ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
6th Edition
ISBN: 9781260325294
Author: SMITH
Publisher: RENT MCG
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Chapter 6, Problem 45P
Interpretation Introduction

(a)

Interpretation: The points on the graph correspond to transition states are to be identified.

Concept introduction: The transition state is formed during the conversion of reactants into products in the chemical reaction. In an energy level diagram, it corresponds to the high potential energy along the y-axis. In this state, the dashed bond implies that bonds are partially broken and partially formed in the reaction.

Interpretation Introduction

(b)

Interpretation: The points that correspond to reactive intermediates are to be stated.

Concept introduction: The transition state is formed during the conversion of reactants into products in the chemical reaction. In an energy level diagram, it corresponds to the high potential energy along the y-axis, while reactive intermediate has low potential energy.

Interpretation Introduction

(c)

Interpretation: The number of steps present in the reaction mechanism is to be identified.

Concept introduction: The number of steps in the reaction depends on the mechanism of the reaction. The activation energy (Ea) aids in determining the rate of the chemical reactions. The small value of Ea exhibits that less energy is required to convert the reactants into products. It increases the rate of reaction.

Interpretation Introduction

(d)

Interpretation: The each step of the mechanism is to be labeled as endothermic or exothermic.

Concept introduction: The chemical reaction in which energy is released during the formation of products is known as exothermic reactions. The energy released during the reaction is denoted by ΔH°. Exothermic and endothermic reactions are opposite to each other. The value of ΔH° for exothermic and endothermic reactions is positive and negative respectively.

Interpretation Introduction

(e)

Interpretation: The overall reaction as endothermic or exothermic is to be labeled.

Concept introduction: The chemical reaction in which energy is released during the formation of products is known as exothermic reactions. The energy released during the reaction is denoted by ΔH°. Exothermic and endothermic reactions are opposite to each other. The value of ΔH° for exothermic and endothermic reactions is positive and negative respectively.

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Chapter 6 Solutions

ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS

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