Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 7, Problem 7.17E
(a)
Interpretation Introduction
Interpretation:
The number of steps in the reaction has to be given.
(b)
Interpretation Introduction
Interpretation:
The rate-determining step of the reaction has to be given.
(c)
Interpretation Introduction
Interpretation:
The fastest step of the reaction has to be given.
(d)
Interpretation Introduction
Interpretation:
The number of intermediates in the reaction has to be given.
(e)
Interpretation Introduction
Interpretation:
The effect of catalyst in the overall reaction has to be given.
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A student proposes the following two-step synthesis of an ether from an alcohol A:
1. strong base
A
2. R
Is the student's proposed synthesis likely to work?
If you said the proposed synthesis would work, enter the chemical
formula or common abbreviation for an appropriate strong base to use
in Step 1:
If you said the synthesis would work, draw the structure of an alcohol
A, and the structure of the additional reagent R needed in Step 2, in
the drawing area below.
If there's more than one reasonable choice for a good reaction yield,
you can draw any of them.
☐
Click and drag to start drawing a structure.
Yes
No
ロ→ロ
0|0
G
Х
D
: ☐
ப
टे
Predict the major products of this organic reaction.
Be sure to use wedge and dash bonds when necessary, for example to distinguish between different major products.
☐
☐
: ☐
+
NaOH
HO
2
Click and drag to start
drawing a structure.
Shown below are five NMR spectra for five different C6H10O2 compounds. For each spectrum, draw the structure of the compound, and assign the spectrum by labeling H's in your structure (or in a second drawing of the structure) with the chemical shifts of the corresponding signals (which can be estimated to nearest 0.1 ppm). IR information is also provided. As a reminder, a peak near 1700 cm-1 is consistent with the presence of a carbonyl (C=O), and a peak near 3300 cm-1 is consistent with the presence of an O–H.
Extra information: For C6H10O2 , there must be either 2 double bonds, or 1 triple bond, or two rings to account for the unsaturation. There is no two rings for this problem.
A strong band was observed in the IR at 1717 cm-1
Chapter 7 Solutions
Chemical Principles: The Quest for Insight
Ch. 7 - Prob. 7A.1ASTCh. 7 - Prob. 7A.1BSTCh. 7 - Prob. 7A.2ASTCh. 7 - Prob. 7A.2BSTCh. 7 - Prob. 7A.3ASTCh. 7 - Prob. 7A.3BSTCh. 7 - Prob. 7A.4ASTCh. 7 - Prob. 7A.4BSTCh. 7 - Prob. 7A.1ECh. 7 - Prob. 7A.2E
Ch. 7 - Prob. 7A.3ECh. 7 - Prob. 7A.4ECh. 7 - Prob. 7A.7ECh. 7 - Prob. 7A.8ECh. 7 - Prob. 7A.9ECh. 7 - Prob. 7A.10ECh. 7 - Prob. 7A.11ECh. 7 - Prob. 7A.12ECh. 7 - Prob. 7A.13ECh. 7 - Prob. 7A.14ECh. 7 - Prob. 7A.15ECh. 7 - Prob. 7A.16ECh. 7 - Prob. 7A.17ECh. 7 - Prob. 7A.18ECh. 7 - Prob. 7B.1ASTCh. 7 - Prob. 7B.1BSTCh. 7 - Prob. 7B.2ASTCh. 7 - Prob. 7B.2BSTCh. 7 - Prob. 7B.3ASTCh. 7 - Prob. 7B.3BSTCh. 7 - Prob. 7B.4ASTCh. 7 - Prob. 7B.4BSTCh. 7 - Prob. 7B.5ASTCh. 7 - Prob. 7B.5BSTCh. 7 - Prob. 7B.1ECh. 7 - Prob. 7B.2ECh. 7 - Prob. 7B.3ECh. 7 - Prob. 7B.4ECh. 7 - Prob. 7B.5ECh. 7 - Prob. 7B.6ECh. 7 - Prob. 7B.7ECh. 7 - Prob. 7B.8ECh. 7 - Prob. 7B.9ECh. 7 - Prob. 7B.10ECh. 7 - Prob. 7B.13ECh. 7 - Prob. 7B.14ECh. 7 - Prob. 7B.15ECh. 7 - Prob. 7B.16ECh. 7 - Prob. 7B.17ECh. 7 - Prob. 7B.18ECh. 7 - Prob. 7B.19ECh. 7 - Prob. 7B.20ECh. 7 - Prob. 7B.21ECh. 7 - Prob. 7B.22ECh. 7 - Prob. 7C.1ASTCh. 7 - Prob. 7C.1BSTCh. 7 - Prob. 7C.2ASTCh. 7 - Prob. 7C.2BSTCh. 7 - Prob. 7C.1ECh. 7 - Prob. 7C.2ECh. 7 - Prob. 7C.3ECh. 7 - Prob. 7C.4ECh. 7 - Prob. 7C.5ECh. 7 - Prob. 7C.6ECh. 7 - Prob. 7C.7ECh. 7 - Prob. 7C.8ECh. 7 - Prob. 7C.9ECh. 7 - Prob. 7C.11ECh. 7 - Prob. 7C.12ECh. 7 - Prob. 7D.1ASTCh. 7 - Prob. 7D.1BSTCh. 7 - Prob. 7D.2ASTCh. 7 - Prob. 7D.2BSTCh. 7 - Prob. 7D.1ECh. 7 - Prob. 7D.2ECh. 7 - Prob. 7D.3ECh. 7 - Prob. 7D.5ECh. 7 - Prob. 7D.6ECh. 7 - Prob. 7D.7ECh. 7 - Prob. 7D.8ECh. 7 - Prob. 7E.1ASTCh. 7 - Prob. 7E.1BSTCh. 7 - Prob. 7E.1ECh. 7 - Prob. 7E.2ECh. 7 - Prob. 7E.3ECh. 7 - Prob. 7E.4ECh. 7 - Prob. 7E.5ECh. 7 - Prob. 7E.6ECh. 7 - Prob. 7E.7ECh. 7 - Prob. 7E.8ECh. 7 - Prob. 7E.9ECh. 7 - Prob. 1OCECh. 7 - Prob. 7.1ECh. 7 - Prob. 7.2ECh. 7 - Prob. 7.3ECh. 7 - Prob. 7.4ECh. 7 - Prob. 7.5ECh. 7 - Prob. 7.6ECh. 7 - Prob. 7.7ECh. 7 - Prob. 7.9ECh. 7 - Prob. 7.11ECh. 7 - Prob. 7.14ECh. 7 - Prob. 7.15ECh. 7 - Prob. 7.17ECh. 7 - Prob. 7.19ECh. 7 - Prob. 7.20ECh. 7 - Prob. 7.23ECh. 7 - Prob. 7.25ECh. 7 - Prob. 7.26ECh. 7 - Prob. 7.29ECh. 7 - Prob. 7.30ECh. 7 - Prob. 7.31E
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