Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter 7, Problem 17CTQ
Interpretation Introduction

Interpretation: The structure of cis-1, 3-dimethylcyclohexane needs to be drawn in the chair conformation and the same molecule needs to be drawn after the chair flip.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

  Custom eBook for Organic Chemistry, Chapter 7, Problem 17CTQ , additional homework tip  1

Here, the substituted groups in the chair conformation are represented as follows:

  Custom eBook for Organic Chemistry, Chapter 7, Problem 17CTQ , additional homework tip  2

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

During the flipping, no bond is break. The numbering in the chair form is represented as follows:

  Custom eBook for Organic Chemistry, Chapter 7, Problem 17CTQ , additional homework tip  3

During ring flipping, mirror image of the chair conformation is formed.

It is represented as follows:

  Custom eBook for Organic Chemistry, Chapter 7, Problem 17CTQ , additional homework tip  4

Now, the ring flipping with groups attached can be represented as follows;

  Custom eBook for Organic Chemistry, Chapter 7, Problem 17CTQ , additional homework tip  5

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Can you please help mne with this problem. Im a visual person, so can you redraw it, potentislly color code and then as well explain it. I know im given CO2 use that to explain to me, as well as maybe give me a second example just to clarify even more with drawings (visuals) and explanations.
Part 1. Aqueous 0.010M AgNO 3 is slowly added to a 50-ml solution containing both carbonate [co32-] = 0.105 M and sulfate [soy] = 0.164 M anions. Given the ksp of Ag2CO3 and Ag₂ soy below. Answer the ff: Ag₂ CO3 = 2 Ag+ caq) + co} (aq) ksp = 8.10 × 10-12 Ag₂SO4 = 2Ag+(aq) + soy² (aq) ksp = 1.20 × 10-5 a) which salt will precipitate first? (b) What % of the first anion precipitated will remain in the solution. by the time the second anion starts to precipitate? (c) What is the effect of low pH (more acidic) condition on the separate of the carbonate and sulfate anions via silver precipitation? What is the effect of high pH (more basic)? Provide appropriate explanation per answer
Part 4. Butanoic acid (ka= 1.52× 10-5) has a partition coefficient of 3.0 (favors benzene) when distributed bet. water and benzene. What is the formal concentration of butanoic acid in each phase when 0.10M aqueous butanoic acid is extracted w❘ 25 mL of benzene 100 mL of a) at pit 5.00 b) at pH 9.00
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