 7.78PCh. 7 - Prob. 7.79PCh. 7 - Prob. 7.80PCh. 7 - Prob. 7.81PCh. 7 - 7-82 An equilibrium mixture of O2, SO2, and SO3...Ch. 7 - Prob. 7.83PCh. 7 - Prob. 7.84P
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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