CHEMISTRY >CUSTOM<
14th Edition
ISBN: 9781259137815
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 7, Problem 31QP
Explain the trends in
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1. For each of the reaction "railroads" below, you are either asked to give the structure(s) of the starting
material(s) or product(s), or provide reagents/conditions to accomplish the transformation, as
indicated by the boxes.
a.
NaOMe
H+
.CO,H
HO₂C
MeOH (excess)
MeOH
H3C
Br
يع
CH3
1. LiAlH4
2. H3O+
3. PBг3
H3C
1. Et-Li
2. H3O+
-CO₂Me
-CO₂Me
OH
CH3
CH3
ল
CH3
Predict the intermediate 1 and final product 2 of this organic reaction:
NaOMe
ག1, ད།་, -
+
H
You can draw 1 and 2 in any arrangement you like.
2
work up
Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge)
bonds at the chiral center.
Explanation
Check
Click and drag to start drawing a structure.
Х
© 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | P
What is the total energy cost associated with the compound below adopting the shown conformation?
CH3
HH
DH
CH3
Chapter 7 Solutions
CHEMISTRY >CUSTOM<
Ch. 7.1 - Practice Problem ATTEMPT What element(s) would you...Ch. 7.1 - Practice Problem BUILD
Arrange the following...Ch. 7.1 - Practice ProblemCONCEPTUALIZE Three different...Ch. 7.1 - 7.1.1 Which of the following elements would you...Ch. 7.1 - Prob. 2CPCh. 7.1 - Prob. 3CPCh. 7.2 - Practice Problem ATTEMPT Without using a periodic...Ch. 7.2 - Practice ProblemBUILD Identify the elements...Ch. 7.2 - Prob. 1PPCCh. 7.2 - 7.2.1 Which electron configuration is correct for...
Ch. 7.2 - Which of the following equations correctly...Ch. 7.3 - Practice Problem ATTEMPT Referring only to a...Ch. 7.3 - Practice Problem BUILD
For which of the following...Ch. 7.3 - Practice Problem CONCEPTUALIZE
Based on size and...Ch. 7.4 - Practice Problem ATTEMPT Which element. Mg or Al,...Ch. 7.4 - Prob. 1PPBCh. 7.4 - Practice ProblemCONCEPTUALIZE Imagine an...Ch. 7.4 - 7.4.1 Arrange the elements in order of increasing...Ch. 7.4 - Arrange the elements Li. Be. and B in order of...Ch. 7.4 - For each of the following pairs of elements,...Ch. 7.4 - Prob. 4CPCh. 7.5 - Practice ProblemATTEMPT Would you expect Mg or Al...Ch. 7.5 - Prob. 1PPBCh. 7.5 - Practice ProblemCONCEPTUALIZE In the same...Ch. 7.5 - Prob. 1CPCh. 7.5 - 7.5.2 Which of the following pairs are...Ch. 7.5 - 7.5.3 Select the correct ground-state electron...Ch. 7.5 - Prob. 4CPCh. 7.6 - Practice Problem ATTEMPT Between which two charges...Ch. 7.6 - Practice ProblemBUILD What must the distance be...Ch. 7.6 - Prob. 1PPCCh. 7.6 - Which of the following species are isoelectronic...Ch. 7.6 - Which of the following are arranged correctly in...Ch. 7.6 - 7.6.3 Which of the following is the most realistic...Ch. 7.6 - Which of the following is the most realistic...Ch. 7.7 - Practice Problem ATTEMPT Write electron...Ch. 7.7 - Practice ProblemBUILD List all the species (atoms...Ch. 7.7 - Practice Problem CONCEPTUALIZE
Select the correct...Ch. 7.8 - Practice Problem ATTEMPT
Write electron...Ch. 7.8 - Practice Problem BUILD
What common d-block ion...Ch. 7.8 - Prob. 1PPCCh. 7.9 - Practice ProblemATTEMPT Arrange the following...Ch. 7.9 - Practice Problem BUILD
List all the common ions...Ch. 7.9 - Practice ProblemCONCEPTUALIZE Which periodic...Ch. 7 - Often we can compare properties of two elements...Ch. 7 - 7.2
The colored spheres represent the ions Based...Ch. 7 - Group 8A exhibits the highest first ionization...Ch. 7 - Which of the following best describes why Z eff...Ch. 7 - 7.1 Briefly describe the significance of...Ch. 7 - What is Moseley's contribution to the modern...Ch. 7 - 7.3 Describe the general layout of a modern...Ch. 7 - 7.4 What is the most important relationship among...Ch. 7 - Prob. 5QPCh. 7 - Prob. 6QPCh. 7 - Prob. 7QPCh. 7 - 7.8 What is a main group element? Give names and...Ch. 7 - 7.9 Without referring to a periodic table, write...Ch. 7 - Prob. 10QPCh. 7 - You are given a sample of a dark, shiny solid and...Ch. 7 - What are valence electrons? For main group...Ch. 7 - Write the outer electron configurations for the...Ch. 7 - Use the first-row transition metals ( Sc to Cu )...Ch. 7 - Arsenic is not an essential element for the human...Ch. 7 - 7.16 In the periodic table, the element hydrogen...Ch. 7 - 7.17 A neutral atom of a certain element has 34...Ch. 7 - 7.18 Group the following electron configurations...Ch. 7 - Group the following electron configurations in...Ch. 7 - Prob. 20QPCh. 7 - Specify the group of the periodic table in which...Ch. 7 - Prob. 22QPCh. 7 - Explain why the atomic radius of Be is smaller...Ch. 7 - The electron configuration of B is 1 S 2 2 S 2 2 P...Ch. 7 - 7 25 The electron configuration of C is . (a) If...Ch. 7 - Define atomic radius. Does the size of an atom...Ch. 7 - How does atomic radius change (a) from left to...Ch. 7 - Prob. 28QPCh. 7 - Sketch the outline of the periodic table, and show...Ch. 7 - Prob. 30QPCh. 7 - Explain the trends in electron affinity from...Ch. 7 - A hydrogen-like ion is an ion containing only one...Ch. 7 - Prob. 33QPCh. 7 - On the basis of their positions in the periodic...Ch. 7 - 7.35 Arrange the following atoms in order of...Ch. 7 - 7.36 Which is the largest atom in the third period...Ch. 7 - Which is the smallest atom in Group 7A ?Ch. 7 - Based on size, identify the spheres shown as Na,...Ch. 7 - Based on size, identify the spheres shown as K,...Ch. 7 - Why is the radius of the lithium atom considerably...Ch. 7 - Use the second period of the periodic table as an...Ch. 7 - Arrange the following in order of increasing first...Ch. 7 - Arrange the following in order of increasing first...Ch. 7 - 7.44 Use the third period of the periodic table as...Ch. 7 - In general, the first ionization energy increases...Ch. 7 - Prob. 46QPCh. 7 - 7.47 Two atoms have the electron configurations ....Ch. 7 - Prob. 48QPCh. 7 - Specify which of the following elements you would...Ch. 7 - Considering their electron affinities, do you...Ch. 7 - Explain why alkali metals have a greater affinity...Ch. 7 - 7.52 How does the electron configuration of ions...Ch. 7 - 7.53 What do we mean when we say that two ions or...Ch. 7 - Prob. 54QPCh. 7 - Give three examples of first-row transition metal...Ch. 7 - A M 2+ ion derived from a metal in the first...Ch. 7 - A metal ion with a net +3 charge has five...Ch. 7 - Prob. 58QPCh. 7 - 7.59 Group the species that are isoelectronic: .
Ch. 7 - 7.60 Write the ground-state electron...Ch. 7 - Prob. 61QPCh. 7 - 7.62 Which of the following species are...Ch. 7 - Prob. 63QPCh. 7 - Prob. 64QPCh. 7 - Indicate which one of the two species in each of...Ch. 7 - Prob. 66QPCh. 7 - Prob. 67QPCh. 7 - Prob. 68QPCh. 7 - Prob. 69QPCh. 7 - Prob. 70QPCh. 7 - Prob. 71QPCh. 7 - Prob. 72QPCh. 7 - Prob. 73QPCh. 7 - Prob. 74QPCh. 7 - Prob. 75QPCh. 7 - Prob. 76QPCh. 7 - Prob. 77QPCh. 7 - Prob. 78QPCh. 7 - 7 79 Write balanced equations for the reactions...Ch. 7 - Write formulas for and name the binary hydrogen...Ch. 7 - Prob. 81QPCh. 7 - Prob. 82APCh. 7 - Prob. 83APCh. 7 - Write equations representing the following...Ch. 7 - Prob. 85APCh. 7 - Write the empirical (or molecular) formulas of...Ch. 7 - 7.87 Arrange the following species in...Ch. 7 - In which of the following are the species written...Ch. 7 - Which of the following properties show a clear...Ch. 7 - Prob. 90APCh. 7 - Prob. 91APCh. 7 - 7.92 For each pair of elements listed, give three...Ch. 7 - Prob. 93APCh. 7 - Explain why the first electron affinity of sulfur...Ch. 7 - Prob. 95APCh. 7 - 7.96 Predict the products of the following oxides...Ch. 7 - 7.97 write the formulas and names of the oxides of...Ch. 7 - Prob. 98APCh. 7 - The formula for calculating the energies of an...Ch. 7 - 7.100 Why do noble gases have negative electron...Ch. 7 - 7.101 The atomic radius of K is 227 pm and that of...Ch. 7 - 7.102 The atomic radius of F is 72 pm and that of ...Ch. 7 - Match each of the elements on the right with its...Ch. 7 - Prob. 104APCh. 7 - Prob. 105APCh. 7 - Prob. 106APCh. 7 - Prob. 107APCh. 7 - Explain, in terms of their electron...Ch. 7 - 7.109 Write the formulas and names of the hydrides...Ch. 7 - Prob. 110APCh. 7 - Prob. 111APCh. 7 - Prob. 112APCh. 7 - Most transition metal ions are colored. For...Ch. 7 - Prob. 114APCh. 7 - Prob. 115APCh. 7 - Prob. 116APCh. 7 - 7.117 Although it is possible to determine the...Ch. 7 - Prob. 118APCh. 7 - Prob. 119APCh. 7 - Predict the atomic number and ground-state...Ch. 7 - Prob. 121APCh. 7 - 7.122 Match each of the elements on the right with...Ch. 7 - One way to estimate the effective charge ( Z eff )...Ch. 7 - Use your knowledge of thermochemistry to calculate...Ch. 7 - Prob. 125APCh. 7 - 7.126 On one graph, plot the effective nuclear...Ch. 7 - 7.127 One allotropic form of an element X is a...Ch. 7 - 7.128 Calculate the maximum wavelength of light...Ch. 7 - Prob. 129APCh. 7 - Element M is a shiny and highly reactive metal (...Ch. 7 - Write the ground-state electron configurations of...Ch. 7 - Thallium (Tl) is a neurotoxin and exists mostly in...Ch. 7 - Both Mg 2+ and Ca 2+ are important biological...Ch. 7 - Prob. 134APCh. 7 - Prob. 135APCh. 7 - Prob. 136APCh. 7 - Prob. 137APCh. 7 - 7.138 The ionization energy of a certain element...Ch. 7 - 7.139 Experimentally, the electron affinity of an...Ch. 7 - A halogen has valence electrons in which orbitals?...Ch. 7 - Prob. 2SEPPCh. 7 - Prob. 3SEPPCh. 7 - Prob. 4SEPP
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