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Chemistry: The Central Science Plus Mastering Chemistry with Pearson eText -- Access Card Package (14th Edition)
14th Edition
ISBN: 9780134292816
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Matthew E. Stoltzfus
Publisher: PEARSON
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Textbook Question
Chapter 7, Problem 50E
If the
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Students have asked these similar questions
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
cus
и
124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
Chapter 7 Solutions
Chemistry: The Central Science Plus Mastering Chemistry with Pearson eText -- Access Card Package (14th Edition)
Ch. 7.3 - Hypothetical elements X and Y form a molecule XY2,...Ch. 7.3 - Prob. 7.1.2PECh. 7.3 - Prob. 7.2.1PECh. 7.3 -
Arrange Be, C, K, and Ca in order of increasing...Ch. 7.3 - Arrange the following atoms and ions in order of...Ch. 7.3 - Prob. 7.3.2PECh. 7.3 - Prob. 7.4.1PECh. 7.3 - Prob. 7.4.2PECh. 7.4 - Prob. 7.5.1PECh. 7.4 - Prob. 7.5.2PE
Ch. 7.4 - Consider the following statements about first...Ch. 7.4 - Prob. 7.6.2PECh. 7.4 - Prob. 7.7.1PECh. 7.4 -
Write the electron configurations for (a) Ga3+...Ch. 7.6 - Prob. 7.8.1PECh. 7.6 - Prob. 7.8.2PECh. 7.6 - Prob. 7.9.1PECh. 7.6 - Prob. 7.9.2PECh. 7.7 - Prob. 7.10.1PECh. 7.7 - Prob. 7.10.2PECh. 7 - Prob. 1DECh. 7 - Prob. 1ECh. 7 -
7.2 Which of these spheres represents F, which...Ch. 7 - Prob. 3ECh. 7 - Prob. 4ECh. 7 - Prob. 5ECh. 7 - Prob. 6ECh. 7 - Prob. 7ECh. 7 - Prob. 8ECh. 7 - Prob. 9ECh. 7 - Prob. 10ECh. 7 - Prob. 11ECh. 7 -
7.12 Moseley's experiments on X rays emitted from...Ch. 7 - Among elements 1-18, which element or elements...Ch. 7 - Prob. 14ECh. 7 - Detailed calculations show that the value of Zeff...Ch. 7 - Detailed calculations show that the value of Zeff...Ch. 7 - Which will experience the greater effective...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Prob. 19ECh. 7 - Prob. 20ECh. 7 - Tungsten has the highest melting point of any...Ch. 7 - Prob. 22ECh. 7 - Estimate the As-I bond length from the data in...Ch. 7 - Prob. 24ECh. 7 - Using only the periodic table, arrange each set of...Ch. 7 - Using only the periodic table, arrange each set of...Ch. 7 - Prob. 27ECh. 7 - Prob. 28ECh. 7 - Which neutral atom is isoelectronic with each of...Ch. 7 - Some ions do not have a corresponding neutral atom...Ch. 7 - Consider the isoelectronic ions F- and Na+. (a)...Ch. 7 - Prob. 32ECh. 7 - Prob. 33ECh. 7 - Arrange each of the following sets of atoms and...Ch. 7 - Prob. 35ECh. 7 - In the ionic compoundsLiF,NaCI,KBr, andRbl, the...Ch. 7 - Prob. 37ECh. 7 -
7.38 Write equations that show the process for...Ch. 7 - Prob. 39ECh. 7 - Prob. 40ECh. 7 - Prob. 41ECh. 7 - (a) What is the trend in first ionization energies...Ch. 7 - Prob. 43ECh. 7 - Prob. 44ECh. 7 - Prob. 45ECh. 7 - Prob. 46ECh. 7 - Prob. 47ECh. 7 - Prob. 48ECh. 7 - Write an equation for the second electron affinity...Ch. 7 - If the electron affinity for an element is a...Ch. 7 - Prob. 51ECh. 7 -
7.52 What is the relationship between the...Ch. 7 - Prob. 53ECh. 7 - Consider the following equation: Ca + (g) + e-...Ch. 7 -
7.55(a) Does metallic character increase,...Ch. 7 - Prob. 56ECh. 7 - Prob. 57ECh. 7 - Prob. 58ECh. 7 - Predict whether each of the following oxides is...Ch. 7 - Prob. 60ECh. 7 - Would you expect manganese(II) oxide, MnO, react...Ch. 7 - Prob. 62ECh. 7 - Prob. 63ECh. 7 - An element X reacts with oxygen to form X02 and...Ch. 7 - Prob. 65ECh. 7 - Prob. 66ECh. 7 - Prob. 67ECh. 7 - Prob. 68ECh. 7 - Prob. 69ECh. 7 - Write a balanced equation for the reaction that...Ch. 7 - (a) As described in Section 7.7 , the alkali...Ch. 7 - Prob. 72ECh. 7 - Prob. 73ECh. 7 - Prob. 74ECh. 7 - Prob. 75ECh. 7 - Prob. 76ECh. 7 - Prob. 77ECh. 7 - Prob. 78ECh. 7 - Consider the stable elements through lead (Z =...Ch. 7 -
17.80]Figure 7.4 shows the radial probability...Ch. 7 - (a) If the core electrons were totally effective...Ch. 7 - Prob. 82AECh. 7 - Prob. 83AECh. 7 - Prob. 84AECh. 7 - Prob. 85AECh. 7 - The following observations are made about two...Ch. 7 - Prob. 87AECh. 7 - Prob. 88AECh. 7 - Prob. 89AECh. 7 - Prob. 90AECh. 7 - Explain the variation in the ionization energies...Ch. 7 - Prob. 92AECh. 7 - Prob. 93AECh. 7 - Prob. 94AECh. 7 - Prob. 95AECh. 7 - Prob. 96AECh. 7 - Prob. 97AECh. 7 - The electron affinities. in kJ/mol, for the group...Ch. 7 -
7.99 Hydrogen is an unusual element because it...Ch. 7 - Prob. 100AECh. 7 - Prob. 101AECh. 7 - Which of the following is the expected product of...Ch. 7 - Elemental cesium reacts more violently with water...Ch. 7 - Prob. 104AECh. 7 - Prob. 105AECh. 7 - Prob. 106AECh. 7 - Prob. 107AECh. 7 - Prob. 108AECh. 7 - Prob. 109IECh. 7 - Prob. 110IECh. 7 - Prob. 111IECh. 7 - Mercury in the environment can exist in oxidation...Ch. 7 - When magnesium metal is burned in air (Figure 3.6...Ch. 7 - Prob. 114IECh. 7 - Prob. 115IE
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- 3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forwardLabel the spectrum with spectroscopyarrow_forward
- Q1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forwardLabel the spectrumarrow_forwardNonearrow_forward
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