ORGANIC CHEMISTRY-EBOOK>I<
ORGANIC CHEMISTRY-EBOOK>I<
9th Edition
ISBN: 9781305084414
Author: McMurry
Publisher: INTER CENG
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Chapter 6.SE, Problem 29EDRM
Interpretation Introduction

a)

ORGANIC CHEMISTRY-EBOOK>I<, Chapter 6.SE, Problem 29EDRM , additional homework tip  1

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

b)

ORGANIC CHEMISTRY-EBOOK>I<, Chapter 6.SE, Problem 29EDRM , additional homework tip  2

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

Interpretation Introduction

c)

ORGANIC CHEMISTRY-EBOOK>I<, Chapter 6.SE, Problem 29EDRM , additional homework tip  3

Interpretation:

Curved arrows are to be drawn to show the flow of electrons in the given reaction. The structure of carbon radical that is formed when the halogen radical add to the alkenes is to be drawn.

Concept introduction:

In reactions involving free radicals homolytic cleavage of covalent bonds takes place. The free radicals produced in the initiation step reacts with the other reactant present in the propagation steps to yield new radicals.

To draw:

Curved arrows to show the flow of electrons in the given reaction and to show the structure of carbon radical that is formed when the halogen radical add to the alkenes.

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Chapter 6 Solutions

ORGANIC CHEMISTRY-EBOOK>I<

Ch. 6.7 - Prob. 11PCh. 6.9 - Which reaction is faster, one with ∆G‡ = +45...Ch. 6.10 - Prob. 13PCh. 6.SE - Prob. 14VCCh. 6.SE - Prob. 15VCCh. 6.SE - Prob. 16VCCh. 6.SE - Look at the following energy diagram: (a) Is...Ch. 6.SE - Look at the following energy diagram for an...Ch. 6.SE - What is the difference between a transition state...Ch. 6.SE - Prob. 20EDRMCh. 6.SE - Prob. 21EDRMCh. 6.SE - Draw an energy diagram for a two-step exergonic...Ch. 6.SE - Draw an energy diagram for a reaction with keq =...Ch. 6.SE - The addition of water to ethylene to yield ethanol...Ch. 6.SE - When isopropylidenecyclohexane is treated with...Ch. 6.SE - Prob. 26EDRMCh. 6.SE - Draw the electron-pushing mechanism for each...Ch. 6.SE - Draw the complete mechanism for each polar...Ch. 6.SE - Prob. 29EDRMCh. 6.SE - Identify the functional groups in the following...Ch. 6.SE - Identify the following reactions as additions,...Ch. 6.SE - Identify the likely electrophilic and nucleophilic...Ch. 6.SE - For each reaction below identify the electrophile...Ch. 6.SE - Prob. 34APCh. 6.SE - Follow the flow of electrons indicated by the...Ch. 6.SE - Prob. 36APCh. 6.SE - Prob. 37APCh. 6.SE - Despite the limitations of radical chlorination of...Ch. 6.SE - Prob. 39APCh. 6.SE - Answer question 6-39 taking all stereoisomers into...Ch. 6.SE - Prob. 41APCh. 6.SE - Prob. 42APCh. 6.SE - Prob. 43APCh. 6.SE - The reaction of hydroxide ion with chloromethane...Ch. 6.SE - Prob. 45APCh. 6.SE - Ammonia reacts with acetyl chloride (CH3COCl) to...Ch. 6.SE - The naturally occurring molecule α-terpineol is...Ch. 6.SE - Prob. 48APCh. 6.SE - Prob. 49APCh. 6.SE - Draw the structures of the two carbocation...
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