(a) Interpretation: Whether the given compound is isolated in the optically active form or not is to be stated. Concept introduction: A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

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Answer 1

Question

Chapter 7, Problem 7.12P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(d)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

Answer 2

Question

Chapter 7, Problem 7.12P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(d)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

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Answer 3

Question

Chapter 7, Problem 7.12P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(d)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

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Answer 4

Question

Chapter 7, Problem 7.12P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(d)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

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Answer 5

Chapter 7, Problem 7.12P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Interpretation Introduction

(d)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Answer 6

Chapter 7, Problem 7.12P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Answer 7

Chapter 7, Problem 7.12P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether the given compound is isolated in the optically active form or not is to be stated.

Concept introduction:

A carbon atom that has four non-equivalent atoms or groups attached to it is known as chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A chiral compound is able to move the plane polarized light is known to be optically active compound.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that the given compound can be isolated in the optically active form.

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