Macroscale and Microscale Organic Experiments
Macroscale and Microscale Organic Experiments
7th Edition
ISBN: 9781305577190
Author: Kenneth L. Williamson, Katherine M. Masters
Publisher: Brooks Cole
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Chapter 6, Problem 9Q
Interpretation Introduction

Interpretation:

Method to prepare freeze-dried food should be explained.

Concept introduction:

Sublimation is the conversion of a solid phase of a substance to the vapor phase and the vice-versa is known as a deposition. The amount of heat required for this conversion is known as heat of sublimation (ΔHsub). The conversion is as follows:

  GasDepositionSublimationSolid

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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