EBK MANUFACTURING ENGINEERING & TECHNOL
7th Edition
ISBN: 8220100793431
Author: KALPAKJIAN
Publisher: PEARSON
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Chapter 7, Problem 54QTP
(a)
To determine
For five polymers, sketch the UTS versus density graph.
(b)
To determine
For five polymers, sketch the elastic modulus versus UTS where appropriate, plot a range of values.
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There are 4 classifications of structural molecular characteristics of polymers - Linear, Network, Crosslinked. What is the
final type?
Answer:
Molecular weight data for some polymer are tabulated here. Compute (a) the number-average
molecular weight, (b) the weight-average molecular weight. (c) If it is known that this material's degree of
polymerization is 710, which one of the polymers listed in Table 14.3 is this polymer? Why?
Molecular Weight
Range g/mol
15,000-30,000
Xi
Wi
0.04
0.01
30,000-45,000
0.07
0.04
45,000-60,000
0.16
0.11
60,000-75,000
0.26
0.24
75,000-90,000
0.24
0.27
90,000 105,000
0.12
0.16
105,000-120,000
0.08
0.12
120,000-135,000
0.03
0.05
Please make sure to display your thought process? It is imperative to be able to follow how the answer was deduced. Please be as thorough as possible. Please address all parts of this question as they are all part and critical to answering this question correctly. Please show good integrity when answering the question:
Strain-rate, temperature, pressure, and aging time all affect the stress/strain behavior of polymers. Draw a stress-strain curve below for a typical ductile polymer. Clearly label the yield point and the ultimate tensile strength. Using this curve draw two new curves corresponding to same polymer but now tested at: 1) an increase in temperature and 2) an increase in strain rate. Explain what happens to the tensile behavior after: a) a prolong time of aging time is increased and b) when the tensile tests are conducted under super imposed hydrostatic compression
Chapter 7 Solutions
EBK MANUFACTURING ENGINEERING & TECHNOL
Ch. 7 - Summarize the important mechanical and physical...Ch. 7 - What are the major differences between the (a)...Ch. 7 - List properties that are influenced by the degree...Ch. 7 - What is the difference between condensation...Ch. 7 - Explain the differences between linear, branched,...Ch. 7 - What is the glass-transition temperature?Ch. 7 - List and explain the additives commonly used in...Ch. 7 - What is crazing?Ch. 7 - What are polyblends?Ch. 7 - List the major differences between thermoplastics...
Ch. 7 - What is an elastomer?Ch. 7 - What effects does a plasticizing agent have on a...Ch. 7 - Define the following abbreviations: PMMA, PVC,...Ch. 7 - Explain why it would be advantageous to produce a...Ch. 7 - What are the differences and similarities of...Ch. 7 - Are molecular weight and degree of polymerization...Ch. 7 - Why do polymers need to be dried before...Ch. 7 - What characteristics of polymers make them...Ch. 7 - Do polymers strain harden more than metals or vice...Ch. 7 - Inspect various plastic components in an...Ch. 7 - Give applications for which flammability of...Ch. 7 - What characteristics make polymers advantageous...Ch. 7 - What properties do elastomers have that...Ch. 7 - Do you think that the substitution of plastics for...Ch. 7 - Is it possible for a material to have a hysteresis...Ch. 7 - Observe the behavior of the specimen shown in Fig....Ch. 7 - Add more to the applications column in Table 7.3.Ch. 7 - Discuss the significance of the glass-transition...Ch. 7 - Prob. 29QLPCh. 7 - Explain how cross-linking improves the strength of...Ch. 7 - Describe the methods by which the optical...Ch. 7 - How can polymers be made to conduct electricity?...Ch. 7 - Explain the reasons for which elastomers were...Ch. 7 - Give several examples of plastic products or...Ch. 7 - Describe your opinions regarding the recycling of...Ch. 7 - Explain how you would go about determining the...Ch. 7 - Compare the values of the elastic modulus, given...Ch. 7 - Why is there so much variation in the stiffness of...Ch. 7 - Explain why thermoplastics are easier to recycle...Ch. 7 - Give an example where crazing is desirable.Ch. 7 - Describe the principle behind shrink wrapping.Ch. 7 - List and explain some environmental pros and cons...Ch. 7 - List the characteristics required of a polymer for...Ch. 7 - How can you tell whether a part is made of a...Ch. 7 - As you know, there are plastic paper clips...Ch. 7 - By incorporating small amounts of a blowing agent,...Ch. 7 - In injection-molding operations (Section 19.3), it...Ch. 7 - From an environmental standpoint, do you feel it...Ch. 7 - Calculate the areas under the stressstrain curve...Ch. 7 - Prob. 50QTPCh. 7 - Prob. 51QTPCh. 7 - Estimate the number of molecules in a typical...Ch. 7 - Using strength and density data, determine the...Ch. 7 - Prob. 54QTPCh. 7 - Prob. 55SDPCh. 7 - Describe the design considerations involved in...Ch. 7 - Assume that you are manufacturing a product in...Ch. 7 - Assume you work for a company that produces...Ch. 7 - Prob. 59SDPCh. 7 - Make a list of products or parts that currently...Ch. 7 - Prob. 61SDPCh. 7 - Prob. 62SDPCh. 7 - Prob. 63SDPCh. 7 - Prob. 64SDPCh. 7 - With Table 7.3 as a guide, inspect various...
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- (a) There are three main sub-groups of engineering polymers with distinct differences in their structures. Name these sub- groups; describe their structural differences and bonding mechanisms.arrow_forward(a) Draw a qualitative engineering stress-strain curve for A Ductile polymer (i) (ii) A Metal (iii) A ceramic (Iv) (v) A glass A Natural rubber Label carefully. Rationalize your sketch for each materialarrow_forwardNowadays, many cooking utensils are made of polymeric materials. However, people believe that heating plastic utensils would cause harm such as releasing toxic substances. Hence, people are looking for other alternatives to replace plastic. Choose ONE cooking utensil (spatula) and identify the suitable material that will satisfy its criteria. Justify your answer. Your discussion must include the interrelationship between structure-properties-processing of the selected cooking utensil.arrow_forward
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