ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
6th Edition
ISBN: 9781260325294
Author: SMITH
Publisher: RENT MCG
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Chapter 6.8, Problem 19P

Consider the following energy diagram.

Chapter 6.8, Problem 19P, Problem 6.19 Consider the following energy diagram.

How many steps are involved in this

(a) How many steps are involved in this reaction?

(b) Label Δ H ° and E a for each step, and label Δ H ° overall .

(c) Label each transition state.

(d) Which point on the graph corresponds to a reactive intermediate?

(e) Which step is rate-determining?

(f) Is the overall reaction endothermic or exothermic?

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1d. Use Le Chatelier's principle to describe the effect of the following changes on the position of the Haber-Bosch equilibrium: N2(g) + 3H2(g)= 2NH3(9) AH = -92kJ Choose one of the following answers: shift to reactant side, shift to product side or no change and draw the resulting graph. I. Increase the [N2(g)] Effect: H₂ N₂ NH3 II. Decrease the volume of the container. Effect: H₂ N₂2 NH3
f) The unusual molecule [2.2.2] propellane is pictured. 1) Given the bond length and bond angles in the image, what hybridization scheme best describes the carbons marked by the askerisks? 2) What types of orbitals are used in the bond between the two carbons marked by the askerisks? 3) How does this bond compare to an ordinary carbon-carbon bond (which is usually 1.54 Å long)? CH2 1.60Å H₂C * H₂C CH2 C H2C * C Of H₂ 120°
e) Determine the hybridization and geometry around the indicated carbon atoms. H3C CH3 B HC CH2 A C C C CH3

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