CHEMISTRY >CUSTOM<
14th Edition
ISBN: 9781259137815
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 6.2, Problem 1PPA
Practice Problem
ATTEMPT
Calculate the difference in energy (in joules) between a photon with
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 6 Solutions
CHEMISTRY >CUSTOM<
Ch. 6.1 - Practice ProblemATTEMPT What is the frequency (in...Ch. 6.1 - Prob. 1PPBCh. 6.1 - Practice Problem CONCEPTUALIZE
Which of the...Ch. 6.1 - Prob. 1CPCh. 6.1 - Calculate the frequency of light with wavelength...Ch. 6.1 - Prob. 3CPCh. 6.1 - Prob. 4CPCh. 6.2 - Practice Problem ATTEMPT
Calculate the difference...Ch. 6.2 - Prob. 1PPBCh. 6.2 - Prob. 1PPC
Ch. 6.2 - Prob. 1CPCh. 6.2 - Prob. 2CPCh. 6.2 - Prob. 3CPCh. 6.2 - Prob. 4CPCh. 6.3 - Prob. 1PPACh. 6.3 - Practice Problem BUILD
(a) Calculate the...Ch. 6.3 - Prob. 1PPCCh. 6.3 - Prob. 1CPCh. 6.3 - Prob. 2CPCh. 6.3 - Prob. 3CPCh. 6.3 - Prob. 4CPCh. 6.4 - Prob. 1PPACh. 6.4 - Prob. 1PPBCh. 6.4 - Prob. 1PPCCh. 6.4 - Prob. 1CPCh. 6.4 - Prob. 2CPCh. 6.5 - Practice ProblemATTEMPT Calculate the de Broglie...Ch. 6.5 - Prob. 1PPBCh. 6.5 - Prob. 1PPCCh. 6.5 - What is the minimum uncertainty in the position of...Ch. 6.5 - Prob. 2CPCh. 6.6 - Prob. 1PPACh. 6.6 - Prob. 1PPBCh. 6.6 - Prob. 1PPCCh. 6.6 - Prob. 1CPCh. 6.6 - Prob. 2CPCh. 6.6 - Prob. 3CPCh. 6.6 - Prob. 4CPCh. 6.7 - Practice Problem ATTEMPT
(a) What are the possible...Ch. 6.7 - Practice ProblemBUILD (a) What is the lowest...Ch. 6.7 - Practice Problem CONCEPTUALIZE
Imagine a cobbler's...Ch. 6.7 - Prob. 1CPCh. 6.7 - Prob. 2CPCh. 6.7 - Prob. 3CPCh. 6.7 - Prob. 4CPCh. 6.8 - Prob. 1PPACh. 6.8 - Prob. 1PPBCh. 6.8 - Prob. 1PPCCh. 6.8 - Prob. 1CPCh. 6.8 - What element is represented by the following...Ch. 6.8 - Which orbital diagram is correct for the...Ch. 6.9 - Practice Problem ATTEMPT
Write the electron...Ch. 6.9 - Prob. 1PPBCh. 6.9 - Prob. 1PPCCh. 6.9 - Prob. 1CPCh. 6.9 - Prob. 2CPCh. 6.9 - 6.9.3 Which of the following is a d-block element?...Ch. 6.9 - Prob. 4CPCh. 6.10 - Practice ProblemATTEMPT Without referring to...Ch. 6.10 - Practice ProblemBUILD Without referring to Figure...Ch. 6.10 - Practice ProblemCONCEPTUALIZE Consider again the...Ch. 6 - Key Skills Problems What is the noble gas core for...Ch. 6 - Which of the following electron configurations...Ch. 6 - What element is represented by the electron...Ch. 6 - What is the electron configuration of the Lu atom?...Ch. 6 - What is a wave? Using a diagram, define the...Ch. 6 - 6.2 What are the units for wavelength and...Ch. 6 - List the types of electromagnetic radiation having...Ch. 6 - 6.4 Give the high and low wavelength values that...Ch. 6 - (a) What is the wavelength (in nm) of light having...Ch. 6 - 6.6 (a) What is the frequency of light having a...Ch. 6 - 6.7 The SI unit of time is the second, which is...Ch. 6 - 6.8 How many minutes would it take a radio wave to...Ch. 6 - The average distance between Mars and Earth is...Ch. 6 - 6.10 Four waves represent light in four different...Ch. 6 - Briefly explain Planck’s quantum theory and...Ch. 6 - Prob. 12QPCh. 6 - 6.13 Explain what is meant by the photoelectric...Ch. 6 - 6.14 What are photons? What role did Einstein’s...Ch. 6 - A photon has a wavelength of 705 nm. Calculate the...Ch. 6 - The blue color of the sky results from the...Ch. 6 - 6.17 A photon has a frequency of . (a) Convert...Ch. 6 - What is the wavelength (in nm) of radiation that...Ch. 6 - When copper is bombarded with high energy...Ch. 6 - 6.20 A particular form of electromagnetic...Ch. 6 - The retina of a human eye can detect light when...Ch. 6 - The radioactive 60 Co isotope is used in nuclear...Ch. 6 - Photosynthesis makes use of visible light or bring...Ch. 6 - A red light was shined onto a metal sample and the...Ch. 6 - A photoelectric experiment was performed by...Ch. 6 - What are emission spectra? How do line spectra...Ch. 6 - What is an energy level? Explain the difference...Ch. 6 - Briefly describe Bohr's theory of the hydrogen...Ch. 6 - The first line of the Balmer series occurs at a...Ch. 6 - 6.30 Calculate the wavelength (in nm) of a photon...Ch. 6 - Calculate the frequency (Hz) and wavelength (nm)...Ch. 6 - Careful spectral analysis shows that the familiar...Ch. 6 - 6.33 An electron in the hydrogen atom makes a...Ch. 6 - 6.34 Consider the following energy levels of a...Ch. 6 - Some copper compounds emit green light when they...Ch. 6 - Is it possible for a fluorescent material to emit...Ch. 6 - Explain how astronomers are able to tell which...Ch. 6 - How does do Broglie's hypothesis account for the...Ch. 6 - 6.39 Why is Equation 6.9 meaningful only for...Ch. 6 - Does a baseball in flight possess wave properties?...Ch. 6 - 6.41 Thermal neutrons are neutrons that move at...Ch. 6 - Protons can be accelerated to speeds near that of...Ch. 6 - 6.43 What is the de Broglie wavelength (in cm) of...Ch. 6 - 6.44 What is the de Broglie wavelength (in nm)...Ch. 6 - Prob. 45QPCh. 6 - Prob. 46QPCh. 6 - Prob. 47QPCh. 6 - How is the concept of electron density used to...Ch. 6 - 6.49 What is an atomic orbital? How does an atomic...Ch. 6 - 6.50 Alveoli are tiny sacs of air in the lungs....Ch. 6 - 6.51 The speed of a thermal neutron (see Problem...Ch. 6 - 6.52 In the beginning of the twentieth century,...Ch. 6 - Prob. 53QPCh. 6 - Prob. 54QPCh. 6 - Which quantum number defines a shell? Which...Ch. 6 - Prob. 56QPCh. 6 - Prob. 57QPCh. 6 - Prob. 58QPCh. 6 - Prob. 59QPCh. 6 - Prob. 60QPCh. 6 - Prob. 61QPCh. 6 - 6.62 List the hydrogen orbitals in increasing...Ch. 6 - Prob. 63QPCh. 6 - Prob. 64QPCh. 6 - Prob. 65QPCh. 6 - Give the values of the four quantum numbers of an...Ch. 6 - Prob. 67QPCh. 6 - Prob. 68QPCh. 6 - Why do the 3s, 3p, and 3d orbitals have the same...Ch. 6 - Prob. 70QPCh. 6 - Prob. 71QPCh. 6 - Prob. 72QPCh. 6 - Prob. 73QPCh. 6 - Prob. 74QPCh. 6 - Prob. 75QPCh. 6 - Prob. 76QPCh. 6 - Prob. 77QPCh. 6 - Prob. 78QPCh. 6 - Prob. 79QPCh. 6 - Prob. 80QPCh. 6 - Prob. 81QPCh. 6 - Prob. 82QPCh. 6 - Indicate the number of unpaired electrons present...Ch. 6 - Prob. 84QPCh. 6 - Prob. 85QPCh. 6 - Prob. 86QPCh. 6 - Describe the characteristics of transition metals.Ch. 6 - What is the noble gas core? How does it simplify...Ch. 6 - Prob. 89QPCh. 6 - Prob. 90QPCh. 6 - 6.91 Explain why the ground-state electron...Ch. 6 - 6.92 Write the electron configuration of a xenon...Ch. 6 - Prob. 93QPCh. 6 - Prob. 94QPCh. 6 - Prob. 95QPCh. 6 - Prob. 96QPCh. 6 - 6.97 Write the ground-state electron...Ch. 6 - Prob. 98APCh. 6 - Discuss the current view of the correctness of the...Ch. 6 - Distinguish carefully between the following terms:...Ch. 6 - Prob. 101APCh. 6 - Identify the following individuals and their...Ch. 6 - Prob. 103APCh. 6 - Prob. 104APCh. 6 - Prob. 105APCh. 6 - Prob. 106APCh. 6 - Prob. 107APCh. 6 - 6.108 Ionization energy is the minimum energy...Ch. 6 - Prob. 109APCh. 6 - Prob. 110APCh. 6 - Prob. 111APCh. 6 - All molecules undergo vibrational motions. Quantum...Ch. 6 - When an electron makes a transition between energy...Ch. 6 - Prob. 114APCh. 6 - Prob. 115APCh. 6 - Prob. 116APCh. 6 - 6.11 The wave function for the is orbital in the...Ch. 6 - Prob. 118APCh. 6 - Prob. 119APCh. 6 - Prob. 120APCh. 6 - 6.121 Calculate the wavelength and frequency of an...Ch. 6 - Prob. 122APCh. 6 - 6.123 In a photoelectric experiment a student uses...Ch. 6 - Prob. 124APCh. 6 - Prob. 125APCh. 6 - Prob. 126APCh. 6 - Prob. 127APCh. 6 - Prob. 128APCh. 6 - Prob. 129APCh. 6 - Prob. 130APCh. 6 - Prob. 131APCh. 6 - Prob. 132APCh. 6 - 6.133 Blackbody radiation is the term used to...Ch. 6 - Prob. 134APCh. 6 - Prob. 135APCh. 6 - How many photons at 586 nm must be absorbed to...Ch. 6 - Prob. 137APCh. 6 - Prob. 1SEPPCh. 6 - Prob. 2SEPPCh. 6 - What is the energy of a photon with wavelength λ...Ch. 6 - The visible region of the electromagnetic spectrum...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
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