Interpretation:
The molecules of water that are required to carry over 1 molecule of iodobenzene are to be calculated. Also, the mass of water per gram of iodobenzene is to be calculated.
Concept introduction:
Steam distillation is used to extract and purify the temperature-sensitive compounds. Steam distillation is generally used for organic compounds that are sensitive to temperature. The advantage of steam distillation is that the temperature-sensitive compounds can be boiled and extracted at a lower temperature without decomposition.
Dalton law states that in a mixture of non-reacting gases the total pressure exerted by the mixture is equal to the summation of the partial pressure of individual gases present in the mixture.
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Chapter 6 Solutions
Macroscale and Microscale Organic Experiments
- Sodium chloride (NaCl) is commonly used to melt ice on roads during the winter. Calcium chloride (CaCl2) is sometimes used for this purpose too. Let us compare the effectiveness of equal masses of these two compounds in lowering the freezing point of water, by calculating the freezing point depression of solutions containing 200. g of each salt in 1.00 kg of water. (An advantage of CaCl2 is that it acts more quickly because it is hygroscopic, that is. it absorbs moisture from the air to give a solution and begin the process. A disadvantage is that this compound is more costly.)arrow_forwardConcentrated hydrochloric acid contains 1.00 mol HCl dissolved in 3.31 mol H2O. What is the mole fraction of HCl in concentrated hydrochloric acid? What is the molal concentration of HCl?arrow_forwardHow much N2 can dissolve in water at 25 C if the N2 partial pressure is 585 mm Hg?arrow_forward
- If you prepared a saturated aqueous solution of potassiumchloride at 25°C and then heated it to 50°C, wouldyou describe the solution as unsaturated, saturated, orsupersaturated? Explain.arrow_forwardPredict the relative solubility of each compound in the two solvents, on the basis of intermolecular attractions. (a) Is NaCl more soluble in water or in carbon tetrachloride? (b) Is I2 more soluble in water or in toluene (C6H5CH3)? (c) Is ethanol (C2H5OH) more soluble in hexane or in water? (d) Is ethylene glycol (HOCH2CH2OH) more soluble in ethanol or in benzene (C6H6)?arrow_forwardStarch contains CC, CH, CO, and OH bonds. Hydrocarbons have only CC and CH bonds. Both starch and hydrocarbons can form colloidal dispersions in water. Which dispersion is classified as hydrophobic? Which is hydrophilic? Explain briefly.arrow_forward
- Arrange 0.10 m aqueous solutions of the following solutes in order of decreasing freezing point and boiling point. (a) Al(ClO3)3(b) CH3OH (c) (NH4)2Cr2O7 (d) MgSO4arrow_forwardSpecifications for lactated Ringers solution, which is used for intravenous (IV) injections, are as follows to reach 100. mL of solution: 285315 mg Na+ 14.117.3 mg K+ 4.9Q.O mg Ca2+ 368408 mg Cl 231261 mg lactate, C3H5O3 a. Specify the amount of NaCl, KCl, CaCl2 2H2O, and NaC3H5O3 needed to prepare 100. mL lactated Ringers solution. b. What is the range of the osmotic pressure of the solution at 37C, given the preceding specifications?arrow_forwardPredict the relative solubility of each compound in the two solvents, on the basis of intermolecular attractions. (a) Is Br2 more soluble in water or in carbon tetrachloride? (b) Is CaCl2 more soluble in water or in benzene (C6H6)? (c) Is chloroform (CHCl3) more soluble in water or in diethyl ether [(C2H5)2O]? (d) Is ethylene glycol (HOCH2CH2OH) more soluble in water or in benzene (C6H6)?arrow_forward
- The dispersed phase of a certain colloidal dispersion consists of spheres of diameter 1.0 102 nm. (a) What are the volume (V=43r2) and surface area (A = r2) of each sphere? (b) How many spheres are required to give a total volume of 1.0 cm3? What is the total surface area of these spheres in square meters?arrow_forwardSamples of each of the substances listed below are dissolved in 125 g of water. Which of the solutions has the highest boiling point? (a) 3.0 g sucrose, C12H22O11 (b) 1.0 g glycerol, C3H3(OH)3 (c) 1.0 g propylene glycol, C3H6(OH)2 (d) 2.0 g glucose, C6H12(OH)2arrow_forwardConsider two hypothetical pure substances, AB(s) and XY(s). When equal molar amounts of these substances are placed in separate 500-mL samples of water, they undergo the following reactions: AB(s)A+(aq)+B(aq)XY(s)XY(aq) a Which solution would you expect to have the lower boiling point? Why? b Would you expect the vapor pressures of the two solutions to be equal? If not, which one would you expect to have the higher vapor pressure? c Describe a procedure that would make the two solutions have the same boiling point. d If you took 250 mL of the AB(aq) solution prepared above, would it have the same boiling point as the original solution? Be sure to explain your answer. e The container of XY(aq) is left out on the bench top for several days, which allows some of the water to evaporate from the solution. How would the melting point of this solution compare to the melting point of the original solution?arrow_forward
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