Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
5th Edition
ISBN: 9781305367487
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 6, Problem 96QRT
Interpretation Introduction

Interpretation:

The possible Lewis structure for S4N3Cl salt has to be drawn.

Concept Introduction:

Lewis structure otherwise known as Lewis dot diagrams or electron dot structures.

The bond between atoms and lone pairs of electrons that is present in the molecule.  Lewis structure represents each atom and their position in structure using the chemical symbol.  Excess electrons forms the lone pair are given by pair of dots, and are located next to the atom.

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Sulfur tetrafluoride reacts slowly with oxygen gas to form sulfur tetrafluoride monoxide.  Write a balanced chemical equation for the reaction. In the sulfur tetrafluoride monoxide molecule the O atom and the four F atoms are bonded to a central S atom. Write a Lewis structure for this molecule in which the formal charges of all atoms is zero. Use bond energies to estimate the enthalpy of the above reaction. (S-F bond energy = 327 kJ/mole). Is it endothermic or exothermic? Determine the electron geometry of the molecule and predict two possible molecular geometries. Which of the two molecular geometries in part d is more likely to be observed? Explain.
Use the Born-Haber cycle to calculate the lattice energy of KF. [The heat of sublimation of K is 91.6 kJ·mol−1 and  ΔfH(KF) = −567.3 kJ·mol−1.  Bond enthalpy for F2 is  158.8 kJ·mol−1.  Other data may be found in the Ionization Energies Table and the Electron Affinities Table.]
When gaseous sulfur trioxide is dissolved in concentratedsulfuric acid, disulfuric acid forms:SO₃(g)+ H₂SO₄(l) →H₂S₂O₇(l) Use bond energies Table to determine ΔH°ᵣₓₙ. (The S atoms in H₂S₂O₇ are bonded through an O atom. Assume Lewis structures with zero formal charges; BE of SNO is 552 kJ/mol.)

Chapter 6 Solutions

Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card

Ch. 6.6 - Prob. 6.6CECh. 6.7 - Prob. 6.7PSPCh. 6.7 - Prob. 6.7CECh. 6.8 - Prob. 6.8PSPCh. 6.9 - Prob. 6.9PSPCh. 6.9 - Prob. 6.9CECh. 6.10 - Prob. 6.10PSPCh. 6.11 - Prob. 6.10ECh. 6.11 - Prob. 6.11ECh. 6.11 - Prob. 1CECh. 6.11 - Prob. 2CECh. 6.12 - Repeat Problem-Solving Example 6.11, but use N2...Ch. 6.12 - Use MO theory to predict the bond order and the...Ch. 6 - Prob. 1QRTCh. 6 - Prob. 2QRTCh. 6 - Prob. 3QRTCh. 6 - Prob. 4QRTCh. 6 - Prob. 5QRTCh. 6 - Prob. 6QRTCh. 6 - Which of these molecules have an odd number of...Ch. 6 - Prob. 8QRTCh. 6 - Prob. 9QRTCh. 6 - Prob. 10QRTCh. 6 - Prob. 11QRTCh. 6 - Prob. 12QRTCh. 6 - Explain in your own words why the energy of two H...Ch. 6 - Prob. 14QRTCh. 6 - Prob. 15QRTCh. 6 - Prob. 16QRTCh. 6 - Prob. 17QRTCh. 6 - Prob. 18QRTCh. 6 - Prob. 19QRTCh. 6 - Write Lewis structures for tetracyanoethene,...Ch. 6 - Prob. 21QRTCh. 6 - Prob. 22QRTCh. 6 - Prob. 23QRTCh. 6 - Prob. 24QRTCh. 6 - Prob. 25QRTCh. 6 - Prob. 26QRTCh. 6 - Prob. 27QRTCh. 6 - Prob. 28QRTCh. 6 - Prob. 29QRTCh. 6 - For each pair of bonds, predict which is the...Ch. 6 - Prob. 31QRTCh. 6 - Prob. 32QRTCh. 6 - Which bond requires more energy to break: the...Ch. 6 - Estimate ΔrH° for forming 2 mol ammonia from...Ch. 6 - Prob. 35QRTCh. 6 - Light of appropriate wavelength can break chemical...Ch. 6 - Prob. 37QRTCh. 6 - Prob. 38QRTCh. 6 - Prob. 39QRTCh. 6 - Acrolein is the starting material for certain...Ch. 6 - Prob. 41QRTCh. 6 - Prob. 42QRTCh. 6 - Write the correct Lewis structure and assign a...Ch. 6 - Prob. 44QRTCh. 6 - Prob. 45QRTCh. 6 - Two Lewis structures can be written for nitrosyl...Ch. 6 - Prob. 47QRTCh. 6 - Prob. 48QRTCh. 6 - Prob. 49QRTCh. 6 - Prob. 50QRTCh. 6 - Several Lewis structures can be written for...Ch. 6 - Prob. 52QRTCh. 6 - Prob. 53QRTCh. 6 - Prob. 54QRTCh. 6 - Prob. 55QRTCh. 6 - Draw resonance structures for each of these ions:...Ch. 6 - Three known isomers exist of N2CO, with the atoms...Ch. 6 - Write the Lewis structure for (a) BrF5 (b) IF5 (c)...Ch. 6 - Write the Lewis structure for BrF3 XeF4 Ch. 6 - Prob. 60QRTCh. 6 - Prob. 61QRTCh. 6 - Prob. 62QRTCh. 6 - All carbon-to-carbon bond lengths are identical in...Ch. 6 - Prob. 64QRTCh. 6 - Prob. 65QRTCh. 6 - Prob. 66QRTCh. 6 - Prob. 67QRTCh. 6 - Prob. 68QRTCh. 6 - Prob. 69QRTCh. 6 - Prob. 70QRTCh. 6 - Using just a periodic table (not a table of...Ch. 6 - The CBr bond length in CBr4 is 191 pm; the BrBr...Ch. 6 - Prob. 73QRTCh. 6 - Acrylonitrile is the building block of the...Ch. 6 - Prob. 75QRTCh. 6 - Write Lewis structures for (a) SCl2 (b) Cl3+ (c)...Ch. 6 - Prob. 77QRTCh. 6 - Prob. 78QRTCh. 6 - A student drew this incorrect Lewis structure for...Ch. 6 - This Lewis structure for SF5+ is drawn...Ch. 6 - Tribromide, Br3, and triiodide, I3, ions are often...Ch. 6 - Explain why nonmetal atoms in Period 3 and beyond...Ch. 6 - Prob. 83QRTCh. 6 - Prob. 84QRTCh. 6 - Prob. 85QRTCh. 6 - Prob. 86QRTCh. 6 - Which of these molecules is least likely to exist:...Ch. 6 - Write the Lewis structure for nitrosyl fluoride,...Ch. 6 - Prob. 91QRTCh. 6 - Methylcyanoacrylate is the active ingredient in...Ch. 6 - Aspirin is made from salicylic acid, which has...Ch. 6 - Prob. 94QRTCh. 6 - Prob. 95QRTCh. 6 - Prob. 96QRTCh. 6 - Prob. 97QRTCh. 6 - Prob. 98QRTCh. 6 - Nitrosyl azide, N4O, is a pale yellow solid first...Ch. 6 - Write the Lewis structures for (a) (Cl2PN)3 (b)...Ch. 6 - Nitrous oxide, N2O, is a linear molecule that has...Ch. 6 - The azide ion, N3, has three resonance hybrid...Ch. 6 - Hydrazoic acid, HN3, has three resonance hybrid...Ch. 6 - Prob. 104QRTCh. 6 - Experimental evidence indicates the existence of...Ch. 6 - Prob. 106QRTCh. 6 - Prob. 107QRTCh. 6 - Pipeline, the active ingredient in black pepper,...Ch. 6 - Sulfur and oxygen form a series of 2 anions...Ch. 6 - Prob. 110QRTCh. 6 - Prob. 111QRTCh. 6 - Prob. 112QRTCh. 6 - Prob. 113QRTCh. 6 - Prob. 114QRTCh. 6 - Prob. 115QRTCh. 6 - Prob. 116QRTCh. 6 - Prob. 117QRTCh. 6 - Prob. 118QRTCh. 6 - Prob. 6.ACPCh. 6 - Prob. 6.BCPCh. 6 - Prob. 6.CCP
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