a) Interpretation: Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn. Concept introduction: In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals. To draw: Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Question

3) The following molecule, chloral is a common precursor to chloral hydrate, an acetal type molecule that was a first-generation anesthetic. Draw a mechanism that accounts for tis formation and speculate why it does not require the use of an acid catalyst, like most hemiacetal and acetal reaction: (10 pts) H H₂O

Answer 1

Question

Chapter 6.SE, Problem 29EDRM

Interpretation Introduction

a)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

b)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

c)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

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3) The following molecule, chloral is a common precursor to chloral hydrate, an acetal type molecule that was a first-generation anesthetic. Draw a mechanism that accounts for tis formation and speculate why it does not require the use of an acid catalyst, like most hemiacetal and acetal reaction: (10 pts) H H₂O

You are a Quality Manager for a very well-known food ingredient company that produces umami powder, and you are responsible for setting specification limits. The net weight (in grams) of bags of unami powder is monitored by taking samples of six bags on an hourly basis during production. The label on every bag reports a contents of 1KG umami powder. The process mean is μ = 1012 g, and when the process is properly adjusted, it varies with σ = 11 g. QUESTION: Your organisation strives to ensure that >99.97% of bags of umami powder produced conforms to specification. What performance process index value is required to achieve this process yield? Calculate PPK using the following formula: Ppk = (USL – mean)/3 σ Ppk = (mean -LSL)/ 3 σ

You are a Quality Manager for a very well-known food ingredient company that produces umami powder, and you are responsible for setting specification limits. The net weight (in grams) of bags of unami powder is monitored by taking samples of six bags on an hourly basis during production. The label on every bag reports a contents of 1KG umami powder. The process mean is μ = 1012 g, and when the process is properly adjusted, it varies with σ = 11 g. QUESTION: Provide a valid and full justification as to whether you would advise your manager that the process is satisfactory when it is properly adjusted, or would you seek their approval to improve the process?

Answer 2

Question

Chapter 6.SE, Problem 29EDRM

Interpretation Introduction

a)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

b)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

c)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

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Answer 3

Question

Chapter 6.SE, Problem 29EDRM

Interpretation Introduction

a)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

b)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

c)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

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Answer 4

Question

Chapter 6.SE, Problem 29EDRM

Interpretation Introduction

a)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

b)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

c)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

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Answer 5

Chapter 6.SE, Problem 29EDRM

Interpretation Introduction

a)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

b)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

c)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Answer 6

Chapter 6.SE, Problem 29EDRM

Interpretation Introduction

a)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Answer 7

Chapter 6.SE, Problem 29EDRM

Interpretation Introduction

a)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Answer 8

Interpretation Introduction

b)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Answer 9

Interpretation Introduction

b)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Answer 10

Interpretation Introduction

c)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Answer 11

Interpretation Introduction

c)

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Answer 12

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Answer 23

Ch. 6.1 - Prob. 1P Ch. 6.3 - Prob. 2P Ch. 6.3 - Using curved fishhook arrows, propose a mechanism...Ch. 6.4 - Prob. 4P Ch. 6.4 - An electrostatic potential map of boron...Ch. 6.5 - What product would you expect from reaction of...Ch. 6.5 - Reaction of HBr with 2-methylpropene yields...Ch. 6.6 - Prob. 8P Ch. 6.6 - Predict the products of the following polar...Ch. 6.7 - Which reaction is more energetically favored, one...

Solution Summary: The author illustrates the flow of electrons in the given reaction and the structure of carbon radical formed when the halogen radical add to the alkene.

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