EBK ESSENTIAL ORGANIC CHEMISTRY
3rd Edition
ISBN: 8220100659461
Author: Bruice
Publisher: PEARSON
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Chapter 7, Problem 49P
Interpretation Introduction
Interpretation:
- The compound loses a proton more readily from two given compounds has to be predicted.
Concept Introduction:
Effect of delocalized electrons on
Due to Inductive effect, an anion is stabilized by a nearby electronegative atom. In the same way, electron delocalization also effective on stabilization of anion.
Rule: The strength of an acid depends on the stability of its conjugate base.
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a. Determine whether each of the Followery
Molecules
is in
the R- On the y-
Configuration
1-01"/
1-6-4
Br
4
I
el
Br
b. Draw The Fisher projection For all the
Meso compounds that can
exist FOR
The Following molenle
1- Refer to the monosaccharides below to answer each of the following question(s):
CH₂OH
CHO
CH₂OH
CH₂OH
0
H-
OH
0
0
HO-
H
H-
-OH
HO
H
HO H
H OH
HO- H
CH₂OH
H.
OH
HO
H
HO-
H
CH₂OH
CH₂OH
CH3
a. Sorbose
b. Rhamnose
c. Erythrulose
d. Xylulose
Classify each sugar by type; for example, glucose is an aldohexose.
a. Xylulose is ..
b. Erythrulose is .
c. Sorbose is ..
d. Rhamnose is ..
2- Consider the reaction below to answer the following question(s).
CHO
H
OH
CH₂OH
CH₂OH
HO-
H
HO
HO
+
H.
-OH
HO
OH
HO.
H
OH
OH
H
-OH
H
OH
CH₂OH
Q
Z
a.
Refer to Exhibit 25-11. Place a triangle around the anomeric carbon in compound Q.
Compound Z is:
b.
1. the D-anomer.
2. the a-anomer.
3. the ẞ-anomer.
4. the L-anomer.
c. Which anomer is the LEAST stable?
d. Q and Z are cyclic examples of:
a. acetals
b.
hemiacetals
c. alditols
d.
hemialditols
Chapter 7 Solutions
EBK ESSENTIAL ORGANIC CHEMISTRY
Ch. 7.4 - Prob. 1PCh. 7.5 - Prob. 3PCh. 7.6 - a. Predict the relative bond lengths of the three...Ch. 7.6 - Prob. 5PCh. 7.6 - Prob. 6PCh. 7.7 - Prob. 7PCh. 7.7 - Prob. 8PCh. 7.7 - Prob. 9PCh. 7.7 - Prob. 10PCh. 7.8 - Which member of each pair is the stronger acid? a....
Ch. 7.8 - Which member of each pair is the stronger base? a....Ch. 7.9 - Prob. 13PCh. 7.9 - Which species in each of the following pairs is...Ch. 7.9 - Prob. 16PCh. 7.11 - Prob. 18PCh. 7.11 - Prob. 19PCh. 7.11 - Prob. 20PCh. 7.11 - Prob. 21PCh. 7.11 - Prob. 22PCh. 7.12 - Prob. 23PCh. 7.12 - Prob. 24PCh. 7.15 - Prob. 25PCh. 7.15 - Which of the following are aromatic? A...Ch. 7.17 - Prob. 29PCh. 7.17 - Prob. 30PCh. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - Prob. 34PCh. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Which of the compounds in each of the following...Ch. 7 - Prob. 39PCh. 7 - Prob. 40PCh. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Which species in each of the pairs in Problem 45...Ch. 7 - Rank the following anions in order from most basic...Ch. 7 - a. Which oxygen atom has the greater electron...Ch. 7 - Prob. 49PCh. 7 - Which compound is the strongest base?Ch. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - a. Which dienophile in each pair is more reactive...Ch. 7 - Prob. 57PCh. 7 - Draw the product of each of the following...Ch. 7 - Prob. 59PCh. 7 - Prob. 60PCh. 7 - Prob. 61PCh. 7 - a. In what direction is the dipole moment in...Ch. 7 - Propose a mechanism for each of the following...Ch. 7 - Prob. 1PCh. 7 - Prob. 2PCh. 7 - Prob. 3PCh. 7 - Prob. 4PCh. 7 - Prob. 5PCh. 7 - Prob. 6PCh. 7 - Prob. 7PCh. 7 - Prob. 8PCh. 7 - Prob. 9PCh. 7 - Prob. 10PCh. 7 - Prob. 11PCh. 7 - Prob. 12P
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